Technique for sulfur recovery in process of wet desulphurization

A wet desulfurization and sulfur recovery technology, applied in the field of environmental engineering, can solve the problems affecting the desulfurization efficiency of the desulfurization system, the primary and secondary pollution of the environment, and the economic loss, etc., and achieves significant energy saving, consumption reduction, pollution reduction, and small labor load. Effect

Active Publication Date: 2008-02-27
CHANGCHUN DONGSHI TECH & TRADING INDAL
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  • Abstract
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Problems solved by technology

[0002] At present, after wet desulfurization of water gas, semi-water gas, shift gas, city gas, biogas, and natural gas in chemical fertilizer plants and coking plants, a large amount of sulfur foam is produced after flotation in the regeneration tank, and the sulfur foam contains a large amount of water. In some processes, the sulfur foam is directly sent to the sulfur melting kettle for melting sulfur. Due to the evaporation of water, a large amount of steam and electric energy will be consumed. Sodium sulfate, sodium sulfate and other salts, and the raffinate is difficult to handle. If the raffinate is returned to the desulfurization system, it will seriously affect the desulfurization efficiency of the desulfurization system, and will cause tower blockage, affecting subsequent production and causing great economic losses; if it is discharged into the environment , will cause very serious primary and secondary pollution to the environment

Method used

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  • Technique for sulfur recovery in process of wet desulphurization

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Embodiment 1

[0012] According to Fig. 1, the sulfur recovery system is composed of liquid drainage tank 1, liquid storage tank 2, filter 3, sulfur melting kettle 4 and corresponding pipeline valves.

[0013] A semicircular hopper 5 is provided at the bottom of the filter 3, which is connected to the sulfur foam inlet pipe. The hollow drum 6 is a closed structure, and the shaft is connected to the upper part of the closed hopper 5. There are two suction pipes 7, and 2 to 6 liquid suction ports are arranged side by side on each liquid suction pipe 7, and each liquid suction port is connected to a piece of ceramic filter plate 8 to form 2 to 6 rows of disc-type rotary filter mechanisms, and the liquid discharge The negative pressure pipe of the tank 1 is connected to the inner cavity of the hollow drum 6 through a pipe, and the drum 6 generates negative pressure to filter and separate the sulfur foam in the hopper 5 through the ceramic filter plate 8, and the filtrate enters the drainage tank ...

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Abstract

The invention discloses a recycling technique of sulphur in the wet process desulfurizing course, which comprises the following steps: transmitting sulfur foam into the hopper of filter; filtering and separating liquid from sulphur in the sulphur foam; sucking the filtrate into drainage tank on the ceramic filter board under negative pressure and capillary action; sucking the filtrate into the drainage tank to return to desulfuring system to recycle; adsorbing a layer of sulfur filter pie on the surface of ceramic filter board; transmitting the stripped sulphur pie on the surface into sulphur fusing autoclave through scraper at filter drainage position; doing backwash the ceramic filter board in connection with backwash groove; finishing one circulation. The invention uses advanced inorganic ceramic filter to filter the sulphur foam to reduce energy consumption in the sulphur fusing course obviously, which eliminates large amount of residual liquid and side salt in the sulphur fusing course and cooling course respectively to reduce the pollution in the reacting course.

Description

Technical field: [0001] The invention improves the existing desulfurization process in chemical production, especially provides a sulfur recovery process in the wet desulfurization process, which belongs to the technical field of environmental engineering. Background technique: [0002] At present, after wet desulfurization of water gas, semi-water gas, shift gas, city gas, biogas, and natural gas in chemical fertilizer plants and coking plants, a large amount of sulfur foam is produced after flotation in the regeneration tank, and the sulfur foam contains a large amount of water. In some processes, the sulfur foam is directly sent to the sulfur melting kettle for melting sulfur. Due to the evaporation of water, a large amount of steam and electric energy will be consumed. Sodium sulfate, sodium sulfate and other salts, and the raffinate is difficult to handle. If the raffinate is returned to the desulfurization system, it will seriously affect the desulfurization efficiency...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B17/02B01D29/03
Inventor 高志斗汪晓梅
Owner CHANGCHUN DONGSHI TECH & TRADING INDAL
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