Regular iron-carbon micro-electrolysis filler and preparation method thereof

An iron-carbon micro-electrolysis and regularization technology, which is applied in chemical instruments and methods, water/sludge/sewage treatment, water/sewage treatment, etc., can solve the problem of reduced treatment effect of iron-carbon micro-electrolysis filler, easy agglomeration and Channel flow, interruption of micro-electrolysis process, etc., to achieve good treatment effect, convenient packing filling, and prevent hardening

Inactive Publication Date: 2010-09-01
JILIN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, a large number of research results show that there are many defects in the application of this method. After the filler has been in operation for a period of time, it is prone to agglomeration and channeling due to the corrosion of iron, which reduces the treatment effect of the iron-carbon micro-electrolysis filler, and at the same time, iron filings will form on the surface. A layer of metal oxide and hydroxide film, resulting in the passivation of iron filings, which leads to the interruption of the micro-electrolysis process and affects the treatment effect

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] Mix 200g (50% by weight) of iron filings with a diameter less than 1mm, 60g (15% by weight) of powdered activated carbon with a diameter less than 0.1mm and 140g (35% by weight) of clay with a diameter less than 0.15mm, and take a little mixture , add a small amount of water, shake slowly to form granules, put the prepared structured packing with a diameter of 3 to 10mm in an oven, dry the water in it at 40°C, put the packing in a muffle furnace, Under the condition of oxygen isolation, it is roasted at 250°C for 4 hours. After the roasting, the filler is taken out and cooled to obtain the regularized iron-carbon micro-electrolytic filler.

Embodiment 2

[0020] 256g (64% by weight) of iron filings with a diameter less than 1mm, 40g (10% by weight) of powdered activated carbon with a diameter less than 0.1mm and 104g (26% by weight) of clay with a diameter less than 0.15mm are fully mixed, and a little mixture is taken , add a small amount of water, shake slowly to form granules, put the prepared structured packing with a diameter of 3 to 10mm in an oven, dry the water in it at 50°C, put the packing in a muffle furnace, Roast at 400°C for 3 hours under the condition of oxygen isolation. After the calcination, the filler is taken out and cooled to obtain the regularized iron-carbon micro-electrolytic filler.

Embodiment 3

[0022] 272g (68% by weight) of iron filings with a diameter of 0.15~0.5mm, 68g (17% by weight) of powdered activated carbon with a diameter less than 0.1mm and 60g (15% by weight) of clay with a diameter less than 0.15mm are fully mixed, A little mixture, add a small amount of water, shake slowly to form granules, put the prepared structured packing with a diameter of 3-10mm in an oven, dry the water in it at 30°C, put the packing in a muffle furnace , roasted at 600°C for 2 hours under the condition of oxygen isolation, after the roasting, the filler was taken out and cooled to obtain the regularized iron-carbon micro-electrolytic filler.

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Abstract

The invention discloses a regular iron-carbon micro-electrolysis filler and a preparation method thereof, belonging to the technical field of sewage treatment. The filler comprises the following components by weight percent: 50 to 80 percent of scrap iron with the diameter is 0.1 to 1 mm , 5-17 percent of powdery active carbon with the diameter of less than 0.1 mm and 15-35 percent of clay with diameter of less than 0.15 mm. The preparation method of the iron-carbon micro-electrolysis filler comprises the following steps of: a, uniformly mixing the filler according to the weight percentages; b, adding water to make the mixture into granular filler with the diameter of 3 to 10 mm; c, putting the filler into an oven and drying at 30 to 50 DEG C; d, moving the filler into a muffle furnace and baking for 2 to 4 hours at 250 to 600 DEG C in an oxygen-isolated condition; and e, cooling after the filler is baked to obtain the regular iron-carbon micro-electrolysis filler. The invention prevents hardening and passivation of the iron-carbon micro-electrolysis filler, is easy to fill and has advantages of good sewage treatment effect, low cost and easy preparation.

Description

technical field [0001] The invention belongs to the technical field of iron-carbon micro-electrolysis sewage treatment methods, and in particular relates to a preparation method of iron-carbon micro-electrolysis filler. Background technique [0002] Micro-electrolysis is a good process for treating wastewater by using the principle of metal corrosion to form a primary battery. It is also called internal electrolysis, zero-valent iron method, iron filings filtration method, and iron-carbon method. It is a widely researched and applied Wastewater treatment technology has received extensive attention in recent years because of its simple process, convenient operation, and the goal of "treating waste with waste". [0003] However, a large number of research results show that there are many defects in the application of this method. After the filler has been in operation for a period of time, it is prone to agglomeration and channeling due to the corrosion of iron, which reduces ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/461C02F101/34C02F101/36
Inventor 邹东雷李萌赵勇胜邹昊辰
Owner JILIN UNIV
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