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Preparation for water chestnut leather activated char

A technology of activated carbon and water chestnut, applied in the field of preparation of water chestnut skin activated carbon, can solve the problems of high risk, difficulty in centralized collection, and environmental pollution, and achieve the effects of low environmental pollution, reduced preparation cost, and easy collection

Inactive Publication Date: 2008-10-01
SHANDONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, the raw materials for preparing activated carbon mainly include wood, wood chips, fruit shells, etc., among which wood is the main material. However, in recent years, the forest coverage rate has dropped sharply, and the supply of wood has decreased, so that the raw material supply of activated carbon is showing a tense trend, and the price is also on the rise. , leading to great restrictions on the preparation and utilization of activated carbon
In addition, some activated carbons are prepared from coal, sludge, and plastics, but these raw materials will cause environmental pollution, so they cannot be widely used at present.
Recently, the use of fruit shells to make activated carbon has been favored by researchers, but most of the fruit shells are produced in scattered places, which are difficult to collect centrally, and the cost is high, and it is difficult to popularize and use
In addition, the existing activated carbon preparation processes are mainly potassium hydroxide method and zinc chloride method, and the waste liquid produced by these two methods is difficult to reuse, it is easier to cause environmental pollution, and it is more dangerous during operation

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] Water chestnut skin is dried in oven at 105 ℃ or air-dried naturally, then pulverizes, makes it pass through the sieve of 80 meshes, is that the peracetic acid of volume fraction is 30% and carries out pre-oxidation again, soaking time is 9 hours; Pour the used peracetic acid into a designated container, then soak the water chestnut skin with distilled water for 10 hours, then wash with distilled water until the pH is 6.0, and dry at 105°C; Ratio (the ratio of phosphoric acid to water chestnut powder mass) is 1.8:1 impregnation ratio impregnation 16 hours, then puts the water chestnut leather that impregnates in the muffle furnace, carbonizes at 390 ℃, activates 90 minutes, takes out after cooling to normal temperature, Wash with distilled water until the pH is 6.5, and then dry at 105°C to obtain powdered water chestnut skin activated carbon.

Embodiment 2

[0035] Water chestnut skin is dried in oven at 120 ℃ or air-dried naturally, then pulverizes, makes it pass through 100 mesh sieves, is that the peracetic acid of volume fraction is 60% and carries out pre-oxidation again, soaking time is 5 hours; Pour the used peracetic acid into a designated container, then soak water chestnut skin with distilled water for 12 hours, then wash with distilled water until the pH is 6.5, and dry at 120°C; pre-oxidize the particles with 45% phosphoric acid Ratio (the ratio of phosphoric acid to water chestnut powder mass) is 2.0:1 impregnation ratio impregnation 10 hours, then puts the water chestnut skin soaked in the muffle furnace, carbonizes at 430 ℃, activates for 70 minutes, takes out after cooling to normal temperature, Wash with distilled water until the pH is 7.0, and then dry at 120°C to obtain powdered water chestnut skin activated carbon.

Embodiment 3

[0037] The skin of water chestnut is dried in oven at 110 ℃ or air-dried naturally, then pulverizes, makes it pass through 90 mesh sieves, is soaked and carried out pre-oxidation with the peracetic acid of 45% volume fraction again, soaking time is 7 hours; Pour the used peracetic acid into a designated container, then soak water chestnut skin with distilled water for 11 hours, then wash with distilled water until the pH is 6.3, and dry at 115 ° C; Ratio (the ratio of phosphoric acid to water chestnut powder mass) is 1.9: 1 impregnation ratio impregnation 13 hours, then puts the water chestnut skin soaked in the muffle furnace, carbonizes at 410 ℃, activates 80 minutes, takes out after cooling to normal temperature, Wash with distilled water until the pH is 6.7, and then dry at 115°C to obtain powdered water chestnut skin activated carbon.

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PUM

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Abstract

The invention relates to a method for preparing the activated charcoal of water caltrop peels which comprises the preparation of the powdered activated charcoal of water caltrop peels and the lumpish activated charcoal of water caltrop peels. The preparation method of the invention comprises the steps of drying, pre-oxidation, washing, baking and carbonization. Since the method does not adopt methods such as a potassium hydroxide process and a zinc chloride process, etc., during the preparation process, not only environmental pollution can be avoided, but also the operation becomes simple. The activated charcoal of water caltrop peels prepared by the method of the invention can be applied to a plurality of fields. The powdered activated charcoal can be used as an adsorbent to absorb a plurality of common substances as well as toxic and harmful substances such as dyes and phenol, etc., while the lumpish activated charcoal can be taken as fillers used in fluidized beds, moving beds and certain fixed beds and the fillers have better bio-affinity and hydrophilicity, are beneficial to biofilm culturing and cause no secondary pollution to environment after being disused.

Description

technical field [0001] The invention relates to a preparation method of activated carbon, in particular to a preparation method of water chestnut skin activated carbon. Background technique [0002] At present, the raw materials for preparing activated carbon mainly include wood, wood chips, fruit shells, etc., among which wood is the main material. However, in recent years, the forest coverage rate has dropped sharply, and the supply of wood has decreased, so that the raw material supply of activated carbon is showing a tense trend, and the price is also on the rise. , so that the preparation and utilization of activated carbon are greatly restricted. In addition, some activated carbons are prepared from coal, sludge, and plastics, but these raw materials will cause environmental pollution, so they cannot be widely used at present. Recently, the use of fruit shells to make activated carbon has been favored by researchers, but most of the fruit shells are produced in scatte...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B31/08
Inventor 张成禄张建韩福眷史倩倩王丽李超
Owner SHANDONG UNIV
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