Method for recovering and processing discarded fluorescent lamp
A technology for recycling and processing fluorescent lamps, which is applied in glass recycling, recycling technology, electronic waste recycling, etc. It can solve the problems of different forms, waste of resources, and inability to completely remove pollution sources, so as to avoid treatment, simplify processes, and process methods. and economical effect
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[0033] Example 1:
[0034] In the following, a recycling example of the present invention will be described in detail with reference to the process in Figure 1. The discarded fluorescent lamps processed are all 40W T12 straight tube household lighting fluorescent lamps, each tube contains 20-40mg mercury and 4.5g tri-color phosphors. , Its basic composition is 60% Y 2 O 3 :Eu 3+ , 30% Ce 0.67 Mg 0.33 Al 11 O 19 :Tb 3+ , 10% BaMgAl 16 O 27 :Eu 2+ . The glass tube material is mainly made of Na 2 SiO 3 , CaSiO 3 , SiO 2 And a small amount of PbO; end metal parts: generally composed of Al caps, brass plugs, Cu-Ni alloy wires and polyacrylate insulators; the filament is usually tungsten wire.
[0035] 1) Clean the surface of the collected waste fluorescent lamp with decontamination powder, sodium hydroxide solution (2~3mol / L), nitric acid solution (2mol / L), and tap water to remove oil stains. After drying, use a cutting machine to cut off the non-glass part of the end of the lamp, and ...
Example Embodiment
[0043] Example 2:
[0044] Other content and operation are the same as in Example 1, the difference is: in step one, the recovery of gaseous mercury in the cutting process is completed in 25% acetone solution; in step 4) the starting chlorination temperature is 350°C, but the chlorination It takes a little longer to recover each component; in step 5), the glass and phosphor are mixed and recovered, the roasting temperature is controlled at 950℃, the reaction time is 90 minutes, and the control temperatures of the corresponding recovery furnaces 2, 3, 4, and 5 are reduced respectively. It is about 800°C, 700°C, 600°C, and 400°C. Under these conditions, the recovery treatment effect as in Example 1 can also be achieved.
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