Sunscreen paint for dyeing wood and coating method thereof
A wood and primer technology, applied in the direction of coatings, primers, epoxy resin coatings, etc., can solve the problems of discoloration, limited yellowing resistance, and fading of dyed veneer, so as to improve adhesion, reduce damage, and improve durability. The effect of performance
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preparation example 1
[0052] Preparation Example 1, an aminosilane oligomer, prepared according to the following method:
[0053] Step 1: Mix 1000g of N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane (aminosilane coupling agent) with 200g of ethanol, stir evenly, heat up to 50°C, and then dropwise add 50g of water , a mixed solution of 200g ethanol solvent, 30g hydroxy silicone oil and 1.5g emulsifier, and continue to stir and mix for 30min to obtain a hydrolyzed solution of aminosilane coupling agent;
[0054]Step 2: Heat the hydrolyzed solution obtained in step 1 to 100°C to carry out the polymerization reaction, carry out vacuum distillation after 2 hours, and recover the methanol solvent to obtain a prepolymer; heat the prepolymer to 120°C, continue to polymerize for 3 hours, and cool down. Discharge at 25°C to obtain aminosilane oligomer; after testing, the average degree of polymerization of this aminosilane oligomer is 9;
[0055] The hydroxy silicone oil in the above step 1 has a molecular w...
preparation example 2
[0056] Preparation example 2, a kind of aminosilane oligomer, is prepared according to the following method:
[0057] Step 1: Mix 1500g of 3-diethylenetriaminopropylmethyldimethoxysilane (aminosilane coupling agent) with 350g of ethanol, stir evenly, raise the temperature to 60°C, and then dropwise add 45g of water and 300g of ethanol solvent , a mixed solution of 65g hydroxy silicone oil and 3g emulsifier, continue to stir and mix for 1h to obtain a hydrolyzed solution of aminosilane coupling agent;
[0058] Step 2: Heat the hydrolyzed solution obtained in step 1 to 95°C to carry out the polymerization reaction. After 2 hours, perform vacuum distillation to recover the methanol solvent to obtain a prepolymer; heat the prepolymer to 130°C, continue to polymerize for 3 hours, and cool down. The material is discharged at 25° C. to obtain an aminosilane oligomer; after testing, the average degree of polymerization of the aminosilane oligomer is 5.
[0059] The hydroxy silicone o...
preparation example 3
[0060] Preparation example 3, a kind of aminosilane oligomer, is prepared according to the following method:
[0061] Step 1: Mix 1000g of N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane (aminosilane coupling agent) with 200g of ethanol, stir evenly, raise the temperature to 50°C, and then dropwise add 25g of water , a mixed solution of 160g ethanol solvent, 30g hydroxy silicone oil and 2g emulsifier, and continue to stir and mix for 30min to obtain a hydrolyzed solution of aminosilane coupling agent;
[0062] Step 2: Heat the hydrolyzed solution obtained in step 1 to 95°C to carry out the polymerization reaction. After 2 hours, carry out vacuum distillation to recover the methanol solvent to obtain a prepolymer; heat the prepolymer to 110°C, continue to polymerize for 2 hours, and cool down. Discharge at 25°C to obtain aminosilane oligomer; after testing, the average degree of polymerization of this aminosilane oligomer is 3;
[0063] The hydroxy silicone oil in the above ste...
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