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Preparation process of nano powder modified and reinforced die steels

A nano-powder and preparation process technology, which is applied in the field of die steel, can solve the problems of high melting temperature of die steel, poor quality stability of alloy steel, and difficulty in quality assurance, so as to improve wetting performance, increase dispersion, and improve wear resistance. sexual effect

Inactive Publication Date: 2010-11-10
江苏新亚特钢锻造有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, this process is only prepared by using the microalloy grain refinement widely used at home and abroad at present, and the principle of inhibiting the grain growth of steel by alloying elements, especially the use of niobium (Nb) in the metal crystallization process. If it can suppress recrystallization and improve the recrystallization temperature of the material, the manufactured steel ingot still belongs to the range of fine-grained steel and cannot be called nano-alloy steel.
Moreover, this process combines high-purity metal liquid and microalloying to form certain nucleation particles inside the steel. Since these particles are almost precipitated in the austenite below the solidus line, the austenite itself is The nucleation of the core cannot play the role of nucleation core, that is, it has no effect on refining the as-cast grains, and can only act as a pinning hindrance to the grain growth in the later thermal processing process, so there is a requirement for the purity of molten steel High, the quality stability of the alloy steel produced is poor, lack of pinning of the second phase particles to the grains, the quality is difficult to guarantee, the process controllability is poor, the production process control requirements are high, and the control is difficult and other defects
[0016] Due to the high melting temperature of die steel, the difficulty of uniform dispersion technology in steel after nanoparticles are added to steel, etc., seriously restricts the development and application of metal matrix nanocomposites, resulting in some metal matrix nanocomposites developed at home and abroad. The preparation process of metal-based nanocomposites is still in the experimental stage, so that the current research on metal-based nanocomposites is still vacant, at least no products have been formed yet.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] Adding nanoparticles to H13 hot work die steel for modification and strengthening. The chemical composition of H13 hot work die steel is C 0.31~0.45, Cr4.75~5.5, Mo1.10~1.75, Si0.81~1.20, V0.80~1.20, Mn<0.40, and the weight is 1000kg. The material of the nanoparticles is TiN, the particle size is 60nm, and the added amount is 0.5% by weight. The preparation process is:

[0044] 1. Nanoparticle pretreatment process:

[0045] The nanoparticles are pretreated before being added to increase the wettability of the nanoparticles and the steel matrix. The pretreatment process is:

[0046] a. Pour 25000ml of analytical pure ethanol into the container according to the ratio of nanoparticle mixed powder and ethanol to 1g / 5ml, put 5kg of TiN nanoparticles with a particle size of 60nm into the container of analytical pure ethanol, Stir and fully moisten;

[0047] c. Weigh the above-mentioned TiN nanoparticles after pretreatment and the iron powder with a particle size of 200 me...

Embodiment 2

[0058] in Cr 12 Adding nanoparticles to MoV cold work die steel for modification and strengthening. Cr 12 The chemical composition of MoV cold work die steel is C1.45~1.70, Cr4.75~5.5, Mo0.40~0.60, Si<0.40, V0.15~0.30, Mn<0.40, and the weight is 1000kg. The material of the nanoparticles is WC, the size of the particles is 100nm, and the added amount is 0.6% by weight.

[0059] 1. Nanoparticle pretreatment process:

[0060] a. Pour 42000ml of analytical pure ethanol into the container according to the ratio of nanoparticle mixed powder and ethanol to 1g / 7ml, put 6kg of WC nanoparticles with a particle size of 100nm into the container of analytical pure ethanol, Stir and fully moisten;

[0061] c. The above-mentioned WC nanoparticles after pretreatment and the iron powder with a particle size of 200 meshes for pre-diffusion are weighed according to the ratio of 1:1.5 by weight, and put into a stirring ball mill to stir and mix evenly, which will account for the volume of the a...

Embodiment 3

[0066] at W 6 Mo 5 Cr 4 V 2 Adding nanoparticles to high-speed steel for modification and strengthening. W 6 Mo 5 Cr 4 V 2 The chemical composition of high-speed steel is C0.80~0.90, Cr3.80~4.40, W4.50~5.50, Mo5.50~6.75, Si<0.40, Mn<0.40, V1.75~2.25, and the weight is 1000kg. The material of the nanoparticles is TiC, the particle size is 80nm, and the added amount is 0.8% by weight.

[0067] 1. Nanoparticle pretreatment process:

[0068] The nanoparticles are pretreated before being added to increase the wettability of the nanoparticles and the steel matrix. The pretreatment process is:

[0069] a. Pour 48000ml of analytical pure ethanol into the container according to the ratio of nanoparticle mixed powder and ethanol to 1g / 6ml, put 8kg of TiC nanoparticles with a particle size of 80nm into the container of analytical pure ethanol, Stir and fully moisten;

[0070] c. Weigh the above-mentioned TiC nanoparticles after pretreatment and the iron powder with a particle ...

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Abstract

The invention relates to a technical device for preparing nano powder modified and reinforced die steels. The preparation process comprises the following steps: pre-dispersing and mixing pretreated nano reinforced particles together with pre-dispersed iron powder in a stirring-type ball mill, preparing into dispersed prefabricated blocks, adding in steel ladle, dispersing the nanoparticles in a die steel matrix by a block dispersion method, enabling the nano particles to evenly disperse in the die steel matrix and metal wear resistant material matrix by utilizing an electromagnetic stirrer, and moulding by a casting method. The invention adopts nano particle modification process to improve the wettability of the nanoparticles and matrixes, obtain the die steels with evenly distributed nanoparticles by secondary dispersion and an electromagnetic stirring technology and enable the steels to be modified and reinforced. By adding nanoparticles with different materials, the modified die steel can have different properties so as to satisfy different requirements of service conditions; and by adjusting the addition amount of the nanoparticles and the volume fraction thereof, on the premise of ensuring the material impact roughness, the larger the nanoparticle volume fraction is, the higher the material wear resistance is. The nano powder modified and reinforced die steel in the invention has excellent mechanical performance, simple production process and low manufacture cost.

Description

technical field [0001] The invention belongs to the technical field of die steel, and relates to a preparation method of nano powder modified strengthened die steel, in particular to a preparation process of nano powder modified strengthened die steel. Background technique [0002] Mold is the basic process equipment of industrial production and the main indicator to measure the level of product manufacturing in a country. Die steel is the most important technical and material basis of the mold industry. Its variety, specification, performance and quality are decisive for the performance, life, manufacturing cycle and industrial products of the mold to the direction of advanced, diversified, personalized and high added value. Therefore, the research and development of die steel has always been valued by various countries. [0003] With the development of modern mechanical equipment and manufacturing technology, higher and more stringent performance requirements are put forw...

Claims

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Application Information

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IPC IPC(8): C21C7/00
Inventor 谢宗翰丁刚丁家伟耿德英孙健强颖怀
Owner 江苏新亚特钢锻造有限公司
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