Optical media, read inhibiting agents and methods of making and using same
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example 1
[0138] injection-molded 0.62 mm polycarbonate substrate with reverse-mastered DVD5* data features; sputter coated with a fully reflective metallic (aluminum) film: nominally 60 nm thick
[0139] oxygen-active adhesive material: TipSOC chemistry, rapid kinetics—nominally 10 hour total deblocked life in limited-play DVD without diffusion barrier: nominally 50 □m thick
[0140] injection-molded 0.56 mm polycarbonate featureless (mirror) substrate; sputter coated with 2 nm aluminum-oxide film (internal surface)
[0141] acrylate edge-coating to reduce disc-edge diffusion rates, allowing bulk oxygen diffusion to dominate
[0142] The sputter coated thin film of aluminum-oxide provides a significant barrier to oxygen diffusion. Oxygen permeation rates to the oxygen-active adhesive are limited by grain-boundary diffusion through the sputter coated aluminum-oxide thin film. For room-temperature diffusion processes, grain boundary diffusion rates are several orders of magnitude faster than bulk diff...
example a
[0145] injection-molded 0.62 mm polycarbonate substrate with reverse-mastered DVD5* data features; sputter coated with a fully reflective metallic (aluminum) film: nominally 60 nm thick
[0146] oxygen-active adhesive material: TipSOC chemistry, normal kinetics—nominally 30 hour total deblocked life in limited-play DVD without diffusion barrier: nominally 50 □m thick
[0147] injection-molded 0.56 mm polycarbonate featureless (mirror) substrate; sputter coated with 2 nm aluminum-oxide film (internal surface), i.d. sputtering mask 48.0 mm diameter
example b
[0148] injection-molded 0.62 mm polycarbonate substrate with reverse-mastered DVD5* data features; sputter coated with a fully reflective metallic (aluminum) film: nominally 60 nm thick
[0149] oxygen-active adhesive material: TipSOC chemistry, rapid kinetics—nominally 10 hour total deblocked life in limited-play DVD without diffusion barrier: nominally 50 □m thick
[0150] injection-molded 0.56 mm polycarbonate featureless (mirror) substrate; sputter coated with 2 nm aluminum-oxide film (internal surface)—i.d. sputtering mask at 30.0 mm diameter; secondary sputter coating, nominal 2 nm aluminum-oxide film—i.d. sputtering mask at 48.0 mm diameter
Authoring
[0151] A limited play optical device becomes unreadable over time (e.g., 1-5 days), typically following some stimulus, such as exposure to oxygen. In embodiments of the present invention, The optical device is designed and authored, or the reading device is programmed, so that the reading device to read from a desired region before ...
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