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Low-gloss polycarbonate styreneresin composite and preparation method thereof

A technology of styrene resin and polycarbonate resin, which is applied in the field of low-gloss polycarbonate styrene resin composition and preparation, can solve problems such as low efficiency, increased embossing links, and reduced physical and mechanical properties of molded products. To achieve a reasonable effect of the preparation process

Inactive Publication Date: 2010-07-28
SHANGHAI KUMHO SUNNY PLASTICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] 1. Surface embossing, that is, skin texture treatment can achieve good results, but sometimes it cannot meet the required requirements, and a separate embossing link needs to be added, which increases the cost
At the same time, during subsequent use, the pattern may be removed due to wear and tear, causing the gloss to appear again
[0005] 2. Add fillers, such as titanium dioxide, silicon dioxide, silicate or aluminate and other similar inert minerals. Although it can also achieve the purpose of eliminating the surface gloss of molded products, a large amount of fillers must be added to achieve a certain degree of matteness. , which greatly reduces the physical and mechanical properties of molded products or leads to the deterioration of chemical properties, especially the great loss of material toughness
[0007] 4. Adding high-molecular polymers with reactive functional groups, such as PS-g-GMA, etc., due to poor reactivity when improving the gloss of products, requires a high amount of addition, low efficiency, and has a certain impact on mechanical properties.

Method used

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  • Low-gloss polycarbonate styreneresin composite and preparation method thereof

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Experimental program
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Effect test

Embodiment 1-9

[0043] (1) Prepare materials according to the following components and content (wt%):

[0044] Component A: Polycarbonate resin (PC) accounts for 20-85%; Component B: styrene toughener accounts for 5-50%; Component C: styrene-acrylonitrile copolymer (SAN) accounts for 5- 40%, of which SAN contains 60-80% styrene, 20-40% acrylonitrile; component D: special matting agent accounts for 1%-10%; component E: processing aid accounts for 0.1-1.5%.

[0045] Among them, the polycarbonate (A) used in the present invention is well known to those skilled in the art to which the present invention belongs.

[0046] The polycarbonate resin used in the present invention is in the presence of a molecular weight modifier and a catalyst, by reacting dihydric phenol with phosgene or by transesterifying dihydric phenol with a carbonate prepolymer of diphenyl carbonate reaction to prepare.

[0047] The polycarbonate resin includes linear polycarbonate, branched polycarbonate and polyester carbonat...

Embodiment 10

[0085] (1) Prepare materials according to the following components and contents:

[0086] Polycarbonate resin 20kg, styrene toughening agent 50kg; styrene-acrylonitrile resin 40kg; special matting agent 10kg; processing aid 1.5kg, of which polycarbonate resin molecular weight 10000, styrene toughener is Styrene-butadiene-acrylonitrile, the molecular weight of styrene-acrylonitrile resin is 15000, wherein the content of styrene is 60wt%, and the content of acrylonitrile is 40wt%. The special matting agent is montmorillonite intercalated with organic matter. The organic matter is Long-chain alkanes containing at least two epoxyethyl groups and epoxypropyl groups. Montmorillonite is a silicate clay with a layered structure after organic modification. The average wafer thickness is less than 30nm. Processing aids include lubricants, anti- Oxygen agent, release agent, lubricant is pentaerythritol stearate, and antioxidant is commercially available 168 phosphite antioxidants, and ...

Embodiment 11

[0090] (1) Prepare materials according to the following components and content (wt%):

[0091] Polycarbonate resin 85kg, styrene toughening agent 5kg; styrene-acrylonitrile resin 5kg; special matting agent 1kg; processing aid 0.1kg, of which polycarbonate resin molecular weight 50000, styrene toughening agent is Styrene-butadiene-acrylate, styrene-acrylonitrile resin molecular weight is 20000, wherein styrene content is 80wt%, acrylonitrile content is 20wt%, special matting agent is the montmorillonite of intercalation organic matter, and organic matter is Long-chain alkanes containing at least two epoxyethyl groups and epoxypropyl groups. Montmorillonite is a silicate clay with a layered structure after organic modification. The average wafer thickness is less than 30nm. Processing aids include lubricants, anti- Oxygen, release agent and colorant, lubricant is pentaerythritol stearate, antioxidant is commercially available IRGANOX 1076 hindered phenolic antioxidant, release a...

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Abstract

The invention relates to a low-gloss polycarbonate styreneresin composite and a preparation method thereof. The composite comprises the following components (by weight percent): 20-85wt% of polycarbonate resin, 5-50wt% of styrene flexibilizer, 5-40wt% of styrene-acrylonitrile resin,1-10wt% of specific matting agent, and 0.1-1.5wt% of processing agent; the materials are premixed for 3-10 minutes in a high speed mixer, then premix compound is subject to melt extrusion at 230-300 DEG C by a double screw extruding machine, and cooling and pelletizing are carried out, thus obtaining the low-gloss polycarbonate (PC) / styreneresin composite. Compared with the prior art, the invention has the advantages that preparation technology is reasonable and the technical problem of degradation of performance of products as matting efficiency of polycarbonate (PC) / styreneresin composite is low is solved.

Description

technical field [0001] The invention relates to a preparation method, in particular to a low-gloss polycarbonate styrene resin composition and a preparation method. Background technique [0002] Among the various applications of the composition of polycarbonate and styrenic resin, some fields require a low-gloss surface. These application fields are mainly automobiles, decorations, electronic appliances, etc., such as automotive interior parts, and attention should be paid to the design The reflectivity of the instrument panel should not only improve the visibility of the instrument, but also reduce glare through the diffuse reflection method of the cover, and prevent the high points on the instrument panel from forming a reflected image on the inner surface of the windshield, so as not to disturb the driver Therefore, the surface of the instrument panel must be matte or matte to obtain a comfortable and safe driving feeling. [0003] The traditional technical means to solv...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L69/00C08L25/12C08L55/02C08L25/08C08K9/04C08K3/34
Inventor 罗明华李文强李荣群辛敏琦
Owner SHANGHAI KUMHO SUNNY PLASTICS
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