Catalytic conversion method for preparing propylene and high octane gasoline

A high-octane gasoline, catalytic conversion method technology, applied in catalytic cracking, cracking, organic chemistry and other directions, can solve the problems of underutilization of low-carbon olefin potential content, low yield of propylene and aromatic hydrocarbons, etc., and achieve dry gas production. rate reduction, gasoline yield increase, selectivity increase effect

Active Publication Date: 2010-06-30
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] The above prior art still has deficiencies in the design of alkane molecular cracking reactions. At the same time, the product distribution of the prior art is cut according to the conventional FCC fractionation system, and the potential content of aromatics and low-carbon olefins in gasoline or diesel oil is not fully utilized. , resulting in low yields of propylene and aromatics

Method used

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  • Catalytic conversion method for preparing propylene and high octane gasoline
  • Catalytic conversion method for preparing propylene and high octane gasoline
  • Catalytic conversion method for preparing propylene and high octane gasoline

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Experimental program
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Effect test

Embodiment approach 1

[0050] The preferred technical solution of this embodiment comprises the following steps:

[0051] The two reactors are respectively suitable for different catalyst A and catalyst B.

[0052] In the first reactor:

[0053] (1) The refractory raw material enters the bottom of the first reaction zone and contacts with the thermally regenerated catalyst A at a reaction temperature of 600°C-750°C and a weight hourly space velocity of 100h -1 -800h -1 , the reaction pressure is 0.10MPa-1.0MPa (absolute pressure), the weight ratio of catalytic cracking catalyst and raw material is 30-150, and the weight ratio of water vapor and raw material is 0.05-1.0 to carry out the cracking reaction;

[0054] (2) The reaction effluent is mixed with the easily cracked raw material entering from the middle and upper part of the first reaction zone without being separated by an oil agent. -1 -300h -1 The cracking reaction is carried out under the conditions that the reaction pressure is 0.10MPa...

Embodiment approach 2

[0064] The preferred technical solution of this embodiment comprises the following steps:

[0065] The two reactors are respectively suitable for different catalyst A and catalyst B.

[0066] In the first reactor:

[0067] (1) The refractory raw material enters the bottom of the first reaction zone and contacts with the thermally regenerated catalyst A at a reaction temperature of 600°C-750°C and a weight hourly space velocity of 100h -1 -800h -1 , the reaction pressure is 0.10MPa-1.0MPa (absolute pressure), the weight ratio of catalytic cracking catalyst and raw material is 30-150, and the weight ratio of water vapor and raw material is 0.05-1.0 to carry out the cracking reaction;

[0068] (2) The reaction effluent is mixed with the easily cracked raw material entering from the middle and upper part of the first reaction zone without being separated by an oil agent. -1 -300h -1 The cracking reaction is carried out under the conditions that the reaction pressure is 0.10MPa...

Embodiment approach 3

[0078] The preferred technical solution of this embodiment comprises the following steps:

[0079] The two reactors are respectively suitable for different catalyst A and catalyst B.

[0080] In the first reactor:

[0081] (1) The refractory raw material enters the bottom of the first reaction zone and contacts with the thermally regenerated catalyst A at a reaction temperature of 600°C-750°C and a weight hourly space velocity of 100h -1 -800h -1 , the reaction pressure is 0.10MPa-1.0MPa (absolute pressure), the weight ratio of catalytic cracking catalyst and raw material is 30-150, and the weight ratio of water vapor and raw material is 0.05-1.0 to carry out the cracking reaction;

[0082] (2) The reaction effluent is mixed with the easily cracked raw material entering from the middle and upper part of the first reaction zone without being separated by an oil agent. -1 -300h -1 The cracking reaction is carried out under the conditions that the reaction pressure is 0.10MPa...

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Abstract

The invention discloses a catalytic conversion method for preparing propylene and high octane gasoline. After entering different reaction regions of a first riser reactor, raw oils with different cracking performances are contacted with catalytic cracking catalyst to carry out cracking reaction so as to separate a spent catalyst and reaction oil gas, wherein the spent catalyst subject to steam stripping enters a first regenerator to be regenerated by scorching and returns to a first riser, and a product containing the propylene, the gasoline and recracking raw materials is obtained through separation of the reaction oil-gas, wherein the recracking raw materials are sent into a second riser reactor and are contacted with thermal regeneration catalyst to carry out catalytic conversion, and the spent catalyst returns to the second riser reactor after coke burning regeneration in a second regenerator. In the method, the yield of the propylene and the yield of the gasoline are obviously increased, and the gasoline octane number is obviously improved; and under the condition that the propylene yield is dramatically increased, the dry gas yield is obviously lowered by above 80 weight percent.

Description

technical field [0001] This invention pertains to the catalytic conversion of hydrocarbons in the absence of hydrogen, and more particularly to a process for the conversion of heavy feedstocks to propylene and high octane gasoline. Background technique [0002] Propylene is an important organic chemical raw material and a synthetic monomer for polypropylene, acrylonitrile and other products. With the rapid growth of demand for derivatives such as polypropylene, the demand for propylene is also increasing year by year. The demand in the world propylene market has increased from 15.2 million tons 20 years ago to 51.2 million tons in 2000, with an average annual growth rate of 6.3%. It is estimated that the demand for propylene will reach 86 million tons by 2010, with an average annual growth rate of about 5.6%. [0003] The methods for producing propylene are mainly steam cracking and catalytic cracking (FCC), wherein steam cracking uses naphtha and other light oils as raw m...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G11/00C10G11/04C07C11/06C07C4/06
CPCY02P20/52Y02P20/584
Inventor 杨轶男崔守业许友好龚剑洪刘守军程从礼
Owner CHINA PETROLEUM & CHEM CORP
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