Method of forming a self aligned copper capping layer
A technology of barrier layer and interconnection layer, which is applied in the manufacture of electrical components, electrical solid-state devices, semiconductor/solid-state devices, etc.
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[0035] Therefore, here is proposed a process for forming a self-aligned Cu alloy capping layer on metal interconnects with improved adhesion properties and resistance to electromigration and stress-induced voids near the top of the interconnect lines. Cavity formation is inhibited. This can be achieved by forming an intermetallic compound, such as a copper alloy compound (eg, CuAlN), in close proximity to the top of the interconnect. Thus, the indiffusion of aluminum into copper can be controlled.
[0036] Starting from the structure after the chemical mechanical polishing step, and referring to the attached Figure 3a and Figure 4a , copper interconnects 14 are embedded within metal-in-dielectric layer 10 with barrier layer 12 therebetween. In a first example embodiment of the present invention, a thin metallic Al (or Mg, B, Zn, etc.) Figure 3b shown. Next, a reactive annealing process is performed in an ammonia environment, or in a nitrogen, oxygen, or carbon-containi...
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