Water suspension acetamiprid nano capsule prepn and its preparing method

A technology of nanocapsules and water suspension, which is applied in the field of acetamiprid water suspension nanocapsules and pesticide formulations, which can solve the problems of pesticide residues, waste of resources, decomposition and waste, etc., to reduce acute toxicity, improve utilization rate, and stabilize sex-enhancing effect

Inactive Publication Date: 2004-04-28
HEBEI UNIVERSITY OF SCIENCE AND TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] 1. Contains a large amount of organic solvents, such as toluene, xylene, etc., causing thousands of tons of organic solvents to be discharged into nature every year, wasting resources and seriously polluting the environment
[0004] 2. When used, it needs to be diluted with water to form an emulsion. The active ingredients are micron-scale dispersed. The dispersibility of the active ingredients is poor and the effective utilization rate is low, resulting in a large amount of pesticides, resulting in increased agricultural costs and a large number of pesticide residues, which seriously affects the quality of agricultural products.
[0005] 3. The active ingredients have poor permeability, and the active ingredients remaining on the leaves are decomposed and wasted due to environmental factors such as light and air.
[0006] 4. The colonization of biological pesticides in the soil is poor, and the special ecological environment of the soil often inhibits the efficacy of biological pesticides, which limits the large-scale promotion of biological pesticides
[0007] Compared with emulsifiable concentrate, the microemulsion of acetamiprid can better solve the problems of water-based and high dispersion, but it is not a long-acting dosage form, and the release cannot be controlled. More importantly, the cost is high and the effect is not ideal

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0065]Dissolve 0.1g of ammonium persulfate in 20g of water (divided into two parts by 4:1), stand-by; 0.5g of acetamiprid is dissolved in the mixed monomer of 7g of styrene, 8g of butyl acrylate, and 0.2g of acrylic acid; Dissolve 6g of OP-40 and 1g of sodium lauryl sulfate in 50g of 2% polyvinyl alcohol aqueous solution, put it into a container with stirring, add the mixed monomers dissolved in acetamiprid under stirring, and disperse into an emulsion , into the reaction vessel. Heat to keep the temperature at 70±2°C, add the first part of initiator, react for 6 hours, keep warm for 1 hour, and prepare the seed emulsion; add 1.5g of styrene, 1.5g of butyl acrylate, 2g of toluene diisocyanate mixed monomer and Add the second initiator dropwise for 1 hour, keep warm for 2 hours, cool down; add additives, and discharge. The content of acetamiprid in the product was 0.5%.

Embodiment 2

[0067] Dissolve 0.1g of potassium persulfate in 10g of water (divided into two parts according to 4:1), dissolve 1g of acrylamide in 10g of water, and set aside; dissolve 1g of acetamiprid in a mixed monomer of 4g of ethyl acrylate and 7g of butyl acrylate In; 5g OP-40, 4g sodium lauryl sulfate, 4g sodium polymethacrylate are dissolved in 60g water, put into a container with stirring, under stirring, add the mixed monomer that dissolves acetamiprid, Disperse into an emulsion and put it into a reaction vessel. Heat and keep the temperature at 70±2°C, add the first initiator and acrylamide aqueous solution, react for 6 hours, keep warm for 1 hour, and prepare the seed emulsion; add 1g ethyl acrylate, 1g butyl acrylate, 2g 4,4' - diphenylmethane diisocyanate mixed monomer, dropwise for 1 hour, keep warm for 2 hours, cool down; add additives, discharge. The content of acetamiprid in the product was 0.9%.

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PUM

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Abstract

The present invention discloses a water suspended nano acetamiprid capsule preparation prepared via emulsion polymerization process. It has capsule shell of styrene, isocyanate, acrylate and methacrylate copolymer, and core comprising biologically originated pesticide and animal remedy acetamiprid as effective component; contains acetamiprid 0.5-5 wt%, capsule shell 5-30 wt%, additive 10-35 wt% and water in proper proportion. The nano capsule is disersive spherical particle of size smaller than 100 nm. Compared with traditional pesticide preparation forms, the present invention has the features of water based solvent, nano level dispersive effective component, high stability, etc. and may be used in killing animalí»s parasite and various pests of fruit tree, vegetable, flower, cotton, tobacco, etc.

Description

technical field [0001] The invention relates to acetamiprid water-suspended nanocapsules, which belongs to the pesticide preparation technology. Background technique [0002] Acetamiprid is a new generation of ultra-efficient, systemic insecticides that came out in the 1990s, and it belongs to the chlornicotine compound. It has contact and stomach poisoning effects on pests, and its insecticidal mechanism is novel. It can effectively control various pests such as Hemiptera, Lepidoptera, and Coleoptera. It has high activity, small dosage, long-lasting effect, and good quick-acting properties Advantages, especially for pests that have developed severe resistance to organophosphate, carbamate and pyrethroid insecticides. The main dosage form is emulsifiable concentrate. As a traditional dosage form of pesticides, the control effect is acceptable, but there are the following problems: [0003] 1. Contains a large amount of organic solvents, such as toluene, xylene, etc., causi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A01N25/28A01N47/40
Inventor 郑和堂尚青
Owner HEBEI UNIVERSITY OF SCIENCE AND TECHNOLOGY
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