An oligosaprobic polishing composition
一种组合物、酸化合物的技术,应用在抛光组合物、含研磨剂的抛光组合物、磨削/抛光设备等方向,能够解决拥有成本、昂贵清洗溶液等问题
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Embodiment 1
[0050] This example screens copper complexing agents that may be used to reduce green precipitate formation during high speed copper polishing in the presence of large amounts of BTA. This example was tested with a modification of the basic formulation to include 1% by weight of phosphate and 0.5% by weight of various complexing agents.
[0051] Table 1
[0052]
[0053] Citric acid, EDTA, nitrilotriacetic acid and iminodiacetic acid all eliminate polishing pad contamination. But only iminodiacetic acid and EDTA were able to prevent the formation of contamination while having sufficient copper removal rates.
Embodiment 2
[0055] This example illustrates the effect of iminodiacetic acid on the removal rate and green taint formation of a base formulation containing 0.44% by weight phosphate.
[0056] Table 2
[0057]
Embodiment 3
[0060] This example illustrates the effect of ammonium phosphate and pH on copper dishing and removal rate performance.
[0061] table 3
[0062]
[0063] By increasing the ammonium phosphate concentration, the copper removal rate can be increased. Alternatively, raising the pH reduces copper dishing, but slows down the copper removal rate.
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