Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Ketoxime ester compound and use thereof

A technology of ester compounds and compounds, which is applied in the field of ketoxime ester compounds and photopolymerizable compositions, can solve the problems of low sensitivity and poor productivity, and achieve the effect of high transmittance, high sensitivity and transmittance

Active Publication Date: 2011-04-13
MITSUBISHI RAYON CO LTD
View PDF43 Cites 20 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In addition, compared with photopolymerizable negative photosensitive compositions, there are also problems such as low sensitivity and poor productivity.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Ketoxime ester compound and use thereof
  • Ketoxime ester compound and use thereof
  • Ketoxime ester compound and use thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0513] [Example 1] (manufacture of ketoxime ester compound I-1)

[0514]

[0515] Ethylcarbazole (5g, 25.61mmol) and o-naphthoyl chloride (5.13g, 26.89mmol) were dissolved in 30ml of dichloromethane, stirred after cooling to 2°C in an ice-water bath, and aluminum chloride (3.41 g, 25.61 mmol). Stirring was further performed at room temperature for 3 hours. The reaction solution was poured into 200 ml of ice water, 200 ml of dichloromethane was added, and the organic layer was separated. The recovered organic layer was dried over magnesium sulfate and evaporated to give a white solid (10 g). The reaction formula is shown below.

[0516] [chemical formula 25]

[0517]

[0518]

[0519] Dissolve monoketone (7.05g, 22.34mmol) and 3-methylthiopropionyl chloride (3.77g, 21.06mmol) in 100ml of dichloromethane, cool to 2°C in an ice-water bath, stir, and add chloride Aluminum (6.30 g, 40.21 mmol). Stirring was further performed at room temperature for 3.5 h...

Embodiment 2

[0536] [Example 2] (manufacture of ketoxime ester compound 1-2)

[0537]

[0538] According to the same method as in Example 1, obtain 12.4 g of white solid. The reaction formula is shown below.

[0539] [chemical formula 30]

[0540]

[0541]

[0542] According to the same method as in Example 1, 2.0 g of diketone (3.82 g, 8.61 mmol), isoamyl nitrite (1.36 g, 11.62 mmol), and trimethylsilyl chloride (3.12 g, 27.72 mmol) were obtained to obtain 2.0 g of diketone yellow crystals. The reaction formula is shown below.

[0543] [chemical formula 31]

[0544]

[0545]

[0546] According to the same method as in Example 1, 1.6g of the following ketoxime ester compounds were obtained from ketoxime (5.0g, 10.32mmol), acetyl chloride (1.62g, 20.64mmol), triethylamine (2.09g, 20.64mmol) White crystals of I-2.

[0547] [chemical formula 32]

[0548]

[0549] The NMR chemical shift values ​​of this compound are shown below.

[0550] ...

Embodiment 3

[0555] [Example 3] (manufacture of ketoxime ester compound I-8)

[0556] Except that the glutaric acid monoethyl chloride used in the production of the diketone body in the above-mentioned Example 2 was changed to glutaric acid monomethyl chloride, the following ketoxime ester compound I was produced according to the same method as in Example 2- 8. The NMR chemical shift values ​​of the obtained compound are shown below.

[0557] 1 H-NMRδ[ppm]

[0558] 1.49(t, 3H), 2.29(s, 3H), 2.36(s, 3H), 2.73(t, 2H), 3.14(t, 2H), 3.60(s, 3H), 4.43(q, 2H), 7.3 ~7.5(m, 6H), 8.06(dd, 1H), 8.29(dd, 1H), 8.59(d, 1H), 8.83(dd, 1H)

[0559] [chemical formula 34]

[0560]

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
Acid valueaaaaaaaaaa
Acid valueaaaaaaaaaa
Acid valueaaaaaaaaaa
Login to View More

Abstract

Provided are a ketoxime ester compound which can be used as a novel and highly sensitive photopolymerization initiator; and a photopolymerizable composition useful for an interlayer insulating film and a color filter with high sensitivity and high transmittance. The ketoxime ester compound has a specific structure and the photopolymerization composition contains the ketoxime ester compound.

Description

technical field [0001] The present invention relates to a ketoxime ester compound useful as a photopolymerization initiator, a photopolymerization initiator containing the compound, and a photopolymerizable composition containing the photopolymerization initiator. More specifically, it relates to a photopolymerizable composition suitable for forming, for example, liquid crystal display elements, plasma displays, printed wiring boards, large scale integrated circuits, thin transistors, semiconductor packages, color filters , Insulation coating layers, solder resist films, cover films, etc. of various electronic components in organic electroluminescent elements, etc. [0002] In addition, since the ketoxime ester compound of the present invention can be made into a highly sensitive photopolymerization initiator, it can be used in optical color filters used in color televisions, liquid crystal display elements, solid-state imaging elements, cameras, etc. Colorant-containing phot...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C07C323/63C07D209/86C07D295/14G02B5/20G03F7/031
CPCC07C323/63C07D209/86C07C323/47G03F7/031G03F7/0045G03F7/0007
Inventor 龟山泰弘高桥裕子水上润二
Owner MITSUBISHI RAYON CO LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products