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Nanometer polypropylene modifier and its prepn process

A polypropylene and modifier technology, applied in the field of nano-polypropylene modifier, can solve the problems of increased production cost, single function, large material loss, etc.

Inactive Publication Date: 2006-10-18
南京淳达科技发展有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the biggest technical problem in the modification of plastics is that if the rigidity is increased, the toughness will decrease, and if the toughness is increased, the rigidity will be insufficient. In addition, the main technical indicators such as heat resistance and stretchability are also difficult to improve.
It is difficult to solve the above problems at the same time by adding a modifier
[0006] 2. Single function
To change the properties of polypropylene in many ways, it is necessary to add a variety of modifiers of different brands at the same time, which not only increases the production cost, but also reduces the labor efficiency
[0007] 3. More powder
At present, some brand products are still in powder form, and there are many disadvantages in the production process: for example, the container is easy to hang on the wall when storing materials, easy to raise dust when feeding materials, easy to block when feeding materials, and large material loss, which not only causes pollution, but also affects the health of workers. , also makes the measurement inaccurate, directly affects the product quality and increases the production cost

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] 1. Put each component of the present invention into a cantilever double-helix cone mixer according to the following weight ratio for premixing and extensive dispersion:

[0037] Nano fully vulcanized powder rubber: 40%, antioxidant 168: 15%, antioxidant 1010: 15%, dispersant: 5%, antistatic agent 477: 5%, coupling agent: 10%, calcium stearate 10%.

[0038] The operating speed of the cantilever double-helix cone mixer is: 100-150 revolutions per minute, and the mixing time is 40 minutes.

[0039] 2. After premixing and coarse dispersion, put the raw materials into the horizontal ball mill to refine and disperse the raw materials. The process control speed of the horizontal ball mill is 45-50 revolutions per minute.

[0040] 3. After refining and dispersing, put the raw materials into the twin-screw granulator to extrude and granulate to further strengthen the dispersing. During granulation, the material temperature in the twin-screw granulator is controlled within the...

Embodiment 2

[0042] The component of embodiment 2 and the step of preparation process are identical with embodiment 1, and difference is:

[0043] The weight ratio of each component is: Nano fully vulcanized powder rubber: 45%, antioxidant 168: 10%, antioxidant 1010: 15%, dispersant: 5%, antistatic agent 477: 5%, coupling agent : 10%, calcium stearate 10%.

[0044] Due to the addition of 5% nanometer fully vulcanized powdered rubber, the stirring time of step 1) was increased to 60 minutes.

Embodiment 3

[0046] The component of embodiment 3 and the step of preparation process are identical with embodiment 1, difference is:

[0047] The weight ratio of each component is: Nano fully vulcanized powder rubber: 50%, antioxidant 168: 10%, antioxidant 1010: 10%, dispersant: 5%, antistatic agent 477: 5%, coupling agent : 10%, calcium stearate 10%.

[0048] Due to the addition of 5% nanometer fully vulcanized powdered rubber, the stirring time of step 1) was increased to 80 minutes.

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PUM

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Abstract

The present invention relates to one kind of nanometer polypropylene modifier and its preparation process. The nanometer polypropylene modifier is prepared with nanometer completely vulcanized rubber powder in 40-50 %, antioxidant 168 in 10-15 %, antioxidant 1010 in 10-15 %, dispersant in 3-5 %, antistatic agent in 3-5 %, couplant in 3-5 % and calcium stearate in 3-5 %. The preparation process includes the following steps: 1. dispersing and mixing the components in a stirrer; 2. further dispersing in a ball mill; and 3. extruding to pelletize in an extruder while further dispersing. The nanometer polypropylene modifier as one multifunctional product has functions of strengthening, toughening, resisting heat, etc.

Description

technical field [0001] The invention relates to a nanometer polypropylene modifier. Background technique [0002] my country's plastic production and processing volume ranks second in the world, and its annual demand accounts for 10 percent of the world's total consumption. The actual situation in China is: there are many general-purpose plastics produced, resulting in a surplus of products, while the production of engineering plastics is small, and a large number of imports are required to fill the gap every year. Taking polypropylene as an example, the import in 2000 was 1.62 million tons, and the import in 2004 reached 2.85 million tons. [0003] Strengthening the modification of plastics and increasing the production capacity of engineering plastics is one of the major projects in the petrochemical industry during the 11th Five-Year Plan. The K9015 brand polypropylene produced by domestic petrochemical enterprises is mainly used in the manufacture of automobile bumpers...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08K5/09C08L21/00
Inventor 彭令才
Owner 南京淳达科技发展有限公司
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