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Polycrystalline diamond

a technology of polycrystalline diamonds and diamonds, applied in the field of polycrystalline diamonds, can solve the problems of diamond grains falling off, tool breaks or cracks, and uneven wear, and achieve the effect of stable cutting width and stable working

Inactive Publication Date: 2010-06-17
SUMITOMO ELECTRIC IND LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The present invention provides a polycrystalline diamond that can be used in various applications such as water jet orifice, stylus for gravure printing, scriber, diamond cutting tool, and scribing wheel. Compared to conventional tools, the polycrystalline diamond provides stability for a long period of time. Additionally, the invention provides a water jet orifice that provides a cutting width with stability for a long period of time, a stylus for gravure printing, a scriber, a diamond cutting tool, and a scribing wheel that enable stable working for a long period of time.

Problems solved by technology

However, such monocrystalline diamond also has a property that abrasion losses vary (uneven wear) depending on crystal orientations of the diamond.
For this reason, monocrystalline diamond applied to such tools described above is worn away only in a specific plane in a short time as the tools are used, and predetermined effects are not provided, which has been a problem.
For this reason, when monocrystalline diamond is applied to a tool subjected to a stress during use, the tool breaks or cracks, which also has been a problem.
As the amount of the binder decreases, the diamond grains come off and the effects are not provided with stability for a long period of time.
There is also a problem in that adhesive wear occurs between the metal binder region and a metal material being worked and working for a long period of time cannot be performed.
However, removal of a metal binder reduces the binding power of diamond grains, which most likely increases abrasion loss.
However, this polycrystalline diamond has a small binding strength among grains and hence suffers from large abrasion loss, which has been a problem.
A water jet orifice including monocrystalline diamond has a problem in that a target cutting width is no longer achieved after the lapse of usage time.
The orifice having the shape of a cylinder at the initial stage of use suffers from abrasion in a plane susceptible to abrasion in a short time.
Thus, a cutting width is not provided with stability for a long period of time, which is a problem.
As a result, a metal binder region, which is softer than diamond grains, wears away in a short time and a cutting width is not provided with stability for a long period of time, which is a problem.
However, such a diamond thin film has a short wear life, and has a small binding strength among grains and hence has a short wear life, which has been a problem.
However, possibly because such diamond has a property of cleaving, such a tool breaks or cracks by a stress during use, which is a problem.
Due to the property of uneven wear, such diamond is worn away only in a specific plane in a short time as the tool is used, and hence working for a long period of time cannot be performed, which has also been a problem.
However, possibly because monocrystalline diamond has a property of cleaving along the (111) plane as described above, scribers composed of monocrystalline diamond crack or wear unevenly when a plane used for scribing only slightly deviates from the (111) plane, which has been a problem.
However, because of the problems of the cleaving property and the property of uneven wear of monocrystalline diamond as described above, such a tool composed of monocrystalline diamond has a problem in that the tool breaks or cracks due to a stress during use, is worn away only in a specific plane in a short time as the tool is used, and working for a long period of time cannot be performed.
However, as with other tools, such a scribing wheel breaks or cracks due to a stress during use because of the problem of the cleaving property of monocrystalline diamond, which has been a problem.
Due to the property of uneven wear, such a tool is worn away only in a specific plane in a short time as the tool is used, and use of the tool for a long period of time is not possible, which has been a problem.
As a result, the wheel becomes no longer able to roll, which has been a problem.
However, even though sintered diamond is used, the following problems are likely to occur: a metal binder region containing cobalt or the like is softer than diamond grains and hence wears away in a short time, and adhesive wear occurs between the metal binder region and a metal material being worked such as copper and working for a long period of time cannot be performed.
However, this reduces the binding power of diamond grains, which most likely increases abrasion loss.
Polycrystalline diamond that is produced by CVD and is free from a metal binder has a small binding strength among grains and hence probably has a problem in that such diamond has a short wear life.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

Water Jet Orifice

[0126]Examples of orifices according to embodiments of the present invention are described below.

