Non-toxic anti-pollution paint for sea and method for preparing same
A marine anti-fouling and coating technology, applied in anti-fouling/underwater coatings, epoxy resin coatings, polyurea/polyurethane coatings, etc., can solve the problems of ship corrosion, difficult to estimate economic losses, and reduce ship voyage rate, etc. To achieve the effect of preventing attachment growth
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Embodiment 1
[0052] 8000 mesh white tourmaline powder and nano zinc oxide ((KY-ZnO-01: KY-ZnO-02 = 3: 2, Shanghai Caiyu Nano Technology Co., Ltd.) powder (tourmaline: nano zinc oxide = 5: 1) Add 50g into 500ml of water. Then heat and stir in a water bath to raise the temperature to 60°C, then add 0.06g of sodium dodecylbenzenesulfonate, stir at constant temperature for 1h, then stir and disperse at a medium speed (500 rpm) and cool to room temperature , to prepare nano-zinc oxide-coated tourmaline ultrafine powder pre-dispersed slurry;
[0053] The above-mentioned ultrafine powder pre-dispersion slurry is added to the ethanol aqueous solution with a volume percentage concentration of 5%, so that the weight percentage concentration of the mixed powder in the solution is 5%, and the pH of the solution is adjusted by adding ammonia water to 9, and the molar concentration is added dropwise. React with 0.02mol / L silicate ethanol solution, so that the weight ratio of silicate, tourmaline and nan...
Embodiment 2
[0063] Add 50 g of 25,000 mesh white tourmaline powder and nano-zinc oxide (KY-ZnO-02, Shanghai Caiyu Nano Technology Co., Ltd.) powder (tourmaline: nano-zinc oxide=3:1) to 500 ml of water. Then heat and stir in a water bath to raise the temperature to 70 ° C, then add 1 g of sodium dodecylbenzene sulfonate, stir at a constant temperature for 2 hours, then stir and disperse at a medium speed (600 rpm) and cool to room temperature to obtain nano-zinc oxide coating Ultrafine powder pre-dispersed slurry of tourmaline;
[0064] The above-mentioned superfine powder pre-dispersed slurry is added into the ethanol aqueous solution of 25% by volume percentage concentration, so that the weight percentage concentration of the mixed powder in the solution is 40%, and the pH of the solution adjusted by adding ammonia water is 11, and the dropwise molar concentration is React with 1mol / L silicate ethanol solution, so that the weight ratio of silicate, tourmaline and nano-zinc oxide powder m...
Embodiment 3
[0076] Add 50 g of 12500 mesh white tourmaline powder and nano-zinc oxide powder (NP-Z-60, Shanghai Gaona Powder Technology Co., Ltd.) (tourmaline: nano-zinc oxide=4:1) to 500 ml of water. Then heat and stir in a water bath to raise the temperature to 65 ° C, then add 0.1 g of sodium dodecylbenzene sulfonate, stir at a constant temperature for 3 hours, then stir and disperse at a medium speed (750 rpm) and cool to room temperature to prepare nano-zinc oxide coatings. Ultrafine powder pre-dispersed slurry coated with tourmaline;
[0077] The above-mentioned ultrafine powder pre-dispersion slurry is added to the ethanol aqueous solution with a volume percentage concentration of 40%, so that the weight percentage concentration of the mixed powder in the solution is 15%, and the pH of the solution is adjusted to 12 by adding sodium hydroxide solution. The molar concentration of 0.5mol / L silicate ethanol solution is reacted so that the weight ratio of silicate, tourmaline and nano-...
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