Green quick drying hybrid raw lacquer and preparation method thereof
A raw lacquer, green technology, applied in the direction of natural resin coatings, coatings, etc., can solve the problems of fast drying and popularization of raw lacquer, consumption of organic solvents, uneconomical, etc., and achieve good application prospects and market promotion value. , The effect of simple process and convenient operation
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Embodiment 1
[0011] Embodiment 1: at room temperature, 1g nano-TiO 2 Add 20ml of dimethyl sulfoxide to the three-necked flask, mechanically stir for 30min to make it evenly dispersed, and then add nano-TiO 2 10% urushiol by mass, continue to stir for 4 hours to make it fully react. The reacted mixture was centrifuged at high speed, washed and dried. The obtained urushiol-modified nano-TiO 2 In water containing 5% (v / v) n-butanol added at a mass ratio of 5%, stirring and ultrasonication for 30 min each, repeated twice, to obtain uniformly dispersed modified nano-TiO 2 Powder suspension.
[0012] The prepared urushiol-modified nano-TiO 2 The suspension was added to the raw lacquer emulsion at a mass ratio of 1%, stirred for 20 minutes, and then homogenized with a homogenizer for 40 minutes to obtain urushiol-modified nano-TiO 2 Hybrid lacquer coatings.
Embodiment 2
[0013] Embodiment 2: Nano-TiO 2 The water containing 8% (v / v) ethanol added by mass ratio 5%, stirred for 30min, ultrasonicated for 30min, repeated 2 times, and prepared uniformly dispersed nano-TiO 2 Powder suspension.
[0014] The prepared nano-TiO 2 The suspension was added to the raw lacquer emulsion at a mass ratio of 5%, stirred for 20 minutes, and then homogenized with a homogenizer for 1.5 hours to obtain nano-TiO 2 Hybrid lacquer coatings.
Embodiment 3
[0015] Example 3: Ca 2+ - The rectorite is uniformly dispersed in water, and after high-speed stirring, a stable rectorite suspension is obtained. Prepare a certain amount of sodium dodecylsulfonate as a 1% aqueous solution, add it dropwise to the rectorite suspension at 70°C, stir for 5 hours, filter with suction, wash, and dry to obtain sodium dodecylsulfonate modified rectorite. Topstone. Sodium dodecylsulfonate modified rectorite was added into water containing 10% ethanol (v / v) according to the mass ratio, stirred for 30 minutes, ultrasonicated for 20 minutes, and repeated twice to obtain evenly dispersed dodecyl Sodium alkylsulfonates modify rectorite suspensions.
[0016] Add the prepared sodium dodecylsulfonate modified rectorite suspension into the raw lacquer emulsion at a mass ratio of 1%, stir for 20 minutes, and then use a ball mill to grind for 1 hour to obtain sodium dodecylsulfonate modified rectorite Stone hybrid raw lacquer coating.
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