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Low surface energy fluorine carbon antifouling paint

An antifouling coating and low surface energy technology, which is applied in the direction of antifouling/underwater coatings, coatings, paints containing biocides, etc., can solve the problems that cannot be used for long-term antifouling and can only be used for high-speed ships, to prevent Effects of marine bioaccumulation

Inactive Publication Date: 2006-06-28
大连振邦氟涂料股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] An object of the present invention is to provide a non-toxic, non-polluting, long-term anti-fouling coating suitable for various Low surface energy fluorocarbon antifouling coatings with excellent antifouling properties for ships and ships

Method used

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  • Low surface energy fluorine carbon antifouling paint
  • Low surface energy fluorine carbon antifouling paint
  • Low surface energy fluorine carbon antifouling paint

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Embodiment 1: Production of low surface energy fluorocarbon coating

[0036] The weight ratio of A and B components is 13:1, and the formula of A component is as follows:

[0037] Fluorocarbon resin (F-100) 45kg, zinc oxide 7.5kg, titanium dioxide 8kg, antifouling agent 35kg, (including cuprous oxide 27.5kg, SeaNine2117kg, capsaicin 0.5kg), methyl polysiloxane 3kg, BYK -161 0.9kg, BYK-306 0.3kg, BYK-066 0.3kg.

[0038] Group B is DESMODUR  L75;

[0039] Prepare as follows:

[0040] a. According to the formula of component A, add fluororesin, zinc oxide, antifouling agent, pigment and filler, organosilicon compound and a mixed solvent whose weight is 2 / 3 of the total weight of the solvent into the container; disperse at high speed for 2 hours at 2000rpm When the fineness is 50μm, add various additives according to the formula amount, and adjust the viscosity to 60d / s with the remaining mixed solvent, stir well, filter with a 100-mesh filter, and measure and pack.

...

Embodiment 2

[0042] Embodiment 2: Preparation of first component in low surface energy fluorocarbon coating

[0043] The weight ratio of A and B components is 14:1, and the formula of A component is as follows:

[0044]Fluorocarbon resin (F-200) 40kg, zinc oxide 11kg, titanium dioxide 12kg, antifouling agent 32kg (including cuprous oxide 27.5kg, SeaNine2117kg, capsaicin 0.5kg), dimethylpolysiloxane 5kg, BYK- 163 0.9kg, SF-800 0.3kg, SF-707 0.3kg.

[0045] A component is prepared according to the following steps:

[0046] Add fluororesin, zinc oxide, antifouling agent, pigments and fillers, organosilicon compound and a mixed solvent whose weight is 3 / 4 of the total weight of the solvent into the container according to the formula of component A; disperse at high speed for 2 hours at 2000rpm, when the fineness When it is 40μm, add various additives according to the formula amount, and adjust the viscosity to 80d / s with the remaining mixed solvent, stir well, filter with a 120-mesh filter, ...

Embodiment 3

[0047] Embodiment 3: the production of low surface energy fluorocarbon coating

[0048] According to the method described in embodiment 1, low surface energy fluorocarbon paint is produced, and the weight ratio of first and second components is 14: 1, and the formula of first component is as follows:

[0049] Fluorocarbon resin (F-200) 45kg, zinc oxide 13kg, titanium dioxide 10kg, antifouling agent 35kg (including cuprous oxide 25kg, TCPM7kg, SK1100 3kg), BYK-3700 5kg, SF-725 0.9kg, SF-800 0.3kg, SF-707 0.3kg.

[0050] The contact angle of antifouling coating and deionized water measured by OCA20 Dataphysics video contact angle measuring instrument is shown in Table 1. The calculated coating surface energy is shown in Table 2. The contact angle measurement video image of the embodiment coating and deionized water is shown in figure 1 .

[0051] Example

[0052] example

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Abstract

The invention relates to low surface energy fluorine carbon antifouling paint. It belongs to sea antifouling paint field. It is mixed by the first and second component with 12-20:1 weight ratio. The first component is formed the following weight percentage matter: fluorocarbon resin 30-60%, zinc oxide 5-20%, pigment 1-15%, anti-fouling compound 0.1-45%, organic silicon compound 0.1-10%, and auxiliary agent 0.1-2%. The second is aliphatics and aromatic curing agent. The invention mixes the first and second component before painting dressing, then processes room temperature cross linking solidifying to make fluorine carbon paint have low surface energy and high contact angle with water after film forming, and realize synergism anti fouling with antifouling compound to reach the effect of preventing fouling by marine organism.

Description

technical field [0001] The invention relates to a fluorocarbon antifouling paint with low surface energy, which belongs to the field of marine antifouling paint. Background technique [0002] As a special functional protective coating, marine antifouling coatings are used to coat the bottom of ships, marine structures, offshore oil platforms, submarine oil pipelines, etc. to prevent marine organisms from attaching and fouling. [0003] Low surface energy antifouling coatings, the antifouling principle is to develop coatings with unique surface properties, making it difficult for marine organisms to attach to them, even if the adhesion is not firm, the adhesion interface is very weak, and it is easy to fall off under the action of water flow or other external forces. Traditional toxic antifouling coatings generally only have an inhibitory effect on some marine organisms, and with the continuous release of toxic substances, their antifouling effect gradually declines. Low sur...

Claims

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Application Information

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IPC IPC(8): C09D127/12C09D5/16
Inventor 张占平张祖文由继业孙祥山
Owner 大连振邦氟涂料股份有限公司
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