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Thermosetting light-reflecting resin composition, optical semiconductor element mounting board produced therewith, method for manufacture thereof, and optical semiconductor device

a technology of light-reflecting resin and composition, which is applied in the direction of spectacles/goggles, spectral modifiers, solid-state devices, etc., can solve the problems of reducing the performance of the device, the degradation of the device material, and the incompatibility of most compounds used as release agents, etc., to achieve high degree of various characteristics, high releasability, and high reliability

Active Publication Date: 2014-07-22
RESONAC CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The invention is a thermosetting light-reflecting resin that has good optical properties, thermal discoloration resistance, and is highly releasable during molding. This allows for continuous molding processes and reduces the frequency of external release agent usage, resulting in increased productivity. Additionally, the resin composition has good light reflection characteristics and high thermal discoloration resistance, which enables efficient reflection of light and production of optical semiconductor mounting boards with high reliability.

Problems solved by technology

As LED devices have had increased brightness accordingly, the junction temperature has been increased because of increase in the quantity of heat emitted from the elements, or optical energy itself has been increased, which causes the problem of degradation of device materials.
In many cases, however, most compounds used as release agents are not compatible with based resin including epoxy resin, a curing agent and so on, which form a thermosetting light-reflecting resin composition.
Therefore, when a board is formed by molding a resin composition containing such a release agent, the board is more likely to have poor appearance due to insufficient dispersion of the release agent, and this tends to make continuous molding difficult.
The flow behavior as well as insufficient dispersion of the release agent gives rise to destruction of the package or the poor appearance of the package.
A release agent and a dispersing agent optionally used together with the release agent are often thermally-unstable organic compounds.
For example, therefore, when used for a long time under high temperature conditions or when exposed to high-temperature heating or used for optical semiconductor devices, a resin composition containing such compounds tends to be colored or have a reduced diffuse reflectance, so that it may tend to be difficult to obtain sufficient optical properties or reliability.

Method used

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  • Thermosetting light-reflecting resin composition, optical semiconductor element mounting board produced therewith, method for manufacture thereof, and optical semiconductor device
  • Thermosetting light-reflecting resin composition, optical semiconductor element mounting board produced therewith, method for manufacture thereof, and optical semiconductor device
  • Thermosetting light-reflecting resin composition, optical semiconductor element mounting board produced therewith, method for manufacture thereof, and optical semiconductor device

Examples

Experimental program
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examples

[0132]The invention is described in more detail by the examples below, which are not intended to limit the scope of the invention.

examples a1

to A7

[0133]The materials shown below were used in the respective examples.

[0134]*1: Triglycidyl isocyanurate (100 in epoxy equivalent, TEPIC-S (trade name), manufactured by NISSAN CHEMICAL INDUSTRIES, LTD.)

[0135]*2: Hexahydrophthalic anhydride (manufactured by Wako Pure Chemical Industries, Ltd.)

[0136]*3: PX-4ET (trade name), manufactured by Nippon Chemical Industrial Co., Ltd.

[0137]*4: Trimethoxyepoxysilane (A-187 (trade name), manufactured by Dow Corning Toray Co., Ltd.)

[0138]*5: Fused silica (FB-301 (trade name), manufactured by DENKI KAGAKU KOGYO KABUSHIKI KAISHA)

[0139]*6: Hollow particles (S60-HS (trade name), manufactured by Sumitomo 3M Limited)

[0140]*7: Alumina (AO-25R (trade name), manufactured by Admatechs)

[0141]*8: Additives (see Table 1 below)

[0142]*9: Release agent 1 (fatty acid ester, “Hoechst Wax E” (trade name), manufactured by Clariant)

[0143]*10: Release agent 2 (aliphatic ether, UNITOX 420 (trade name), manufactured by Toyo Petrolite Co., Ltd.)

[0144]The details of t...

examples b1 to b14

and Comparative Examples B1 to B14

1. Preparation of Thermosetting Light-Reflecting Resin Compositions

[0186]The raw materials were mixed according to the formulation shown in Tables B1 and B2 below and sufficiently kneaded in a mixer. The mixture was then molten and kneaded under predetermined conditions in a mixing roll, so that a kneaded product was obtained. The resulting kneaded product was then cooled and pulverized, so that each of thermosetting light-reflecting resin compositions of Examples B1 to B14 and Comparative Examples B1 to B14 was prepared. The units of the amounts of raw material given in each table are all parts by weight, and the “-” section means that the corresponding raw material is not added.

2. Evaluation of Thermosetting Light-Reflecting Resin Compositions

[0187]Each of the prepared thermosetting light-reflecting resin compositions of Examples B1 to B14 and Comparative Examples B1 to B14 was subjected to each of the characteristic tests in the same manner as fo...

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Abstract

There is provided a thermosetting light-reflecting resin composition that has a high level of various characteristics required of optical semiconductor element mounting boards, such as optical properties and thermal discoloration resistance, provides high releasability during molding such as transfer molding, and allows molding processes to be performed continuously. There are also provided a highly-reliable optical semiconductor element mounting board and an optical semiconductor device each produced with the resin composition, and methods for efficient production thereof. A thermosetting light-reflecting resin composition is prepared and used, which includes (A) an epoxy resin, (B) a curing agent, (C) a curing catalyst, (D) an inorganic filler, (E) a white pigment, (F) an additive, and (G) a release agent as major components, wherein the resin composition, after curing, has a diffuse reflectance of 80% or more at a light wavelength of 400 nm; and the resin composition is possible to perform transfer molding 100 times or more continuously.

Description

TECHNICAL FIELD[0001]The invention relates to a thermosetting light-reflecting resin composition for use in an optical semiconductor device including a combination of an optical semiconductor element and wavelength conversion means such as a fluorescent substance, an optical semiconductor element mounting board produced therewith, a method for manufacture thereof, and an optical semiconductor device.BACKGROUND ART[0002]In recent years, optical semiconductor devices including a combination of an optical semiconductor element such as an LED (Light Emitting Diode) and a fluorescent substance have grown in demand and found various applications including an outdoor display, a portable liquid crystal backlight, and automotive applications, because of their advantages such as high energy efficiency and long life. As LED devices have had increased brightness accordingly, the junction temperature has been increased because of increase in the quantity of heat emitted from the elements, or opt...

Claims

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Application Information

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Patent Type & Authority Patents(United States)
IPC IPC(8): C08K7/24C08L63/00C08K3/22H01L33/48H01L33/60
CPCH01L2224/48247C08G59/3245H01L33/60C08L63/00H01L2224/48091C08L83/10H01L2224/16245H01L2224/32245H01L33/483C08G77/445H01L2224/73265Y10T428/1068H01L2924/00014H01L2924/00011C09K2323/053C08L83/00H01L2224/0401H01L2924/00012C08G59/40C08K3/00H01L23/14H01L33/52H01L2924/00
Inventor KOTANI, HAYATOURASAKI, NAOYUKIMIZUTANI, MAKOTO
Owner RESONAC CORP
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