Chemical plating material and preparation method thereof
A technology of chemical plating and chemical plating, which is applied in the direction of liquid chemical plating, metal material coating process, coating, etc., can solve the problems of weak bonding between metal plating and substrate, low qualified rate of plating, and peeling off of chemical plating, etc. To achieve the effect of short cycle, simple operation and high production efficiency
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preparation example Construction
[0017] According to the preparation method of the electroless plating material of the present invention, the method includes contacting the plastic substrate with the reducing agent aqueous solution and the divalent copper salt aqueous solution, attaching the elemental copper particle layer to the surface of the plastic substrate, and then performing metal deposition to form the metal plating layer The elementary copper particle layer and the metal plating layer constitute an electroless plating layer, and the contact conditions enable the reducing agent to reduce the divalent copper salt into elemental copper particles with a particle diameter of 15-100 nanometers, and the electroless plating layer and The bonding force between the plastic substrates is 100-400 MPa. The method for contacting the plastic substrate with the aqueous solution of the reducing agent and the aqueous solution of divalent copper salt may be: after the plastic substrate is contacted with the aqueous solu...
reference example 1
[0033] Put 1,000 pieces of 3 cm×3 cm ABS engineering plastic base material (4 grams) of C2950 model C2950 produced by Dongguan Tongxin Engineering Plastics Co., Ltd. into 1 mol / L NaOH and 1 mol / L Na 2 CO 3 And 0.1 mol / L sodium dodecyl sulfonate solution, soak at 50℃ for 10 minutes, take it out and rinse with deionized water twice; then put it in 1 mol / L phosphoric acid solution and soak for 10 minutes , Rinse with deionized water 2 times after taking it out; then put in H containing 1 mol / L 2 SO 4 , 4 mol / L CrO 3 And 0.02 mol / L CrCl 3 ·6H 2 Soak in O solution for 12 minutes at 70°C and rinse with deionized water twice after taking it out.
Embodiment 1
[0035] This embodiment is used to illustrate the electroless plating material and its preparation method provided by the present invention.
[0036] (1) Preparation of electroless plating activation solution: add 0.014 mole of glucose to 50 ml of water, record it as solution A, and keep it constant in a water bath at 80°C. Add 0.024 mol of copper sulfate and 400 wt% of potassium sodium tartrate relative to the weight of copper sulfate in 200 ml of water, and adjust the pH of the solution to 12 with sodium hydroxide, record it as solution B, and keep it constant in a water bath at 80°C;
[0037] (2) Electroless plating activation: Put 10 ABS plastic substrates from Reference Example 1 into the above solution B at 80°C, and then put the above solution A at 0.72×10 per second -5 Add the solution B dropwise at a molar rate, and continue to contact for 10 minutes after the addition is complete, then take out the ABS plastic substrate and rinse with deionized water for 2 minutes. Every 1...
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