Catalyst for gas phase hydrogenation of acetic acid to prepare ethanol
A technology for preparing ethanol and catalysts, applied in metal/metal oxide/metal hydroxide catalysts, physical/chemical process catalysts, organic chemistry, etc., to reduce energy consumption and improve selectivity
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Embodiment 1
[0027] The catalyst of embodiment 1 is 10%Mo-5%Re-1.0%Ru / almond kernel carbon. Prepared by conventional impregnation method: take 8.40 grams of apricot kernel charcoal (20-40 mesh), soak and boil in 3%wt nitric acid for 4 hours before use, wash with distilled water to about pH=7.0, dry at 120°C for 6 hours, and configure 15ml contains 1.8971 grams (NH 4 ) 2 Mo 2 o 4 .4H 2 O, 0.7203 g NH 4 ReO 4 and 0.1996 g RuCl 3 .3H 2 O aqueous solution, air-dried naturally, and oven-dried at 120°C for 4 hours. Before use, in hydrogen at 300°C (atmospheric pressure, 1000h -1 ) reduction activation for 5 hours.
Embodiment 2
[0029] Catalyst 10%W-5.0%Re-1.0%Ru / almond charcoal of embodiment 2. In addition to the configuration 15ml contains 1.5443 grams (NH 4 ) 2 WO 4 Except aqueous solution, all the other preparation steps are identical with embodiment 1.
Embodiment 3
[0031] Catalyst of Example 3 10%W-5.0%Re-1.0%Ru / coir charcoal. Except weighing 8.40 grams of coconut shell charcoal, all the other preparation steps are the same as in Example 2.
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