Polyvinyl chloride organic smectite composite material and preparation process thereof
An organic saponite and composite material technology, applied in the field of polyvinyl chloride-organized saponite composite material and its preparation, to solve the problem of discoloration and degradation and improve the elongation at break.
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Embodiment 1
[0030] Embodiment 1: Stir 100 grams of raw material soapstone in 1000 grams of deionized water to form a stable suspension with a concentration of 10% mass fraction; prepare 0.141 moles of organic cationic salt cetyltrimethylammonium chloride in deionized water into a 2% mass fraction concentration solution. Stir the soapstone suspension at 90°C for 10 minutes at a stirring speed of 1000 rpm, then add the above-mentioned organic cation salt cetyltrimethylammonium chloride solution to the above-mentioned soapstone suspension, and react for 4 hours. Then filter. And the filtrate is washed several times with deionized water, and is detected by 0.1 mol / liter silver nitrate solution until there is no halogen ion in the washing liquid; the organic saponite after washing is dried and ground to obtain a particle size of 60 microns to 74 microns of organic saponite.
[0031] 100 parts by weight of polyvinyl chloride resin, 3 parts by weight of organic soapstone, 5 parts by weight of ...
Embodiment 2
[0032] Embodiment 2: 100 grams of raw material soapstone are stirred in 2000 grams of deionized water to form a stable suspension with a concentration of 5% mass fraction; 0.1194 moles of organic cationic salt dioctadecyldimethylammonium chloride are dissolved in deionized water Prepared into a 5% mass fraction concentration solution. Stir the soapstone suspension at 80°C for 15 minutes at a stirring speed of 900 rpm, then add the above-mentioned organic cation salt dioctadecyldimethylammonium chloride solution to the above-mentioned soapstone suspension and react for 2 hours , and then filter. And the filtrate is washed several times with deionized water, and is detected by 0.1 mol / liter silver nitrate solution until there is no halogen ion in the washing liquid; the organic saponite after washing is dried and ground to obtain a particle size of 60 microns to 74 microns of organic saponite.
[0033] 100 parts by weight of polyvinyl chloride resin, 5 parts by weight of organ...
Embodiment 3
[0034] Embodiment 3: Stir 100 grams of raw material soapstone in 3000 grams of deionized water to form a stable suspension with a concentration of 3.3% mass fraction; prepare 0.1407 moles of organic cationic salt octadecyltrimethylammonium chloride in deionized water into a 2% mass fraction concentration solution. Stir the soapstone suspension at 55°C for 30 minutes at a stirring speed of 750 rpm, then add the above-mentioned organic cation salt octadecyltrimethylammonium chloride solution to the above-mentioned soapstone suspension, and react for 2.5 hours. Then filter. And the filtrate is washed several times with deionized water, and is detected by 0.1 mol / liter silver nitrate solution until there is no halogen ion in the washing liquid; the organic saponite after washing is dried and ground to obtain a particle size of 60 microns to 74 microns of organic saponite.
[0035]100 parts by weight of polyvinyl chloride resin, 4 parts by weight of organic soapstone, 8 parts by ...
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