Concentrate herbicidal composition
A composition and herbicide technology, applied in animal repellents, plant growth regulators, preservation of human or animal bodies, etc., can solve the problems of undisclosed water-soluble herbicides
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Embodiment 1
[0177] A herbicidal suspoemulsion composition containing glyphosate, acetochlor and atrazine as active ingredients together with the safener clofenfur was prepared by the following procedure. "Surfactant M" is an activator containing 70% polyoxyethylene (15) tallow amine (HLB = 14), with the balance being polyethylene glycol for most formulations.
[0178] In a container with a stirring tool, 193 g of Monsanto's MON0139 (62% aqueous solution (by weight) of glyphosate isopropylamine salt), 134 g of Surfactant M, 15 g of propylene glycol, 4 g of sodium sulfite and 1.5 g of BASF's Mazu TM DF 100S (organosiloxane defoamer) was added to 389 g of water to make an aqueous premix. To this aqueous premix was added 247 g of atrazine (97% purity) powder with an average particle size of about 10 μm, 1.5 g of calcium carbonate and 15 g of Floridin's Minugel TM 400 (colloidal attapulgite). Stirring was continued for 10 minutes.
[0179] In a container with a stirring tool, by mixing 70...
Embodiment 2
[0183] Herbicidal suspoemulsions having the compositions shown in Table 2 below were prepared by a procedure similar to that described in Example 1. The stabilization system contains an anionic surfactant, Toximul from Stepan TM TANS-5 (alkylphenol ether sulfate / tallow amine ethoxylate of HLB=8) and two nonionic surfactants, Toximul of Stepan Company TM 8320 (butyl polyoxyalkylene block copolymer of HLB=12) and Toximul of Stepan Company TM SEE-340 (polyoxyethylene (20) sorbitan trioleate with HLB=11) mixture.
[0184] Element
weight%
MON 0139 (62% glyphosate isopropyl ammonium salt)
(Glyphosate a.e.
13.1
6.0)
Acetochlor (93%)
22.6
Atrazine (97%)
16.3
Acetofur
0.7
Anionic surfactants (Toximul TM TANS-5)
Nonionic surfactant mixture (Toximul TM 8320 / SEE-340)
Colloidal Hydrated Silica
colloidal attapulgite
5.5
4.5
1.0
2.0
Activator (surf...
Embodiment 3
[0188] A herbicidal suspoemulsion composition containing the active ingredients glyphosate, acetochlor and atrazine together with the safener clofenfur was prepared by the following procedure.
[0189] In the first mixing bucket, combine 364.9g water, 131.5g MON 0139, 13.3g 50% aqueous sodium hydroxide solution, 10.0g propylene glycol, 1.0g sodium sulfite and 3.0g Henkel's Agnique TM DF 6889 (organosiloxane defoamer) was added together to make an aqueous premix. Preferably the water is added first and the MON 0139 last, but the order of addition is not critical.
[0190] In the second mixing tank, add 7.3g of clofenfur to 227.4g of acetochlor (93% purity), and stir thoroughly to ensure that clofenfur is completely dissolved in acetochlor, thus preparing an organic pre mixture. Then add the anionic surfactant Stepfac of 27.0g Stepan company under continuing to stir TM 8171 (polyoxyethylene (6) nonylphenol phosphate), then add 3.3g Toximul TM 8320 with Toximul TM Nonionic ...
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