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Functional PVC plastic colloidal sols for non-powder PVC gloves and uses thereof

A plastisol and functional technology, applied in the field of PVC plastisol, can solve the problems of skin pollution, low productivity, coating peeling, etc., and achieve the effect of reducing friction, avoiding pinholes, and good slippery wearability

Inactive Publication Date: 2011-05-11
BEIJING COMENS NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Therefore, the powder-free PVC gloves prepared now still have the problems of low productivity, coating shedding may cause pollution and skin allergies may occur, and it is necessary to develop a new preparation method of powder-free PVC gloves and the used finishing agent

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Add 800 parts by mass of deionized water into a reactor with a condensation reflux device, add 6 parts by mass of polymer suspending agent polyvinyl alcohol, add 1 part by mass of sodium polyacrylate as a dispersant, and add 2 parts by mass of magnesium hydroxide , stir to disperse evenly. 5 parts by mass of methyl acrylate, 40 parts by mass of methyl methacrylate, 50 parts by mass of styrene, 5 parts by mass of bisacryloyl-terminated polydimethylsiloxane and 0.5 parts by mass of dibenzoyl peroxide were pre-mixed uniform, and added to the above aqueous medium. Under strong stirring, polymerize at 80-90°C for 6 hours, then raise the temperature to 100°C and keep it warm for 5 hours to fully react the monomers. After polymerization, cool to room temperature, filter, pickle to remove inorganic salts, then wash with water and air-dry, and finally sieve and classify. Polysiloxane-modified styrene-acrylic resin microparticles with a particle diameter of 2 μm to 10 μm are ob...

Embodiment 2

[0043] Add 800 parts by mass of deionized water into a reactor with a condensation reflux device, add 6 parts by mass of polymer suspending agent polyvinyl alcohol, add 1 part by mass of sodium polyacrylate as a dispersant, add 2 parts by mass of calcium phosphate, Stir to disperse evenly. 5 parts by mass of methyl acrylate, 45 parts by mass of methyl methacrylate, 46 parts by mass of styrene, 4 parts by mass of bisacryloyl-terminated polydimethylsiloxane and 0.5 parts by mass of dibenzoyl peroxide were pre-mixed uniform, and added to the above aqueous medium. Under strong stirring, polymerize at 80-90°C for 6 hours, then raise the temperature to 100°C and keep it warm for 5 hours to fully react the monomers. After polymerization, cool to room temperature, filter, pickle to remove inorganic salts, then wash with water and air-dry, and finally sieve and classify. Polysiloxane-modified styrene-acrylic resin microparticles with a particle diameter of 2 μm to 10 μm are obtained....

Embodiment 3

[0062] Add 800 parts by mass of deionized water into a reactor with a condensation reflux device, add 6 parts by mass of polymer suspending agent polyvinyl alcohol, add 1 part by mass of sodium polyacrylate as a dispersant, and add 2 parts by mass of magnesium hydroxide , stir to disperse evenly. Mix 2 parts by mass of methyl acrylate, 45.5 parts by mass of methyl methacrylate, 50 parts by mass of styrene, 2.5 parts by mass of divinyl-terminated polymethylsiloxane and 0.6 parts by mass of dibenzoyl peroxide , and added to the above aqueous medium. Under strong stirring, polymerize at 80-90°C for 6 hours, then raise the temperature to 100°C and keep it warm for 5 hours to fully react the monomers. After the polymerization, cool to room temperature, filter, pickle to remove inorganic salts, then wash with water and air-dry, and finally sieve and classify. Polysiloxane-modified styrene-acrylic resin microparticles with a particle diameter of 2 μm to 10 μm are obtained.

[0063...

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Abstract

The invention discloses a functional PVC plastisol used by powderless PVC gloves and the application of the plastisol, belonging to the technical field of the PVC gloves; to solve the problems of low production efficiency and bad dressing effect of present powderless PVC gloves, the functional PVC plastisol is made from styrene-acrylic resin particles which are modified by PVC emulsification powder, primary plasticizers, secondary plasticizers, viscosity depressants, stabilizing agents and polysiloxane, uniformly mixed and treated with vacuum defoamation; a preheated hand die is gelled to form a film after going through digestion and roast in the ordinary PVC plastisol, then is gelled to form a film by digestion and roast in the functional PVC plastisol of the invention and then the powderless gloves with good dressing effect and no self conglutination are obtained by edge turning and parting.

Description

technical field [0001] The present invention relates to a kind of PVC plastisol and its application, more specifically, the present invention relates to a kind of functional PVC plastisol for preparing powder-free PVC gloves and the method for using it to prepare non-adhesion gloves. Background technique [0002] Disposable film PVC gloves are made by dipping the glove mold into PVC plastisol solution and baking at about 210°C to form a gel into a film. When untreated, due to the self-adhesiveness of the PVC material used to prepare the gloves, it is difficult to release the gloves during production, and the inner surface of the gloves will be seriously stuck after offline, making it inconvenient to wear during use. For this reason, it is necessary to treat the surface of the glove first, and then turn over the treated glove so that the original outer surface becomes the inner surface, so as to solve the above problems. [0003] Traditional powder-free PVC gloves are dip-co...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L27/06C08K5/521B29C41/14B29C41/22B29C41/52B29C41/24A41D19/00C08K5/12C08L51/08
Inventor 贾海亭沈峰
Owner BEIJING COMENS NEW MATERIALS
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