Tire for vehicle wheels comprising crosslinked elastomeric composition
一种弹性组合物、弹性聚合物的技术,应用在车轮、特殊轮胎、轮胎零部件等方向,能够解决胎面硬度、拉伸强度和伸长率添加影响等问题
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Embodiment 1
[0111] Surface treatment of vulcanized rubber in subdivided form
[0112] Dispose of mechanically ground waste rubber according to the following procedure. Table 1 discloses the amounts (parts by weight) of the various components relative to 100 parts by weight of the ground waste rubber itself.
[0113] Table 1
[0114] Example 1 vulcanized rubber 100 oxidizing agent 12.65 Surfactant 1.98 water 12.65
[0115] Vulcanized rubber: mechanically ground waste rubber from scrap tires (<0.425 mm (40 mesh) - from Somir);
[0116] Oxidizing agent: Oxyper TM S131, sodium percarbonate obtained from Solvay;
[0117] Surfactant: Polyol from Perstorp Polyols TM PP50.
[0118] The mechanically ground waste rubber was added to a laboratory impeller mixer (BF srl Engineering) and maintained under stirring. Once the temperature reached 80 °C, the oxidizing agent and surfactant were added and the obtained mixture was stirred for 10 min. Then, th...
Embodiment 2
[0120] Preparation of crosslinkable elastomeric compositions
[0121] The crosslinkable elastomeric compositions given in Table 2 were prepared as follows (amounts of the various components given in phr).
[0122] All components except sulfur and accelerator were mixed together in an internal mixer (model Pomini PL 1.6) for about 5 minutes (first step). Once the temperature reached 145±5°C, the elastomeric composition was discharged. Sulfur and accelerators are then added and mixed in the mill (second stage).
[0123] Table 2
[0124]
[0125] (c) Comparison (i) Invention
[0126] NR: natural rubber;
[0127] BR: cis-1,4-polybutadiene ( BR 40-EniChemElastomeri);
[0128] SBR: Styrene-butadiene rubber (Buna VLS 5025-1 HM-Bayer AG)
[0129] Silica: Precipitated silica ( 1165 MP-Rhone-Poulenc);
[0130] 6: Mixture of zinc salts of fatty acids (palmitic acid, stearic acid and oleic acid present in major amounts) (Great Lakes Chemical Corp.);
[0131] vulcaniz...
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