Method for efficiently and cleanly degrading lignin in straw biomass
A biomass and lignin technology, applied in biofuels, energy wastewater treatment, textiles and papermaking, etc., can solve problems such as difficult direct degradation and utilization, and achieve the effect of improving resource utilization and low cost
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Embodiment 1
[0040] Sesame straw, washed and dried in an oven. Then, use a small pulverizer to crush the washed and dried sesame straws and pass through a 60-mesh sieve, and repeat this operation until all the sesame straws are completely sieved. The sieved powder was collected and kept dry in a vacuum desiccator.
Embodiment 2
[0042] Experiment on the effect of photocatalyst concentration on the degradation rate of lignin: Weigh 2.5g of dry sesame straw powder into a 250mL conical flask, weigh 50mg, 100mg, 150mg, 200mg, 250mg of TiO 2A conical flask was added, and 250 mL of distilled water was added, and ultrasonically dispersed for 15 min. After fully mixing, adjust the pH value of the system to 10, and move it into a photocatalytic reaction device, absorb it in the dark for 35 minutes, and then turn on the ultraviolet lamp (wavelength 254 nm) to irradiate for 6 hours to carry out the photocatalytic reaction. After the reaction, the sample was separated by suction filtration and washed with distilled water until the washing solution was neutral. The washed samples were placed in a constant temperature drying oven at 80°C and dried to constant weight. When TiO 2 When the mass concentration is 0.8g / L, the cellulose content reaches the maximum, which is 55.02%.
Embodiment 3
[0044] Experiment on the effect of the pH value of the catalytic system on the degradation rate of lignin: Weigh 2.5g of dry sesame straw powder and 150mg of TiO 2 Placed in a 250mL conical flask and added 250mL distilled water, ultrasonically dispersed for 15min. After fully mixing, adjust the pH value of the system to 6, 7, 8, 9, 11, 12, respectively, and move it into the photocatalytic reaction device, absorb it in the dark for 35 minutes, and then turn on the ultraviolet lamp (wavelength 254nm) for 6 hours of photocatalysis. reaction. After the reaction, the sample was separated by suction filtration and washed with distilled water until the washing solution was neutral. The washed samples were placed in a constant temperature drying oven at 80°C and dried to constant weight. When the initial pH of the photocatalytic system was 10.0, the mass concentration of lignin reached the lowest value of 14.07%, and the content of cellulose reached the maximum value of 54.88%.
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