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Barrier layer process and arrangement

A device and atomic layer technology, applied in the field of forming a barrier layer and a diffusion barrier layer, can solve the problems of rough surface of polymer, poor compliance, limitation and so on

Inactive Publication Date: 2007-02-21
EDWARDS VACUUM INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The most notable problem is that the polymer has a rough surface, and the film deposited by PECVD by thermal evaporation has poor compliance to the surface undulations of the plastic substrate.
For example, the average surface roughness of commonly available polyethylene terephthalate (PET) is 8-12 root mean square (rms), where The achieved barrier properties are limited by the coverage of the surface plastic by the inorganic barrier material

Method used

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  • Barrier layer process and arrangement

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Embodiment

[0023] A 12 micron thick PET substrate is unrolled from a roll into a cylinder within the processing chamber. The cylinder in the processing chamber is heated to 75°C. The PET substrate was exposed to a first ALD source that deposited trimethylaluminum, and then the substrate was exposed to an ALD source of oxygen or nitrous oxide at a process pressure of 100 mTorr. The PET substrate is sequentially and repeatedly exposed to a source of deposited trimethylaluminum, followed by a source of oxygen or nitrous oxide. This can be done by winding the substrate on a drum and unwinding, exposing the substrate to the same source, or providing multiple sources. The corresponding film thickness for 100 passes through the ALD source is about 120 . Preferably, substrates coated according to the invention have an oxygen permeability of less than 0.1 cm 3 / rice 2 / day, preferably less than 0.010 cm 3 / rice 2 / day, most preferably 0.001 cm 3 / rice 2 / day, its water vapor transmissio...

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Abstract

A method an apparatus is described using atomic layer deposition to form a barrier layer onto a substrate. The coated substrate exhibits reduced permeation to oxygen and water vapor.

Description

Background of the invention [0001] The present invention relates to arrangements and methods for forming barrier layers on substrates to form diffusion barriers for oxygen and water vapor. More specifically, the present invention provides an apparatus and method in which a barrier layer is formed on a plastic substrate using atomic layer deposition. The resulting barrier will more closely conform to the substrate surface and reduce pinhole leakage and cracking. [0002] Food and pharmaceutical packaging often require low diffusion rates, especially for oxygen and water vapor. Glass packaging such as glass jars, airtight glass bottles have sufficiently low oxygen and water vapor transmission rates. Unfortunately, glass-based packaging is expensive. Despite the lower cost of polymer-based packaging, most polymer films of a thickness effective for packaging applications have undesirably high oxygen and water vapor permeability. Lower gas permeation rates can be achieved by la...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C16/00C23C16/40C23C16/455C23C16/54
CPCC23C16/45525C23C16/45551C23C16/545H01L51/5237C23C16/403C23C16/45555H10K50/844
Inventor F·简森
Owner EDWARDS VACUUM INC
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