Bipolar phosphorescent main material containing anthracene derivatives of tetraphenyl silicane and carbazole and organic electroluminescent device
A technology of anthracene derivatives and tetraphenylsilicon, which is applied in the field of organic electroluminescent phosphorescent host materials and light-emitting devices, can solve problems such as low glass transition temperature, unsuitable HOMO/LUMO, and unachievable low triplet energy. The effect of high-quality materials and simple manufacturing process
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[0041] The present invention selects compound 1 (or compound 2, compound 3, compound 4) as the substrate of the light-emitting layer, and tris(2-phenylpyridine) iridium [abbreviated as Ir(ppy) 3 ] as phosphorescent doped materials, using a heating co-evaporation process for high-performance electrophosphorescent devices. The substrate 1 is made of glass or transparent plastic, and the transparent conductive film 2 is a 20Ω / sqITO (indium tin oxide) film as the anode. After the substrate is cleaned, the high-purity O 2 Plasma (plasma bombardment) treatment under the atmosphere for 10 minutes, and then in high vacuum (3 ~ 2 × 10 -4 pa), deposit a hole injection layer 3 with a thickness of 45nm on the transparent conductive film 2, select TCTA (4,4', 4''-tricarbazolyl triphenylamine; then deposit holes on the hole injection layer 3 The hole transport layer 4 is selected from NPB [N, N'-bis(1-naphthyl)-N, N'-diphenylbenzidinediamine] with a thickness of 25nm; and then the light-em...
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