A kind of preparation method of back silver paste for crystalline silicon solar cell
A technology of solar cells and crystalline silicon, which is applied in the manufacture of cables/conductors, conductive materials dispersed in non-conductive inorganic materials, circuits, etc., and can solve the problems of low conversion efficiency of cells
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[0021] A preparation method of back silver paste for crystalline silicon-based solar cell, it comprises the steps:
[0022] Step 1): Vector Preparation
[0023] Add ethyl cellulose resin to 70% to 95% of butyl carbitol ester, butyl carbitol acetate or terpineol according to 5% to 30% by weight or its ratio of 1:1 Or in a mixed solution of 1:1:2, dissolve completely in a constant temperature water tank at a temperature of 75°C to 95°C, and filter through a 250 to 325 mesh screen to obtain an organic carrier;
[0024] Step 2): Slurry Preparation
[0025] The weight percentage is 1.0%~5% lead-free glass powder, 56%~76% flake silver powder (tap density 4.0-6.0g / cm 3 ), 0.2-2% inorganic additives, 10%-30% organic vehicle prepared in step 1), 3%-12% solvent (same as the solvent in step 1)) and 0.1%-1% Plasticizer, 0.1-1% dispersant, mix them evenly in a planetary or other mixer, and then disperse them on a three-roller machine to below 20μm. Finally, filter through a 250-325 mes...
Embodiment 1
[0029] 1) Preparation of organic carrier: add 5% ethyl cellulose resin to 95% terpineol by weight percentage, heat to 75°C in a constant temperature water bath until completely dissolved, and filter through 250 mesh for later use;
[0030] 2) preparation of slurry: 3% glass powder, 70% flake silver powder, 0.2% Bi 2 o 3 , step 1) prepared 20% organic carrier, 5.8% terpineol solvent, 0.6% tri-n-butyl citrate, 0.4% BYK-111, they are mixed uniformly in planetary or other mixers, and then Disperse on a three-roll machine to a thickness below 20 μm, and finally filter through a 250-mesh screen to obtain an environmentally friendly silver paste with a viscosity of 90 kcps.
Embodiment 2
[0032] 1) Preparation of the organic carrier: add 10% ethyl cellulose resin to 90% butyl carbitol by weight percentage, heat to 85°C in a constant temperature water bath until completely dissolved, filter at 325 mesh for later use;
[0033] 2) Preparation of slurry: by weight percentage, the above-mentioned 1.0% glass powder, 76% flake silver powder, 0.8% ZrO 2 , 10% organic vehicle, 11.0% butyl carbitol, 0.2% acetyl tri-n-butyl citrate, 1% BYK-110, mix them evenly in a planetary or other mixer, and then mix them in a three-roller Disperse on the machine to below 20μm, and finally filter through a 325-mesh sieve to obtain an environmentally friendly silver paste with a viscosity of 80kcps.
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