Non-halogenous insulated wire and a wiring harness

Abstract

A non-halogenous insulated wire [possessing sufficient flame retardancy and excellent heat resistance, wear resistance and flexibility, ]and a wiring harness including the wire. The wire includes a conductor, an inside coat of one or more layers and an outermost coat, wherein the outermost coat is in the range of 10 to 100 μm in thickness and is made from a resin composition including an olefin resin with a melting point of 180 ° C. or more and / or an olefin resin having a —Si(XI) (X 2) (X 3) group, by 20 wt% or more, and at least one of the layers of the inside coat is made from a resin composition including (A) an olefin resin with a melting point of 180 ° C. or more by 50-5 to part weight, (B) an olefin resin by 50 to 95 part weight, and (C) a metallic hydrate by 30 to 250 part weight.

Description

TECHNICAL FIELD[0001]The present invention relates to a non-halogenous insulated wire and a wiring harness, and more specifically relates to a non-halogenous insulated wire having a multilayered structure and a wiring harness including the same.BACKGROUND ART[0002]Conventionally, insulated wires in which conductors are covered with covering materials made from a resin composition are frequently used in carrying out wiring of parts for a car and electric / electronic equipment. In this type of insulated wires, especially in the insulated wire to be used in a section where heat resistance is required, used as the covering material is a vinyl chloride resin composition of which heat resistance is improved by adjusting types, amounts or polymerization degrees of a thermal stabilizer and a plasticizer to be added thereto, or by forming cross-links therein.[0003]However, there is a problem that this type of vinyl chloride resin composition includes halogen elements, so that it emits harmful...

AI Technical Summary

Benefits of technology

[0014]The non-halogenous insulated wire according to the present invention has a multilayered structure which is built up of the outermost coat which is in the specified range in thickness and is made from the specified resin composition, and the inside coat formed of one or more layers in which at least one of the layers is made from the specified resin composition.

[0015]By the inclusion of the inside coat which includes the specified part weight of metallic hydrate, the non-halogenous insulated wire possesses sufficient flame retardancy.

[0016]In addition, by the inclusion of the specified outermost coat and the specified inside coat, even if the non-halogenous insulated wire is used in a section exposed to relatively high temperatures such as surroundings of an auto engine compartment, a covering material of the non-halogenous insulated wire is hardly melted or hardly deformed with heat, so that the non-halogenous insulated wire is excellent in heat resistance.

[0017]In addition, by the inclusion of the outermost coat made from the resin composition which is not filled with a large amount of metallic hydrate, the non-halogenous insulated wire is excellent especially in mechanical properties such as wear resistance compared with a conventional insulated wire in which a conductor is covered with one layer of a flame-retardant resin composition containing a large amount of metallic hydrate.

[0018]In addition, by the inclusion of the specified outermost coat and the specified inside coat, the non-halogenous insulated wire is excellent in flexibility.

[0019]In this case, when (A) the olefin resin with the melting point of 180° C. or more included in the inside coat has flexural modulus no higher than that of the olefin resin with the melting point of 180° C. or more included in the outermost coat, wear resistance of the outermost coat and flexibility of the inside coat are further improved.

Problems solved by technology

However, there is a problem that this type of vinyl chloride resin composition includes halogen elements, so that it emits harmful halogenous gas into the atmosphere in case of car fire or at the time of combustion for disposing of electric / electronic equipment by incineration, causing environmental pollution.

However, the olefin resin is essentially combustible, and the non-halogenous flame retardant is inferior to a halogenous flame retardant in effect of flame retardancy.

For these reasons, the non-halogenous flame-retardant resin composition requires a large amount of metallic hydrate to be added thereto in order to secure sufficient flame retardancy, thus bringing a disadvantage that mechanical properties such as wear resistance, tensile elongation and tensile strength remarkably degrade.