Powder-Metallurgically Produced, Wear-Resistant Material

Abstract

A wear-resistant material comprising an alloy that contains: 1.5-5.5 wt. % carbon, 0.1-2.0 wt. % silicon, max. 2.0 wt. % manganese, 3.5-30.0 wt. % chromium, 0.3-10 wt. % molybdenum, 0-10 wt. % tungsten, 0.1-30 wt. % vanadium, 0-12 wt. % niobium, 0.1-12 wt. % titanium and 1.3-3.5 wt. % nickel, the remainder being comprised of iron and production-related impurities, whereby the carbon content fulfils the following condition:CAlloy [w %]=S1+S2+S3where S1=(Nb+2(Ti+V−0.9)) / a, S2=(Mo+W / 2+Cr−b) / 5, S3=c+(TH−900)·0.0025, where 7<a<9, 6<b<8, 0.3<c<0.5 and 900° C.<TH<1,220° C.Also. method for producing the wear-resistant material and to uses of the material.

Description

CROSS-REFERENCE TO RELATED APPLICATION[0001]The present application claims the benefit of priority of International Patent Application No. PCT / EP2006 / 004086 filed on May 2, 2006, which application claims priority of German Patent Application No. 10 2005 020 081.8 filed Apr. 29, 2005. The entire text of the priority application is incorporated herein by reference in its entirety.FIELD OF THE DISCLOSURE[0002]The disclosure relates to a powder-metallurgically produced, wear-resistant material from an alloy, as well as to a method for producing the material, the use of said material and a powder material.BACKGROUND[0003]Wear-resistant alloys on the basis of iron are widely used. In this connection, the resistance to wear is achieved from the hardness of the martensitic metal matrix and the content of hard carbides, nitrides or borides of the elements chromium, tungsten, molybdenum, vanadium, niobium or titanium. This group includes cold work steel and high-speed tool steels, as well as ...

AI Technical Summary

Benefits of technology

[0011]The alloy content in the metal matrix is decisive for achieving the martensitic structure even in the event of slow cooling. In principle, all alloy elements that are dissolved in the metal matrix and that shift the “perlite notch” to the right in the time-temperature transformation diagram (TTT diagram) shown in the following have a favorable effect. In addition to carbon, this includes the elements chromium, molybdenum and vanadium, but particularly nickel, which is used in the alloys according to the disclosure for this reason. Although the austenite-stabilizing effect of nickel is known, it has not been used to any appreciable degree in the PM alloys known until now. The regulation of a desired nickel content in the metal matrix is relatively simple, because nickel does not participate in the carbide formation necessary for a high level of wear-resistance. Because of the presence of the carbides deposited from the melt, the nickel content is somewhat higher in the matrix than in the alloy. The nickel content primarily acts in the metal matrix and increases the austenite range as the content increases. It can be assumed that the nickel content in the metal matrix per volume percent of carbide lies above the content of nickel in the alloy by 0.025 wt %. The austenite-stabilizing effect of the nickel makes it possible to convert the alloys into the hard, wear-resistant martensite, even in the case of very slow cooling.

[0013]The summand S3 represents a portion of carbon that can be dissolved, if there is sufficient molybdenum content in the alloy, by means of the selection of the austenitizing temperature in the metal matrix. As the hardening temperature increases, more molybdenum-containing carbides are dissolved. As a result, the austenite becomes richer in molybdenum and carbon, which expand the austenite range and consequently increase the critical cooling rate.

[0016]The material according to the disclosure can be economically hardened by known measures, whereby even thick-walled components are through-hardened without increased costs.

[0022]According to a further preferred embodiment, the alloy can additionally have 0.3 to 3.5 wt. % N. In some applications, the addition of nitrogen has proven advantageous.

[0045]The powder can advantageously be used as a semi-finished product. One result of this is to make it possible for a buyer to convert the semi-finished product into the desired end form.

Problems solved by technology

A multitude of powder compositions for wear-resistant materials are known, but these generally are not sufficient for thick-walled composite parts as far as their through-hardening characteristics are concerned.

This leads to the development of the problem of insufficient hardening for the heat treatment of the larger-walled composite parts after the HIP step.

The steel powders known today are not suitable for this purpose, because they have been optimised for semi-finished products and workpieces with smaller wall thicknesses.

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