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Preparation process of battery pole plate of lead-acid battery with high cycle performance

A lead-acid battery, battery plate technology, applied in lead-acid battery electrodes, battery electrodes, circuits, etc., can solve problems affecting battery performance and battery life, reduce sulfation, and achieve good conductivity and dispersion. , Improve the effect of corrosion resistance

Pending Publication Date: 2022-04-12
ZHANGZHOU HUAWEI POWER SUPPLY TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Both of these conditions will result in affecting battery performance and battery life
At present, there is no effective solution for the above in the prior art

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] This embodiment provides a battery plate preparation process for a lead-acid battery with high cycle performance. The battery plate includes a positive plate and a negative plate. This specific embodiment discloses the preparation process of the positive plate and the preparation process of the negative plate.

[0044] The preparation process of the positive plate comprises the following steps:

[0045] Step 1. Prepare positive plate raw materials, including: 0.07-0.10 parts of calcium, 0.004-0.025 parts of lanthanum, 1.4-1.5 parts of tin, 0.015-0.025 parts of aluminum, 0.002-0.0025 parts of silver, and the balance is lead powder;

[0046] The lead powder includes more than 99.2% lead by weight, and the lead powder also includes bismuth, zinc, iron, arsenic, copper, nickel, cadmium and the like.

[0047] Step 2, preparing a lanthanum-tin master alloy, the lanthanum-tin master alloy comprising 20% ​​by weight of lanthanum and 80% by weight of tin;

[0048] Include the f...

Embodiment 2

[0065] This embodiment discloses the preparation process of the negative electrode plate, and the negative electrode plate includes the negative electrode grid plate and the negative electrode lead paste coated on the surface of the negative electrode grid plate.

[0066] The preparation process of the negative plate comprises the following steps:

[0067] a. Preparation of negative plate raw materials, including: 0.1 parts by weight of fibers, 0.6-1.5 parts of organic additives, 4.5 parts of multilayer graphene microflakes, 10 parts of dilute sulfuric acid, 12 parts of deionized water, and the balance is lead with an oxidation degree of 71%. pink;

[0068] The density of the dilute sulfuric acid is 1.4g / cm 3 ;

[0069] The bulk density of the multilayer graphene microsheet is 0.06-0.09g / cm 3 ;

[0070] B, the lead powder that above-mentioned step a prepares, organic additive and multi-layer graphene microchip 4 are dropped into and paste machine dry stirring 5-10min mixes...

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Abstract

The invention relates to a preparation process of a battery pole plate of a lead-acid battery with high cycle performance, the battery pole plate of the lead-acid battery comprises a positive pole plate and a negative pole plate, the preparation process of the positive pole plate comprises the following steps: step 1, preparing raw materials of the positive pole plate, including 0.07-0.10 part of calcium, 0.004-0.025 part of lanthanum, 1.4-1.5 parts of tin, 0.015-0.025 part of aluminum, 0.002-0.0025 part of silver and the balance of lead powder; 2, preparing a lanthanum-tin master alloy, wherein the lanthanum-tin master alloy comprises 20% by weight of lanthanum and 80% by weight of tin; step 3, preparing a calcium-aluminum master alloy; step 4, preparing a positive plate, adding lead powder into a smelting furnace, heating to melt, then sequentially adding the calcium-aluminum master alloy, the lanthanum-tin master alloy and the residual tin, and uniformly stirring to obtain a positive plate alloy; and preparing the positive plate alloy into the positive plate. The positive plate battery plate prepared by the invention has good corrosion resistance and high mechanical strength.

Description

technical field [0001] The invention relates to the technical field of lead-acid batteries, in particular to a process for preparing battery plates of lead-acid batteries with high cycle performance. Background technique [0002] There are many reasons for the failure of the lead-acid battery service life, and the common reasons are: (1) corrosion of the positive plate of the lead-acid battery; (2) sulfation of the negative plate. specific: [0003] After the positive plate is corroded, lead oxides and salts are formed, which makes the positive plate lose its supporting active material and conductivity, and affects the service life of the battery. [0004] The negative electrode active material of the negative plate appears sulfation phenomenon, that is, the negative electrode generates irreversible large-particle crystal lead sulfate, and the conductivity of the negative plate of the battery becomes poor. [0005] Both of these conditions will result in impacts on battery...

Claims

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Application Information

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IPC IPC(8): H01M4/16H01M4/20H01M4/62H01M4/57C22C11/06C22C1/03
CPCY02E60/10
Inventor 柯志民郭锡民张英恢宋子明沈艺坡林念书
Owner ZHANGZHOU HUAWEI POWER SUPPLY TECH
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