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Optical glass for precision press molding, preform for precission press molding, and process for the production thereof

a technology of precision press molding and optical glass, which is applied in the field of optical glass for precision press molding, can solve the problems of poor suitability for press molding, and achieve the effect of softening the preform

Inactive Publication Date: 2006-10-19
HOYA CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0010] Under the circumstances, it is an object of the present invention to provide a high-refractivity low-dispersion optical glass which does not require machining of an optical-function surface, such as polishing or lapping, after precision press molding thereof and which is used for producing an optical element, a precision press molding preform made of the above optical glass, an optical element made of the above glass, and processes for the production of the above preform and the above optical element.

Problems solved by technology

However, the above optical glasses aim at an improvement in devitrification resistance, and there is therefore involved a problem that expensive components such as Lu2O3, etc., are essential, or that a large amount of Sb2O3 that is a harmful component is essentially incorporated, for improving such optical glasses in stability.
Further, of glass compositions disclosed in the above Publications, compositions that can attain a refractive index nd>1.8 and an Abbe's number νd>35 very useful for optical designing contain almost no ZnO or Li2O that is said to be effective for decreasing the glass transition temperature, so that they have poor suitability to press molding.
Generally, a glass having such optical constants has a large content of rare earth metal oxide component and has a low degree of stabilization against devitrification, so that it has been difficult to develop a composition that makes it possible to decrease the glass transition temperature to a region in which the glass can be press molded economically.

Method used

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  • Optical glass for precision press molding, preform for precission press molding, and process for the production thereof
  • Optical glass for precision press molding, preform for precission press molding, and process for the production thereof
  • Optical glass for precision press molding, preform for precission press molding, and process for the production thereof

Examples

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examples

[0085] The present invention will be explained more specifically with reference to Examples hereinafter, while the present invention shall not be limited to these Examples.

examples 1-64

[0086] Oxides, carbonates, sulfates, nitrates, hydroxides, etc., such as SiO2, H3BO3, La2O3, ZnO, ZnCO3, ZrO2, Li2CO3, etc., as raw materials were provided, and 250 to 300 g of each of these components was weighed so as to form compositions shown in Tables 1 to 7. These raw materials in each Example were fully mixed to prepare a formulated batch, the formulated batch was placed in a platinum crucible, and the formulated batch was melted in air in an electric furnace maintained at 1,200 to 1,450° C., with stirring for 2 to 4 hours. After melted, the glass melt was allowed to flow into a 40×70×15 mm mold made of carbon and allowed to cool to a glass transition temperature, and immediately thereafter, the glass was placed in an annealing furnace and annealed in a glass transition temperature range for about 1 hour. Then, the glass in the furnace was allowed to cool to room temperature, to give an optical glass. In the thus-obtained optical glasses, there was precipitated no crystal tha...

example 65

[0102] Precision press molding preforms were produced from the optical glasses obtained in Examples 1 to 64 as follows. First, melting, refining and homogenization were carried out to obtain a molten glass that was to give one of the above optical glasses, the molten glass was dripped from a flow nozzle made of a platinum alloy toward a receiving member, and in a concave portion of the receiving member, the received molten glass drop was floated and rolled while a gas was ejected upward from a gas ejection port formed in a bottom of the concave portion, to shape the molten glass into a preform (Method 1). The thus-formed preforms from the above optical glasses had a weight equivalent to the weight of an intended end product, underwent no devitrification and had a smooth surface free of defects such as a flaw, soiling and alteration.

[0103] Separately, the same molten glass drop as above was dropped from the flow nozzle in the same manner as above into liquid nitrogen and shaped into...

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Abstract

A high-refractivity high-dispersion optical glass for producing an optical element, which requires no machining, such as polishing or lapping, of an optical-function surface after precision press molding, containing B2O3, SiO2, La2O3, Gd2O3, ZnO, Li2O, ZrO2 and Ta2O5 as essential components, containing 0 to 1 mol % of Sb2O3 as an optional component, substantially containing none of PbO and Lu2O3, having a glass transition temperature of 630° C. or lower, and (1) having a refractive index nd and an Abbe's number νd which satisfy all of the following relational expressions, 1.80<nd≦1.90, 35≦νd≦50, and nd≧2.025−(0.005×νd) or (2) having an nd of greater than 1.85 and a νd of greater than 35.

Description

TECHNICAL BACKGROUND [0001] 1. Field of the Invention [0002] The present invention relates to an optical glass for precision press molding, a preform for precision press molding, an optical element, and processes for the production of the preform and the optical element. More specifically, the present invention relates to a high-refractivity low-dispersion optical glass which does not require machining of an optical-function surface such as polishing or lapping after precision press molding thereof and which is used for producing an optical element such as an ultra-precision aspherical lens, a precision press molding preform made of the optical glass, an optical element made of the same, and processes for the production of the above preform and optical element. [0003] 2. Prior Art [0004] In recent years, digital cameras have appeared, and as the integration and function of machines and devices using an optical system are rapidly enhanced, it is increasingly demanded to enhance the p...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C03C3/068C03B11/00C03B7/00B29C43/02B29C43/36G02B1/00C03B11/08
CPCB29C43/021B29C43/361B29C2043/3618B29L2011/0016C03B11/005C03C3/068C03B11/084C03B2215/07C03B2215/66C03B2215/72C03B11/08
Inventor HAYASHI, KAZUTAKAZOU, XUELU
Owner HOYA CORP
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