Hydrophilic processing method for zinc nickle alkaline accumulator diaphragm
A technology for hydrophilic treatment and storage batteries, which is applied in battery pack parts, circuits, electrical components, etc., can solve the problems of inability to apply zinc-nickel storage batteries, and achieve good hydrophilic liquid absorption performance, improved cycle life, and good air permeability. Effect
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[0047] Example 1
[0048] This example illustrates a method of making a non-hydrophilic membrane hydrophilic:
[0049] a. Preparation of hydrophilic treatment solution
[0050] According to the following weight percentages:
[0051] Hydrophilic surfactant: C 8 H 17 CH 2 COONa 0.1%
[0052] Oxidizer: hydrogen peroxide 1%
[0053] Ketones: Acetone 3%
[0054] Alcohols: 3% isopropanol
[0055] Deionized water: balance
[0056] b. The non-hydrophilic diaphragm is completely immersed in the hydrophilic treatment solution for 5 minutes;
[0057] c. Clean the treated diaphragm with deionized water until the PH value reaches 7;
[0058] d. Preparation of coating solution
[0059] According to the following weight percentages:
[0060] Additive to inhibit zinc dendrite growth: C 8H 17 CH 2 NH 3 ·HCl 6%
[0061] Deionized water: balance
[0062] e. The diaphragm is completely immersed in the coating solution for 2 minutes;
[0063] f. Dry at 65℃ or dry naturally.
[0064] Note: This ratio o...
Example Embodiment
[0067] Example 2
[0068] This example illustrates a method of making a non-hydrophilic membrane hydrophilic:
[0069] a. Preparation of hydrophilic treatment solution
[0070] According to the following weight percentage:
[0071] Hydrophilic surfactant: C 9 H 19 CH 2 OSO 3 Na 6%
[0072] Oxidizer: sodium hypochlorite 3%
[0073] Ketones: Acetone 2%
[0074] Alcohols: 2% isopropanol
[0075] Alkali: potassium hydroxide 0.5%
[0076] Deionized water: balance
[0077] b. The non-hydrophilic diaphragm is completely immersed in the hydrophilic treatment solution for 20 minutes;
[0078] c. Clean the treated diaphragm with deionized water until the PH value reaches 7;
[0079] d. Preparation of coating solution
[0080] According to the following weight percentages:
[0081] Additive to inhibit zinc dendrite growth: C 8 H 17 CH 2 NH3·HCl 6%
[0082] Deionized water: balance
[0083] e. The diaphragm is completely immersed in the coating solution for 5 minutes;
[0084] f. Dry at 75℃ o...
Example Embodiment
[0086] Example 3
[0087] This example illustrates a method of making a non-hydrophilic membrane hydrophilic:
[0088] a. Preparation of hydrophilic treatment solution
[0089] According to the following weight percentage:
[0090] Hydrophilic surfactant: C 12 H 25 C 6 H 5 SO 3 K 16%
[0091] Oxidizer: hydrogen peroxide 1%
[0092] Ketones: Acetone 2%
[0093] Alcohols: ethanol 3%
[0094] Deionized water: balance
[0095] b. The non-hydrophilic diaphragm is completely immersed in the hydrophilic treatment solution for 30 minutes;
[0096] c. Clean the treated diaphragm with deionized water until the PH value reaches 7;
[0097] d. Preparation of coating solution
[0098] According to the following weight percentage:
[0099] Additive to inhibit zinc dendrite growth: tetrabutyl amine bromide 0.1%
[0100] Deionized water: balance
[0101] e. The diaphragm is completely immersed in the coating solution for 1 min;
[0102] f. Dry at 85℃ or dry naturally.
[0103] Note: This ratio of...
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