Polyurethane urea elastic fibre and its preparation method

一种弹性纤维、聚氨酯脲的技术，应用在聚氨酯脲弹性纤维及其制备领域，能够解决没有描述耐光、耐废气、耐氯、抗氧化总耐候性、聚氨酯类弹性纤维性能和颜色易被日光改变、不能防止弹性体性能的等问题，达到优异耐热性和防紫外性、原有性能不会劣化、提高耐光性和加工性的效果

Inactive Publication Date: 2006-08-09
KOLON IND INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, if the polyurethane-based elastic fiber is exposed to the atmosphere, there is a problem that its original performance and color will be changed by sunlight, and it is easily changed by exhaust gas in the atmosphere, and it is also easily oxidized by the natural air outside, making it Its original performance deteriorates
[0004] In order to remedy these defects, Korean patent application No.90-10867 discloses the method of using phenolic antioxidants, amine UV light stabilizers and methacrylate yellowing inhibitors as additives, but its disadvantage is that methyl Acrylics have poor heat resistance, which causes the polymer to flow out and sublimate when spinning at high temperatures, causing troubles in processing
[0005] In U.S. Patent No. 4,548,975, a method for improving the thermal and oxidation stability of fibers by using phenolic antioxidants and phosphite antioxidants is disclosed, but it has a disadvantage that the polyurethane elastic fibers made performance and color are easily changed by sunlight
[0006] In Korean Patent Laid-Open No. 93-11337, a method for producing weatherable elastomers using phenolic antioxidants, phosphite antioxidants, amino acid yellowing inhibitors, and benzotriazole light stabilizers is described , but it has a problem that benzotriazole light stabilizers have almost no heat resistance and compatibility with polyurethane elastomers, making it flow out and sublimate during spinning, which has a bad effect on the process
[0007] Korean Patent Application No. 93-28704 describes a method for producing chlorine-resistant elastic fibers using inorganic salts, but it has a problem that the technology cannot prevent deterioration of elastomer properties caused by light and heat
[0008] Korean Patent Laid-Open No. 97-7688 discloses a composition using a phenolic antioxidant and a metal salt chlorine resistant agent, but it has a problem that this method cannot prevent fading and deterioration of physical properties caused by sunlight
[0009] In Korean Patent Laid-Open No. 96-11609, benzophenol-based light-resistant agents and inorganic salt chlorine-resistant agents are used to improve the performance of resistance to ultraviolet light and chlorine, but it has a problem that it cannot prevent the deterioration of physical properties due to heat or exhaust gas and fade
[0010] As described above, there are many proposals for compositions containing various stabilizers that improve the weather resistance of polyurethane-based elastomers, but there is no description of a technology that combines total weather resistance with light resistance, exhaust gas resistance, chlorine resistance, oxidation resistance, etc., and Method for preparing polyurethane elastic fiber capable of running for a long time in a stable processing state

Method used

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  • Polyurethane urea elastic fibre and its preparation method
  • Polyurethane urea elastic fibre and its preparation method
  • Polyurethane urea elastic fibre and its preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] A mixture of 4,4'-diphenylmethane diisocyanate and polytetramethylene ether glycol with a molar ratio of 2.0 was reacted at 90° C. for 90 minutes to prepare isocyanate-terminated polyurethane urea (prepolymer).

[0054] After cooling the prepolymer to 40°C, N,N'-dimethylacetamide was added to prepare a 45% solution containing the prepolymer. Cool the prepolymer solution to 5°C, then, to prepare the polyurethaneurea solution, add N,N'-dimethylacetamide solution containing 96% equivalent of ethylenediamine and 6% equivalent of diethylamine slowly under vigorous stirring , to grow and / or terminate its chain.

[0055] In the obtained polyurethaneurea solution, add 1.2% (weight) of 1,3,5-tri(4-tert-butyl-3-hydroxyl-2,6-xylene)-1 which accounts for the solids of the polyurethaneurea solution , 3,5-triazine-2,4,6-(1H,3H,5H)trione, 1.0% by weight of 1,1,1',1'-tetramethyl-4,4'-( Methylene-two-p-phenylene) diamino acid exhaust gas stabilizer, 1.2% (weight) of zinc oxide chlorin...

Embodiment 2

[0057] Use the method identical with embodiment 1, make polyurethane urea elastic fiber, difference is to use the additive N of 1.5% (weight). 2 -(4-carboethoxyphenyl)-N 1 -Methyl-N 1 - phenylformamidine UV absorber. Then, the light resistance, oxidation resistance (heat resistance), chlorine resistance and exhaust gas resistance of the fibers were evaluated, and the results are shown in Table 1 below.

Embodiment 3

[0059] Use the method identical with embodiment 1, make polyurethane urea elastic fiber, difference is to use the additive N of 1.0% (weight). 2 -(4-carboethoxyphenyl)-N 1 -Methyl-N 1 - phenylformamidine UV absorber. Then, the light resistance, oxidation resistance (heat resistance), chlorine resistance and exhaust gas resistance of the fibers were evaluated, and the results are shown in Table 1 below.

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Abstract

This invention relates to a polyurethaneurea elastic fiber of which the weatherability is excellent and the preparing method thereof. The invention prepares the polyurethaneurea elastic fiber by adding the formamidine type ultraviolet absorber of formula I to the spinning dope and the strength maintenance rate of the polyurethaneurea elastic fiber is over 90 % after being left for 24 hours at the Fade-O-Meter in which the sunshine carbon arc is installed, wherein, R1 and R2 represent an each alkyl group of 1 to 5 carbon atoms.

Description

[0001] This application is a divisional application of the parent application with the application date of January 8, 2001, the application number 00800787.x, and the name "polyurethane urea elastic fiber and its preparation method". technical field [0002] The invention relates to a polyurethane urea elastic fiber with excellent weather resistance and a preparation method thereof. technical background [0003] Polyurethane elastic fiber has excellent elasticity and elastic recovery, so it is widely used in socks, women, underwear, sportswear, swimwear, etc. However, if the polyurethane-based elastic fiber is exposed to the atmosphere, there is a problem that its original performance and color will be changed by sunlight, and it is easily changed by exhaust gas in the atmosphere, and it is also easily oxidized by the natural air outside, making it Its original performance deteriorates. [0004] In order to remedy these defects, Korean patent application No.90-10867 disclos...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D01F6/70D01F6/72D01F1/02C09K3/00D01F1/10D01F6/94
CPCD01F1/106D01F6/70
Inventor 权一天刘锡哲许亨敦
Owner KOLON IND INC
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