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Comprehensive recycling process of chemical byproduct iron sludge

A technology of by-product iron and chemical industry, which is applied in the field of comprehensive recycling process of chemical by-product iron slime, can solve the problems of difficult recycling of chemical by-product iron slime and high cost of natural iron ore, so as to improve the overall economic benefit and practicality Strong performance and cost reduction effect

Pending Publication Date: 2022-06-28
CHUYUAN HIGH NEW TECH GRP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to overcome the above-mentioned technical deficiencies, provide a comprehensive recycling process of chemical by-product iron slime, and solve the technical problem in the prior art that the chemical by-product iron slime is difficult to effectively recycle and use natural iron ore as a raw material with high cost

Method used

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  • Comprehensive recycling process of chemical byproduct iron sludge

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] 1) 1 kg of the above-mentioned iron slime raw material is washed once to remove the organic substances contained therein to obtain washed tailings and washed coarse concentrate, and the obtained washed coarse concentrate iron-containing solid product TFe content is 62.75%.

[0037] 2) Perform weak magnetic separation I on the washed coarse concentrate obtained by water washing in step 1) to obtain magnetic separation concentrate A and the first magnetic separation tailings; the magnetic field strength of the weak magnetic separation magnetic separator is 100 KA / m. The first magnetic separation tailings were reduced and roasted for 90 minutes at 800 ° C and the ratio of mine to coal was 10, and the products obtained from roasting were ground. Conduct weak magnetic separation II to obtain magnetic separation concentrate B and second magnetic separation tailings.

[0038]3) Combine the magnetic separation concentrate B obtained from the weak magnetic separation II in the s...

Embodiment 2

[0040] 1) 1kg of the above-mentioned iron sludge raw material is washed twice to remove the organic substances contained therein to obtain washed tailings and washed coarse concentrate, and the obtained washed coarse concentrate iron-containing solid product TFe content is 63.52%.

[0041] 2) Perform weak magnetic separation I on the washed coarse concentrate obtained from the water washing in step 1) to obtain magnetic separation concentrate A and the first magnetic separation tailings; the magnetic field strength of the weak magnetic separation magnetic separator is 80 KA / m. The first magnetic separation tailings were reduced and roasted for 110 minutes at 850°C and the ratio of mine to coal was 11. The products obtained from roasting were ground. The particle size of the ground products was -0.074mm, accounting for 88.6%. Conduct weak magnetic separation II to obtain magnetic separation concentrate B and second magnetic separation tailings.

[0042] 3) Combine the magnetic ...

Embodiment 3

[0044] 1) 1kg of the above-mentioned iron sludge raw material is washed twice to remove the organic substances contained therein to obtain washed tailings and washed coarse concentrate, and the obtained washed coarse concentrate iron-containing solid product TFe content is 63.52%.

[0045] 2) Perform weak magnetic separation I on the washed coarse concentrate obtained from the water washing in step 1) to obtain magnetic separation concentrate A and the first magnetic separation tailings; the magnetic field strength of the weak magnetic separation magnetic separator is 120 KA / m. The first magnetic separation tailings were reduced and roasted for 110 minutes at 900°C and the ratio of mine to coal was 10. The products obtained from roasting were ground. The particle size of the ground products was -0.074mm, accounting for 86.3%. Conduct weak magnetic separation II to obtain magnetic separation concentrate B and second magnetic separation tailings.

[0046] 3) Combine the magnetic...

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Abstract

The invention relates to a comprehensive recycling process of chemical byproduct iron sludge, which comprises the following steps: (1) washing iron sludge to obtain washed rough concentrate and washed tailings, and carrying out magnetic separation on the washed rough concentrate to obtain magnetic concentrate A and first magnetic separation tailings; (2) performing reduction roasting on the first magnetic separation tailings to obtain roasted ore, grinding the roasted ore, and performing magnetic separation to obtain magnetic separation concentrate B and second magnetic separation tailings; (3) the magnetic separation concentrate A and the magnetic separation concentrate B are combined, ground and magnetically separated, and magnetic separation concentrate C and third magnetic separation tailings are obtained; the magnetic concentrate C is subjected to reverse flotation impurity removal, and reverse flotation concentrate containing magnetite concentrate and reverse flotation tailings are obtained; the second magnetic separation tailings and the third magnetic separation tailings are combined to serve as iron-containing raw materials for cement production. The method is simple and convenient in technological process, high in practicability and suitable for industrial production, the total recovery rate of the obtained magnetite concentrate is high, and the cost of adopting natural iron ore as a high-purity magnetite concentrate raw material is effectively reduced.

Description

technical field [0001] The invention belongs to the field of comprehensive utilization of solid waste, and in particular relates to a comprehensive recovery and utilization process of chemical by-product iron sludge. Background technique [0002] The chemical by-product iron sludge is the product of the oxidation of iron powder used as a reducing agent in the production of dye intermediates. The main component of chemical by-product iron sludge is iron oxides, mainly Fe 3 O 4 exist in the form, at the same time, may be mixed with Fe 2 O 3 , FeO, and a small amount of unreacted iron filings, with high iron content. The earliest use of more disposal methods is stockpiling and landfill. Due to the fine particle size of iron mud and the presence of toxic substances, long-term stacking not only occupies land, but also causes air and groundwater pollution. [0003] Since the 1980s, my country has carried out research on the utilization of iron sludge, recycling iron sludge a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B03B7/00
CPCB03B7/00Y02P10/20
Inventor 李智力杨丘唐远何东升廖杰陈红兵安建平朱秀文陈琲琲
Owner CHUYUAN HIGH NEW TECH GRP