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High-temperature, spin-on, bonding compositions for temporary wafer bonding using sliding approach

a technology of bonding compositions and wafers, applied in the direction of layered products, transportation and packaging, chemistry apparatuses and processes, etc., can solve the problems of increasing capacitance, requiring thicker transmission lines, and large ic footprin

Inactive Publication Date: 2008-08-21
BREWER SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Thick substrates cause an increase in capacitance, requiring thicker transmission lines, and, in turn, a larger IC footprint.
This requires longer dry-etch times and produces larger quantities of post-etch residue, thus significantly reducing throughput.
Larger vias also require larger quantities of metallization, which is more costly.
When wafer thickness is reduced to less than 300 μm, it becomes difficult or impossible to maintain control with regard to attachment and handling of the wafer during further thinning and processing.
In some cases, mechanical devices may be made to attach and hold onto thinned wafers, however, they are subject to many problems, especially when processes may vary.
The major drawback with this approach is that the composition must be chemically removed, typically by dissolving in a solvent.
This is very time-consuming, thus reducing throughput.
Furthermore, the use of the solvent adds to the cost and complexity of the process, and it can be hazardous, depending upon the solvent required to dissolve the bonding composition.
First, the tapes have limited thickness uniformity across the active wafer / carrier substrate interface, and this limited uniformity is often inadequate for ultra-thin wafer handling.
Second, the thermal release adhesive softens at such low temperatures that the bonded wafer / carrier substrate stack cannot withstand many typical wafer processing steps that are carried out at higher temperatures.

Method used

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  • High-temperature, spin-on, bonding compositions for temporary wafer bonding using sliding approach
  • High-temperature, spin-on, bonding compositions for temporary wafer bonding using sliding approach
  • High-temperature, spin-on, bonding compositions for temporary wafer bonding using sliding approach

Examples

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Effect test

example 1

[0056]Formulations were made by dissolving various cellulose derivatives (obtained from Eastman Chemical Company, Kingsport, Tenn.) in appropriate solvents. The exact materials and quantities used are reported in Table I.

TABLE IBonding Composition Formulations from Cellulose Materials.SAMPLESAMPLESAMPLESAMPLE1.11.21.31.4INGREDIENTS(g)(g)(g)(g)Cellulose acetate (29.5%)20000butyrate (17%)Cellulose acetate01800trimelliateCellulose acetate (2%)00250butyrate (52%)Cellulose acetate (18.5%)00025butyrate (31%)Propylene glycol08200monomethyl etherMethyl isoamyl ketone5007550Ethyl acetoacetate300025

example 2

Cycloolefin Resin and Poly(α-Pinene) Blend

[0057]Formulations were made by dissolving Zeonex 480R resin (obtained from Zeon Chemicals, Louisville, Ky.) and / or poly(α-pinene) (obtained from Aldrich, Milwaukee, Wis.) and / or poly(β-pinene) (obtained from Aldrich, Milwaukee, Wis.) in D-limonene (obtained from Florida Chemical Company). Bis(trimethoxysilylethyl)benzene (obtained from Aldrich, Milwaukee, Wis.) was added as an adhesion promoter. The exact compositions of the formulations are reported in Table II.

TABLE IIBonding Composition Formulations from Poly(cycloolefin)and Pinene Materials.SAMPLESAMPLESAMPLESAMPLE2.12.22.32.4INGREDIENTS(g)(g)(g)(g)Zeonex 480R12055.946.0520Poly(α-pinene)014.330.70Poly(β-pinene)0005D-limonene280144.8138.1574.875Bis(trimethoxysilyl-0.50.2680.2680.125ethyl)benzene

example 3

Cycloolefin Resin and Rosin Ester Blend

[0058]The formulations were made by dissolving Zeonex 480R resin and Eastotac H142W (obtained from Eastman Chemicals, Kingsport, Tenn.) in a suitable solvent. Irganox 1010 and Irgafos 168 (obtained from Ciba Specialty Chemicals, Tarrytown, N.Y.) were added to one of the formulations to prevent thermal oxidation at high temperatures. Triton X-100 (obtained from Aldrich, Milwaukee, Wis.) was added to reduce de-wetting problems, and bis(trimethoxysilylethyl)benzene was added to promote adhesion. The exact compositions of the formulations are reported in Table M.

TABLE IIIBonding Composition Formulations Based onPoly(cycloolefin) and Rosin Ester Blends.SAMPLESAMPLESAMPLESAMPLE3.13.23.33.4INGREDIENTS(g)(g)(g)(g)Zeonex 480R35 g740Eastotac H142W753160D-limonene12303060Mesitylene000140Irganox 10100002Irgafos 1680001Triton X-1000001Bis(trimethoxysilyl-0001ethyl)benzene

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PUM

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Abstract

New compositions and methods of using those compositions as bonding compositions are provided. The compositions comprise a polymer dispersed or dissolved in a solvent system, and can be used to bond an active wafer to a carrier wafer or substrate to assist in protecting the active wafer and its active sites during subsequent processing and handling. The compositions form bonding layers that are chemically and thermally resistant, but that can also be softened to allow the wafers to slide apart at the appropriate stage in the fabrication process.

Description

RELATED APPLICATIONS[0001]This application also claims the priority benefit of U.S. Provisional Patent Application No. 60 / 828,572, entitled HIGH-TEMPERATURE SPIN-ON ADHESIVES FOR TEMPORARY WAFER BONDING USING SLIDING APPROACH, filed Oct. 6, 2006, the entire disclosure of which is incorporated by reference herein.GOVERNMENT FUNDING[0002]This invention was made with government support under contract number W911 SR-05-C-0019 awarded by the United States Army Research, Development, and Engineering Command. The United States Government has certain rights in the invention.BACKGROUND OF THE INVENTION[0003]1. Field of the Invention[0004]The present invention is broadly concerned with novel compositions and methods of using those compositions to form bonding compositions that can support active wafers on a carrier wafer or substrate during wafer thinning and other processing.[0005]2. Description of the Prior Art[0006]Wafer (substrate) thinning has been used to dissipate heat and aid in the e...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): H01L21/30
CPCH01L21/6835H01L2221/68327H01L2221/6834Y10T156/1168Y10T156/1153Y10T156/1189H01L2924/30105Y10T156/11Y10T156/19Y10T156/1972Y10T428/31678H01L21/302H01L21/304H01L21/52B29B17/02B32B38/10B32B43/006C09J2301/502
Inventor PILLALAMARRI, SUNIL K.LI, CHENGHONG
Owner BREWER SCI
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