Hydrocracking method of deep cut anthracene oil

A technology of hydrocracking and deep anthracene oil, which is applied in the fields of hydrotreating process, petroleum industry, and hydrocarbon oil treatment, etc. It can solve the problem that the nitrogen content of heavy distillate meets the feed requirements, the activity stability of hydrogenation catalyst is unfavorable, Affecting the operation cycle of the device and other issues, achieving the effect of safe and stable operation, saving equipment investment and increasing load

Active Publication Date: 2011-05-04
CHINA PETROLEUM & CHEM CORP +1
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] CN101024780A uses conventional anthracene oil as raw material to produce high-quality diesel oil. It adopts a series process of hydrofinishing-hydrocracking. The ammonia and water generated in the process of hydrofinishing have adverse effects on the activity and stability of subsequent hydrogenation catalysts, affecting the device operating cycle, can not process deep dipanthracene oil
CN101033409A refines and produces oil with a nitrogen content of <400 μg/g...

Method used

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  • Hydrocracking method of deep cut anthracene oil
  • Hydrocracking method of deep cut anthracene oil
  • Hydrocracking method of deep cut anthracene oil

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~3

[0060] See Table 2 for the properties of deep drawn anthracene oil raw materials. See the example process figure 1 .

[0061] Table 2 Feedstock oil properties

[0062] Crude oil name

Deep drawn anthracene oil

Distillation range / ℃

IBP / 10%

203 / 324

30% / 50%

345 / 380

70% / 90%

407 / 492

95% / EBP

550 / 648

Density (20℃) / g·cm -3

1.15

S / μg·g -1

5500

N / μg·g -1

13200

Four components*,% (mass fraction)

Saturation point

0.1

Aromatic

72.09

Gum

23.31

Asphaltene

4.5

[0063] *The four components are measured using SH / T 0509-1992 standard method.

[0064] In the embodiment, two reactors are used in the hydrorefining reaction zone. The first reactor is filled with hydrogenation protective agents FZC-100, FZC-102B, and FZC-103 from top to bottom, and the second reactor is filled with hydrorefining catalyst. 3936. In the embodiment, the volume ratio of FZC-100:FZC-102B:FZC-103:3936 is as follows: 6:15:19:60. The results of the reaction are shown in Table 3.

Embodiment 4

[0066] The hot low-fraction oil obtained in Example 1 is recycled back to the hydrorefining reaction zone at a circulating weight ratio of 3.0, and the remaining part enters the hydrocracking reaction zone, and passes through the hydrorefining catalyst 3936, the hydrodecarbonization catalyst HDC-1, The volume ratio of the hydrocracking catalyst A1 and the post-treatment hydrofining catalyst FF-26 is 40:15:40:5.

Embodiment 5

[0068] The hydrorefining oil obtained in Example 1 was replaced with the hydrorefining oil obtained in Example 2, the cycle weight ratio was 5.0, the hydrocracking catalyst was changed to A2, and the rest were the same as in Example 4.

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Abstract

The invention provides a hydrocracking method of deep cut anthracene oil. The method comprises the following steps of: refining deep cut anthracene oil by means of hydrogenation, then subjecting the deep cut anthracene oil into gas-liquid separation by means of a hot high-pressure separator and a hot low-pressure separator, partially recycling the hot low boiling point oil obtained into the hydrofining region to mix with the deep cut anthracene oil, infusing the residual hot low boiling point oil into the hydrocracking region and then orderly adding a hydrofining catalyst, a hydrodecarbonation catalyst and a hydrocracking catalyst, wherein the hydrocracking product and the gas separated from the hot high-pressure separator are entered into a cold high-pressure separator, the liquid separated during the hydrocracking process and the gas separated from the hot low-pressure separator are entered into a cold low-pressure separator, and the liquid separated during the hydrocracking process is infused into the product distillation column after stripping so as to obtain gasoline and diesel fractions. The hydrocracking method of deep cut anthracene oil provided by the invention has the advantages that the deep cut anthracene oil can be processed, the range of raw material is enlarged, the deep cut anthracene oil can be inversed in the maximum extent and the yield of light fuel oil is improved; simultaneously, the activity of hydrocracking catalyst is effectively protected and the device can be run in a long period.

Description

Technical field [0001] The invention relates to a deep drawn anthracene oil hydrocracking method, in particular to a deep drawn anthracene oil hydrocracking method to produce clean fuel oil. Background technique [0002] Coal tar is a by-product of coking technology, and anthracene oil is one of its distillation products. Generally, the fraction at 300-360°C is called I anthracene oil, the fraction at 360-500°C is called II anthracene oil, and the fraction above 500°C is a bituminous component. In recent years, coal tar hydrogenation has attracted much attention in the coal chemical industry. The dry point of the hydrogenated raw materials is generally less than 500-550°C. As a processing raw material that needs to be increased in added value, the asphalt component is currently only used as an electrode and carbon raw material. The economy is slightly worse (see "Development and Utilization of Coal Tar Pitch and Its Prospects", "Entrepreneur's World", Issue 8, 2007). At present,...

Claims

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Application Information

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IPC IPC(8): C10G67/02
Inventor 许杰关明华
Owner CHINA PETROLEUM & CHEM CORP
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