[0127]Examples 1-1 to 1-3 are examples in which surface roughness was varied. Examples 1-4 to 1-6 are examples in which orifice bore diameter was varied. Examples 1-7 to 1-12 are examples in which average grain diameter and D90 grain diameter were varied. Examples 1-13 and 1-14 are examples in which both average grain diameter and orifice bore diameter were increased.

example 1-1

[0128]Graphite having an average grain diameter of 100 nm and a D90 grain diameter of 180 nm, which is (average grain diameter+0.9×average grain diameter) or less, was prepared as non-diamond carbon serving as the material of diamond. This material was directly converted and sintered into diamond under a pressure condition under which diamond is thermodynamically stable. As a result, a polycrystalline diamond having an average grain diameter of 200 nm and a D90 grain diameter of 370 nm was obtained. The thus-obtained polycrystalline diamond had an extremely high hardness of 110 GPa. An orifice was produced from this polycrystalline material, the orifice having an orifice bore diameter of 200 μm, an orifice level of 5 mm, and a surface roughness Ra of 290 nm in the surface of the orifice bore. This orifice was evaluated for a water jet cutting property. The cutting time over which the orifice diameter was expanded to 300 μm was determined and it was a long time of 160 hours. For comp...

example 1-2

[0129]Graphite having an average grain diameter of 100 nm and a D90 grain diameter of 180 nm, which is (average grain diameter+0.9×average grain diameter) or less, was prepared as non-diamond carbon serving as the material of diamond. This material was directly converted and sintered into diamond under a pressure condition under which diamond is thermodynamically stable. As a result, a polycrystalline diamond having an average grain diameter of 200 nm and a D90 grain diameter of 370 nm was obtained. The thus-obtained polycrystalline diamond had an extremely high hardness of 110 GPa. An orifice was produced from this polycrystalline material, the orifice having an orifice bore diameter of 200 μm, an orifice level of 5 mm, and a surface roughness Ra of 50 nm in the surface of the orifice bore. This orifice was evaluated for a water jet cutting property. The cutting time over which the orifice diameter was expanded to 300 μm was determined and it was a long time of 240 hours. For compa...

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Abstract

An object is to provide polycrystalline diamond applicable to diverse applications; and a water jet orifice, a stylus for gravure printing, a scriber, a diamond cutting tool, and a scribing wheel that include such polycrystalline diamond. This object is achieved by polycrystalline diamond obtained by converting and sintering non-diamond carbon under an ultrahigh pressure and at a high temperature without addition of a sintering aid or a catalyst, wherein sintered diamond grains constituting the polycrystalline diamond have an average grain diameter of more than 50 nm and less than 2500 nm and a purity of 99% or more, and the diamond has a D90 grain diameter of (average grain diameter+average grain diameter×0.9) or less.

Description

TECHNICAL FIELD [0001]The present invention relates to polycrystalline diamond obtained by converting and sintering non-diamond carbon without addition of a sintering aid or a catalyst.BACKGROUND ART [0002]Natural and artificial monocrystalline diamonds have been used for various applications because of their excellent properties. A tool including monocrystalline diamond is, for example, a water jet orifice (Patent Document 1), a stylus for gravure printing (Patent Documents 2 and 3), a scriber (Patent Document 4), a diamond cutting tool (Patent Documents 5 and 6), or a scribing wheel (Patent Document 7).[0003]However, such monocrystalline diamond also has a property that abrasion losses vary (uneven wear) depending on crystal orientations of the diamond. For example, abrasion loss considerably varies between the (111) plane and the (100) plane. For this reason, monocrystalline diamond applied to such tools described above is worn away only in a specific plane in a short time as the...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C01B31/06B05B1/02B24B7/00B24B5/00B05B1/00
CPCB26F3/004Y10T428/268C01B31/06C03B33/107C04B35/528C04B35/645C04B2235/425C04B2235/5427C04B2235/5436C04B2235/5445C04B2235/5454C04B2235/5481C04B2235/72C04B2235/781C04B2235/785Y10T428/218B82Y30/00C01B32/25C01B32/26B01J3/06
Inventor SATO, TAKESHIYAMAMOTO, KATSUKOTODA, NAOHIROSUMIYA, HITOSHIKOBAYASHI, YUTAKA
Owner SUMITOMO ELECTRIC IND LTD
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