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An oligosaprobic polishing composition

一种组合物、酸化合物的技术,应用在抛光组合物、含研磨剂的抛光组合物、磨削/抛光设备等方向,能够解决拥有成本、昂贵清洗溶液等问题

Active Publication Date: 2009-09-09
ROHM & HAAS ELECTRONICS MATERIALS CMP HLDG INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

These cleaning steps require powerful and expensive cleaning solutions and result in a "cost of ownership" by delaying wafer throughput

Method used

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  • An oligosaprobic polishing composition
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  • An oligosaprobic polishing composition

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] This example screens copper complexing agents that may be used to reduce green precipitate formation during high speed copper polishing in the presence of large amounts of BTA. This example was tested with a modification of the basic formulation to include 1% by weight of phosphate and 0.5% by weight of various complexing agents.

[0051] Table 1

[0052]

[0053] Citric acid, EDTA, nitrilotriacetic acid and iminodiacetic acid all eliminate polishing pad contamination. But only iminodiacetic acid and EDTA were able to prevent the formation of contamination while having sufficient copper removal rates.

Embodiment 2

[0055] This example illustrates the effect of iminodiacetic acid on the removal rate and green taint formation of a base formulation containing 0.44% by weight phosphate.

[0056] Table 2

[0057]

Embodiment 3

[0060] This example illustrates the effect of ammonium phosphate and pH on copper dishing and removal rate performance.

[0061] table 3

[0062]

[0063] By increasing the ammonium phosphate concentration, the copper removal rate can be increased. Alternatively, raising the pH reduces copper dishing, but slows down the copper removal rate.

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Abstract

The present invention relates to an oligosaprobic polishing composition. Particularly,the invention is an aqueous composition useful for chemical mechanical polishing of a patterned semiconductor wafer containing a copper interconnect metal. The aqueous composition includes an oxidizer, an inhibitor for the copper interconnect metal, 0.001 to 15 weight percent of a water soluble modified cellulose, non-saccaride water soluble polymer, 0 to 15 complexing agent for the copper interconnect metal, 0 to 15 weight percent phosphorus compound, 0.05 to 20 weight percent of an acid compound that is capable of complexing copper ions, and water; and the solution has an acidic pH.

Description

technical field [0001] The present invention relates to chemical mechanical polishing (CMP) of semiconductor wafer materials, and more particularly to CMP compositions and methods for polishing metal interconnect features on semiconductor wafers in the presence of dielectric or barrier materials. Background technique [0002] Typically the semiconductor wafer is a silicon wafer having a dielectric layer comprising a plurality of trenches arranged within the dielectric layer to form a pattern for circuit interconnection. The patterning typically has a corrugated structure or a double corrugated structure. A barrier layer overlies the patterned dielectric layer, and a metal layer overlies the barrier layer. The thickness of the metal layer is at least sufficient to fill the patterned trenches to form circuit interconnections. [0003] CMP processes often include multiple polishing steps. For example, the first step removes excess interconnect metal, such as copper, at an in...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09G1/16H01L21/304B24B29/00B24B37/04
CPCC09G1/04C09G1/02H01L21/3212C23F3/04C09K3/14C23F1/00C23F1/14C23F1/32H01L21/304H01L21/30625
Inventor T·M·托马斯王红雨
Owner ROHM & HAAS ELECTRONICS MATERIALS CMP HLDG INC