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Porous ceramic for use in slide member and its manufacturing method and mechanical seal ring using it

A sliding member and manufacturing method technology, applied in the direction of engine seals, ceramic products, mechanical equipment, etc., can solve the problems of increased sliding area, increased sliding torque, and insufficient guarantee of lubricity, and achieves significant wear loss, restraint The effect of wear and high strength

Active Publication Date: 2012-08-08
KYOCERA CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In addition, when the friction of the sliding contact surface is serious after long-term sliding operation, the grooves and processing scratches disappear, and when the surface with few pores introduced by the pore-forming material appears, the actual sliding area increase, the supply of lubricant cannot be performed sufficiently, and the problem of increased slip torque occurs
In addition, when the porosity is large, if the dispersion of the pores is insufficient, the possibility of becoming through pores increases. Therefore, the prior art tends to suppress the porosity, and sufficient lubricity cannot be ensured in many cases.

Method used

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  • Porous ceramic for use in slide member and its manufacturing method and mechanical seal ring using it
  • Porous ceramic for use in slide member and its manufacturing method and mechanical seal ring using it
  • Porous ceramic for use in slide member and its manufacturing method and mechanical seal ring using it

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0117] Add a specified amount of alumina powder, yttrium oxide powder, dispersant and water to the silicon carbide powder, put it into a ball mill, mix for 48 hours, and form a slurry. After adding and mixing a molding aid to this slurry, it spray-dried and obtained the granulated powder with an average particle diameter of 18 micrometers.

[0118] Next, to this granulated powder, 8% by weight of the resin particles shown in Table 1 was added and mixed to obtain a mixed raw material, and the mixed raw material was molded into a predetermined shape under a pressure of 98 MPa to obtain samples No. 1 to 11. . Thereafter, sample Nos. 1 to 11 were held at 600° C. for 5 hours in a nitrogen atmosphere to degrease, and then held at 1850° C. for 3 hours in an argon atmosphere to perform sintering. Here, for samples No. 1 to 11, there are 3 discs each with at least either one of the upper and lower sides used as the sliding surface for the independent air hole evaluation, and 10 each o...

Embodiment 2

[0130] Add a specified amount of sintering aid, dispersant and water to the silicon carbide powder and put it into a ball mill, mix for 48 hours to form a slurry. At this time, those shown in Table 2 were used as sintering aids. After adding and mixing a molding aid to this slurry, it spray-dried and obtained the granulated powder with an average particle diameter of 18 micrometers.

[0131] Next, to this granulated powder, suspension-polymerized non-crosslinkable polystyrene resin particles were added and mixed in the amount shown in Table 2 as a pore forming agent to obtain mixed raw materials, respectively. This mixed raw material was molded under a pressure of 98 MPa into a bending test piece having a shape conforming to JIS C 2141-1992.

[0132] The obtained compact was held at 600° C. for 5 hours in a nitrogen atmosphere for degreasing, and then sintered at 1850° C. for 3 hours in an argon atmosphere to obtain sample Nos. 12 to 14. In addition, about sample No.12~14, p...

Embodiment 3

[0138] Add a specified amount of alumina powder, yttrium oxide powder, dispersant and water to the silicon carbide powder, put it into a ball mill, mix for 48 hours, and form a slurry. After adding and mixing a molding aid to this slurry, it spray-dried and obtained the granulated powder with an average particle diameter of 18 micrometers.

[0139] Next, to this granulated powder, 8% by weight of suspension-polymerized non-crosslinked polystyrene resin particles having an average particle diameter and a maximum particle diameter as shown in Table 3 were added and mixed as a pore-forming agent to obtain a mixed raw material. This mixed raw material was molded into a ring shape under a pressure of 98 MPa to obtain a molded body. Then, the molded body was degreased and fired in a reducing atmosphere to obtain sample Nos. 15 to 17. About the obtained sample No. 15-17, the measurement of the pore diameter of an independent pore, and an abrasion test were performed.

[0140] Speci...

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Abstract

A porous ceramic for sliding members having independent pores of pore size not smaller than 5 [mu]m. The pores are compressed flatly in the direction perpendicular to the sliding surface. The cross-directional area (S1) of each pore in the direction is 95% or less of the area (S2) when the cross-section of the pore is a true circle. The ratio (P75 / P25) of the cumulative 75 vol% pore size (P75) tothe cumulative 25 vol% pore size (P25) is 1.9 or less in the cumulative distribution curve of pore size of the independent pores in a plane parallel to the sliding surface. This porous ceramic can besuitably utilized for a sliding member such as a seal ring.

Description

technical field [0001] The present invention mainly relates to porous ceramics for forming sliding members such as seal rings in mechanical seals used as shaft seals for automobile cooling water pumps and refrigerators, and methods for producing the same. Background technique [0002] As an example of the use of the porous ceramic for sliding members, a (mechanical) seal ring used in a mechanical seal is mentioned. The so-called mechanical seal is one of the shaft seal devices of fluid equipment for the purpose of completely sealing the fluid of the rotating parts of various machines. The ring structure has a vibration-absorbing mechanism, and plays the role of restricting fluid leakage on the sliding surface approximately perpendicular to the relatively rotating shaft. [0003] The basic structure of the mechanical seal is as follows: figure 1 As shown, the seat ring 5 and the driven ring 6 constituting the sealing ring are installed between the rotating shaft 1 and the h...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B38/00C04B38/06F16J15/34
CPCC04B38/0054C04B38/0615C04B2235/3217C04B35/565C04B2235/3225F16J15/3496Y10T428/249956Y10T428/249957Y10T428/249969Y10T428/24997Y10T428/249975Y10T428/249978Y10T428/249979C04B38/0058C04B35/00
Inventor 原毅益山伸一郎
Owner KYOCERA CORP
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