Atmospheric-pressure plasma processing method

a plasma processing and atmospheric pressure technology, applied in the direction of liquid/gas/vapor textile treatment, manufacturing tools, textile treatment, etc., can solve the problems of limited plasma treatment of commercially important substrates, complicated and prohibitively expensive treatment of these substrates using vacuum-based plasmas, and limited power density that a dbd discharge can achieve. achieve the effect of reducing the distance and fast plasma processing speed

Inactive Publication Date: 2016-12-01
APJET INC
View PDF7 Cites 5 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0010]Accordingly, it is an object of embodiments of the present invention to provide an atmospheric-pressure plasma processing apparatus effective for producing a large area, temperature-controlled, stable plasma discharge, wherein active species generated in the plasma exit the discharge and impinge unimpeded on a material to be processed disposed outside of the discharge, but in close proximity thereto.
[0011]Another object of embodiments of the present invention is to provide an atmospheric-pressure plasma generating apparatus for producing active chemical species, wherein the plasma electrodes are cooled, thereby producing a neutral gas temperature that can be controlled.
[0012]Yet another object of embodiments of the present invention is to provide an atmospheric-pressure plasma generating apparatus effective for producing active chemical species, including gas metastables, ionic species and active physical components.
[0018]Benefits and advantages of the present invention include, but are not limited to, faster plasma processing speed resulting from an unobstructed path and a minimum distance for the excited species formed in the plasma to the material being processed. The lower neutral gas temperature, and the location of the material to be processed away from the electrical influence of the plasma, permit heat-sensitive substrates to be treated and heat-sensitive processes to be employed.

Problems solved by technology

Treatment of these substrates using vacuum-based plasmas would be complicated and prohibitively expensive.
The present state of the art for plasmas operating at or near atmospheric pressure also limits the use of plasma for treatment of these commercially-important substrates.
However, since electrical power must be transmitted through the dielectric cover, the power density that a DBD discharge can achieve is limited.
Low power density typically produces slow processing, because low-power density in the plasma also results in a slow generation rate of the active, chemical species responsible for materials processing.
Further, the metal screens cannot be water-cooled, leading to a high, neutral gas temperature (>150° C.
), especially if high rf power is used since heat removal is limited to conduction at the point of contact with the housing, and from the heat capacity of the gas as it exits the plasma.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Atmospheric-pressure plasma processing method
  • Atmospheric-pressure plasma processing method
  • Atmospheric-pressure plasma processing method

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0041]In the following EXAMPLE 1, use of the embodiment of the present invention illustrated in FIG. 3, hereof, with two powered plasma regions (13.56 MHz), for processing fabrics is described. Clearly, many substrates may be treated by embodiments of the present apparatus. A monomer, which is polymerized by the action of free radicals, such as an acrylate, is applied to the fabric by spraying, as an example. The monomer may have various functional groups suitable for imparting desired properties to the fabric including repellency, wicking, antimicrobial activity, flame retardancy, as examples. After application to the fabric, the treated portion is moved into the vicinity of plasma regions 50a-50d such that excited species therefrom impinge thereon. The monomer is cured as the treated fabric is exposed to the plasma products, forming thereby a polymeric material which adheres to the fabrics. As an example, the hydrocarbon portions of polymerized 2-(Perfluorohexyl) ethyl acrylate (c...

example 2

[0044]When the plasma gas is exposed to sufficient electric field from the electrode, active species generation occurs. Electrode heights investigated range from 1″ to ¼″. The thinner electrodes have smaller plasma volume, and hence require less RF power to maintain the plasma at a constant power density; therefore, RF power can be saved and smaller power generators can be used. Since the process results remain the same, there is an observed improvement in the YPM / kW metric. FIG. 8 is a graph of the power required in Watts at 13.56 MHz for achieving a score of 100 using the AATCC TM 22 water repellency spray test for undyed polyester poplin as a function of electrode height, for 0.25 in, 0.5 in, and 1 in. The fabric speed was 5 Yd / min., the process gas dose was 90L / Yd2 of He / N2 gas blend, the power density was 16 W / cm3 in each of 4 plasma regions (5 electrodes), the tube porosity was 53%, the electrode length was 12″, the electrode gap was 2 mm, and the electrodes to fabric spacing ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
heightaaaaaaaaaa
heightaaaaaaaaaa
distanceaaaaaaaaaa
Login to view more

Abstract

Methods for atmospheric pressure plasma discharge processing using powered electrodes having elongated planar surfaces; grounded electrodes having elongated planar surfaces parallel to and coextensive with the elongated surfaces of the powered electrodes, and spaced-apart a chosen distance therefrom, forming plasma regions, are described. RF power is provided to the at least one powered electrode, both powered and grounded electrodes may be cooled, and a plasma gas is flowed through the plasma regions at atmospheric pressure; whereby a plasma is formed in the plasma regions. The material to be processed may be moved into close proximity to the exit of the plasma gas from the plasma regions perpendicular to the gas flow, and perpendicular to the elongated electrode dimensions, whereby excited species generated in the plasma exit the plasma regions and impinge unimpeded onto the material.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS[0001]The present application claims the benefit of U.S. Provisional Patent Application No. 61 / 702,919 for “Atmospheric-Pressure Plasma Processing Apparatus And Method” which was filed on Sep. 19, 2012, and is a divisional of patent application Ser. No. 13 / 826,089 for “Atmospheric-Pressure Plasma Processing Apparatus And Method which was filed on Mar. 14, 2013, the entire contents of which applications are hereby specifically incorporated by reference herein for all that they disclose and teach.FIELD OF THE INVENTION[0002]The present invention relates generally to apparatus and method for plasma processing of materials and, more particularly, to an atmospheric-pressure plasma processing apparatus capable of producing a stable discharge having a neutral gas temperature that can be controlled using a cooling system, for generation of active chemical species including gas metastable and radical species effective for large area plasma processing, w...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(United States)
IPC IPC(8): D06B19/00D06B1/02
CPCD06B19/007D10B2401/021D06B1/02H05H1/46H05H2240/10H05H1/466H05H2245/40B23K10/003
Inventor CORNELIUS, CARRIE E.ROCHE, GREGORY A.TYNER, DAVID W.
Owner APJET INC
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products