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A bismuth sodium lithium titanate, lead-free piezoelectric technology, applied in ceramics, piezoelectric/electrostrictive/magnetostrictive devices, circuits, etc., can solve the problems of difficult polarization and practical application, and achieve electric hysteresis Good loop rectangularity, excellent piezoelectric ferroelectric properties, excellent performance effects
Inactive Publication Date: 2006-06-21
SICHUAN UNIV
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Simple Bi 0.5 Na 0.5 TiO 3 Ceramic coercive field is extremely large (73Kv / cm), polarization is difficult, and it is difficult to be practical, so Bi 0.5 Na 0.5 TiO 3 Modification to obtain lead-free piezoelectric ceramic system with low coercive field and good piezoelectric ferroelectric performance
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Embodiment 1
[0014] Formulation: [0.87Bi 0.5 (Na 0.925 Li 0.075 ) 0.5 TiO 3 +0.06BaTiO 3 +0.01SrTiO 3 +0.06CaTiO 3 ](97wt%)+Li 2 O(1wt%)+Y 2 o 3 (2wt%)
[0015] Performance: d 33 (pC / N) tgδ(%) ε 33 / ε 0 k p (%) Qm Poisson's ratio
[0016] 208 4.3 989 36.67 78 0.302
Embodiment 2
[0018] Formulation: [0.84Bi 0.5 (Na 0.925 Li 0.075 )0.5TiO 3 +0.08BaTiO 3 +0.02SrTiO 3 +0.06CaTiO 3 ](97wt%)+Li 2 O(1wt%)+Fe 2 o 3 (2wt%)
[0019] Performance: d 33 (pC / N) tgδ(%) ε 33 / ε 0 k p (%) Qm Poisson's ratio
[0020] 168 3.8 1185 17.3 82 0.297
[0021] When u=0, the composition formula (1-y-z) Bi is formed (1-w) (Na 1-x Li x ) w TiO 3 +yBaTiO 3 +zSrTiO 3 or add dopant M α o β (wt%) lead-free piezoelectric ceramics.
Embodiment 3
[0023] Formulation: 0.92Bi 0.6 (Na 0.90 Li 0.10 ) 0.4 TiO 3 +0.06BaTiO 3 +0.02SrTiO 3
[0024] Performance: d 33 (pC / N) tgδ(%) ε 33 / ε 0 k p (%) Qm Poisson's ratio
[0025] 200 3.6 940 32.1 109 0.296
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Abstract
The bismuth sodium titanate lithium barium strontium calcium lead-free piezoelectric ceramics relates to a new type of multi-element lead-free piezoelectric ceramic composition and belongs to the field of piezoelectric ceramics with perovskite structure and environment coordination. The composition provided by the invention can use general formula (1-y-z-u) Bi (1-w) (Na 1-x Li x ) w TiO 3 +yBaTiO 3 +zSrTiO 3 +uCaTiO 3 +aM α o β (wt%), where 0<x<0.5, 0≤y<1, 0≤z<1, 0≤u<1, 0<(y+z+u)<1, 0.3≤w≤0.7 ,M α o β It is one or more doped oxides whose content a accounts for the main component (1-y-z-u) Bi (1-w) (Na 1-x Li x ) w TiO 3 +yBaTiO 3 +zSrTiO 3 +uCaTiO 3 The weight ratio is 0-10%, M is an element with a valence of +1-+6 and can form a solid oxide with oxygen, such as Na, K, Li, Ni, Zn, Cr, Co, Nb, Ta, Al, Cu , Fe, Ce, Pr, Nd, Sm, Gd, Dy, Er, Yb, In, Y, Sc, La, Ho, Lu, Sn, Sb, Mn, Ca, Ba, Sr, Mg, Si, etc., α and β denotes the number of atoms of the corresponding element M and oxygen in the relevant oxide, respectively. The system piezoelectric ceramic composition d 33 Up to 200pC / N or more, k p It can reach more than 35.0%, its process is stable, it can be obtained by using traditional piezoelectric ceramic preparation technology and industrial raw materials, and it has practicability.
Description
1. Technical field [0001] The invention relates to a novel multi-component lead-free piezoelectric ceramic composition, which belongs to the field of piezoelectric ceramics with perovskite structure and environment coordination. 2. Background technology [0002] Since the discovery of the piezoelectricity of barium titanate ceramics in the mid-1940s, the structural feature is ABO 3 The research and development of piezoelectric ceramics is very active. Piezoelectric ceramics and their components have been widely used in industry, especially in the field of information industry. Lead zirconate titanate (Pb(Ti, Zr)O 3 ) as the representative lead-based binary system, the A position is Pb; the B position is (Ti, Zr) and lead zirconate titanate (Pb(Ti, Zr)O 3 ) as the base material, add the third component, such as lead magnesium niobate-lead titanate [Pb(Mg 1 / 3 Nb 2 / 3 )O 3 -PbTiO 3 ] as a representative, the A position is Pb, and the B position is Mg 1 / 3 Nb 2 / 3 The lead-...
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