Polymer substrate material, membrane bioreactor (MBR) flat membrane supporting plate material and preparation method of polymer substrate material
A base material and polymer technology, applied in the field of processing materials, can solve the problems of high cost and heavy weight, and achieve the effects of low price, good injection molding and extrusion capabilities, and easy processing
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Embodiment 1
[0028] The polymer base material of this embodiment is characterized by comprising: terephthalic acid, ethylene glycol and cyclohexanedimethanol, the molar ratio of which is 0.8:0.75:0.75.
[0029] The preparation method of the polymer base material of this embodiment includes the following steps: mixing terephthalic acid, ethylene glycol and cyclohexanedimethanol to form a slurry, first performing an esterification reaction, and completing the esterification reaction The intrinsic viscosity is 0.10dl / g, and polycondensation reaction is carried out.
[0030] Wherein, esterification comprises carrying out separately successively:
[0031] (1) The first esterification stage: under the esterification conditions of a gauge pressure of 50kpa, a temperature of 250°C, and a liquid level of 30%, the residence time was 2.5 hours;
[0032] (2) The second esterification stage: gauge pressure 0.5kpa, temperature 260°C, liquid level 35% under esterification conditions, residence time 1.5 ...
Embodiment 2
[0039] The polymer base material of this embodiment is characterized by comprising: terephthalic acid, ethylene glycol and cyclohexanedimethanol, the molar ratio of which is 1.2:0.8:1.0.
[0040] The preparation method of the polymer base material of this embodiment includes the following steps: mixing terephthalic acid, ethylene glycol and cyclohexanedimethanol to form a slurry, first performing an esterification reaction, and completing the esterification reaction The intrinsic viscosity is 0.17dl / g, and polycondensation reaction is carried out.
[0041] Wherein, esterification comprises carrying out separately successively:
[0042] (1) The first esterification stage: under the esterification conditions of gauge pressure 85kpa, temperature 265°C, and liquid level 55%, the residence time is 4 hours;
[0043] (2) The second esterification stage: gauge pressure 3.5kpa, temperature 270 ° C, liquid level 50% under the esterification conditions, residence time 2 hours;
[0044]...
Embodiment 3
[0050] The polymer base material of this embodiment is characterized in that it comprises: terephthalic acid, ethylene glycol and cyclohexane dimethanol, and its molar ratio is (0.8~1.5):(0.75~0.8):(0.75~1.2) .
[0051] The preparation method of the polymer base material of this embodiment includes the following steps: mixing terephthalic acid, ethylene glycol and cyclohexanedimethanol to form a slurry, first performing an esterification reaction, and completing the esterification reaction The intrinsic viscosity is (0.10-0.20) dl / g, and then undergoes polycondensation reaction.
[0052] Wherein, esterification comprises carrying out separately successively:
[0053] (1) The first esterification stage: under the esterification conditions of gauge pressure (50-100) kpa, temperature (250-280) ° C, liquid level (30-80)%, residence time (2.5-5) hours;
[0054] (2) The second esterification stage: gauge pressure (0.5-5.0) kpa, temperature (260-285) ° C, liquid level (35-70)% unde...
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