Low-gloss polycarbonate styreneresin composite and preparation method thereof
A technology of styrene resin and polycarbonate resin, which is applied in the field of low-gloss polycarbonate styrene resin composition and preparation, can solve problems such as low efficiency, increased embossing links, and reduced physical and mechanical properties of molded products. To achieve a reasonable effect of the preparation process
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Embodiment 1-9
[0043] (1) Prepare materials according to the following components and content (wt%):
[0044] Component A: Polycarbonate resin (PC) accounts for 20-85%; Component B: styrene toughener accounts for 5-50%; Component C: styrene-acrylonitrile copolymer (SAN) accounts for 5- 40%, of which SAN contains 60-80% styrene, 20-40% acrylonitrile; component D: special matting agent accounts for 1%-10%; component E: processing aid accounts for 0.1-1.5%.
[0045] Among them, the polycarbonate (A) used in the present invention is well known to those skilled in the art to which the present invention belongs.
[0046] The polycarbonate resin used in the present invention is in the presence of a molecular weight modifier and a catalyst, by reacting dihydric phenol with phosgene or by transesterifying dihydric phenol with a carbonate prepolymer of diphenyl carbonate reaction to prepare.
[0047] The polycarbonate resin includes linear polycarbonate, branched polycarbonate and polyester carbonat...
Embodiment 10
[0085] (1) Prepare materials according to the following components and contents:
[0086] Polycarbonate resin 20kg, styrene toughening agent 50kg; styrene-acrylonitrile resin 40kg; special matting agent 10kg; processing aid 1.5kg, of which polycarbonate resin molecular weight 10000, styrene toughener is Styrene-butadiene-acrylonitrile, the molecular weight of styrene-acrylonitrile resin is 15000, wherein the content of styrene is 60wt%, and the content of acrylonitrile is 40wt%. The special matting agent is montmorillonite intercalated with organic matter. The organic matter is Long-chain alkanes containing at least two epoxyethyl groups and epoxypropyl groups. Montmorillonite is a silicate clay with a layered structure after organic modification. The average wafer thickness is less than 30nm. Processing aids include lubricants, anti- Oxygen agent, release agent, lubricant is pentaerythritol stearate, and antioxidant is commercially available 168 phosphite antioxidants, and ...
Embodiment 11
[0090] (1) Prepare materials according to the following components and content (wt%):
[0091] Polycarbonate resin 85kg, styrene toughening agent 5kg; styrene-acrylonitrile resin 5kg; special matting agent 1kg; processing aid 0.1kg, of which polycarbonate resin molecular weight 50000, styrene toughening agent is Styrene-butadiene-acrylate, styrene-acrylonitrile resin molecular weight is 20000, wherein styrene content is 80wt%, acrylonitrile content is 20wt%, special matting agent is the montmorillonite of intercalation organic matter, and organic matter is Long-chain alkanes containing at least two epoxyethyl groups and epoxypropyl groups. Montmorillonite is a silicate clay with a layered structure after organic modification. The average wafer thickness is less than 30nm. Processing aids include lubricants, anti- Oxygen, release agent and colorant, lubricant is pentaerythritol stearate, antioxidant is commercially available IRGANOX 1076 hindered phenolic antioxidant, release a...
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