Optical glass for precision press molding, preform for precission press molding, and process for the production thereof
a technology of precision press molding and optical glass, which is applied in the field of optical glass for precision press molding, can solve the problems of poor suitability for press molding, and achieve the effect of softening the preform
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[0085] The present invention will be explained more specifically with reference to Examples hereinafter, while the present invention shall not be limited to these Examples.
examples 1-64
[0086] Oxides, carbonates, sulfates, nitrates, hydroxides, etc., such as SiO2, H3BO3, La2O3, ZnO, ZnCO3, ZrO2, Li2CO3, etc., as raw materials were provided, and 250 to 300 g of each of these components was weighed so as to form compositions shown in Tables 1 to 7. These raw materials in each Example were fully mixed to prepare a formulated batch, the formulated batch was placed in a platinum crucible, and the formulated batch was melted in air in an electric furnace maintained at 1,200 to 1,450° C., with stirring for 2 to 4 hours. After melted, the glass melt was allowed to flow into a 40×70×15 mm mold made of carbon and allowed to cool to a glass transition temperature, and immediately thereafter, the glass was placed in an annealing furnace and annealed in a glass transition temperature range for about 1 hour. Then, the glass in the furnace was allowed to cool to room temperature, to give an optical glass. In the thus-obtained optical glasses, there was precipitated no crystal tha...
example 65
[0102] Precision press molding preforms were produced from the optical glasses obtained in Examples 1 to 64 as follows. First, melting, refining and homogenization were carried out to obtain a molten glass that was to give one of the above optical glasses, the molten glass was dripped from a flow nozzle made of a platinum alloy toward a receiving member, and in a concave portion of the receiving member, the received molten glass drop was floated and rolled while a gas was ejected upward from a gas ejection port formed in a bottom of the concave portion, to shape the molten glass into a preform (Method 1). The thus-formed preforms from the above optical glasses had a weight equivalent to the weight of an intended end product, underwent no devitrification and had a smooth surface free of defects such as a flaw, soiling and alteration.
[0103] Separately, the same molten glass drop as above was dropped from the flow nozzle in the same manner as above into liquid nitrogen and shaped into...
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