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Method for hot-dip galvanizing strip steels

A technology of hot-dip galvanizing and strip steel, applied in hot-dip galvanizing process, coating, metal material coating process, etc., can solve the deterioration of corrosion resistance, galvanized layer damage, strip corrosion resistance, black resistance Problems such as poor modified lubrication performance, to achieve good welding performance and coating performance, improved wear resistance and adhesion performance, and optimized coating grain orientation.

Active Publication Date: 2014-12-24
WUXI GUANGRUN METAL PROD CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In order to meet these characteristics, some domestic iron and steel enterprises have developed alloyed hot-dip galvanized sheets. The production method of alloyed hot-dip galvanized strip steel is to heat the hot-dip galvanized strip steel in an alloying furnace after galvanizing at about 500°C. , the alloying reaction between the surface pure zinc layer and the steel substrate is formed to form an alloyed coating composed of Fe-Zn compounds, but the corrosion resistance, blackening resistance and electrical conductivity of the alloyed hot-dip galvanized strip steel are poor , and the coating is prone to powdering and peeling during stamping deformation, and the galvanized layer is easily damaged, which not only deteriorates the corrosion resistance, but also easily causes surface defects, affecting the appearance after coating
The Chinese patent application with application number 02801081.7 introduces a production method of alloyed hot-dip galvanized strip steel, but the strip steel produced by it has disadvantages such as poor corrosion resistance, blackening resistance, and lubricating performance. On January 27, 2002, the Directive on Waste Electrical and Electronic Equipment (WEEE-2002 / 96 / EC) and the Directive on Prohibiting the Use of Certain Hazardous Substances in Large Electrical and Electronic Equipment (RoHS-2002 / 95 / EC) were officially announced. The directive requires that the sale of electronic and electrical equipment containing hazardous substances such as Hg, Cd, Cr6+, Pb, PPBs, and PBDEs will be prohibited in the EU market from July 1, 2006
However, general zinc-iron alloy products usually use non-passivation or hexavalent chromium passivation, which seriously affects their performance and environmental protection requirements.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A strip steel hot-dip galvanizing method, comprising the steps of:

[0024] (1) Pretreatment: The strip steel is subjected to an electrochemical degreasing process to completely remove impurities such as oil stains, rust and carbon black on the surface of the steel plated parts;

[0025] (2) Annealing: The degreased and cleaned strip enters the continuous annealing furnace for heat treatment: the heat treatment temperature is 730°C;

[0026] (3) Hot-dip galvanizing: the temperature of the steel strip entering the zinc pot is 500°C, and the temperature of the zinc bath is 490°C; the zinc bath contains the following components in weight percentage: Al 0.5%, Cu0.06%, Fe 0.3%, and The amount is zinc and unavoidable impurities;

[0027] (4) Air knife thickness control: the above-mentioned steel strip that is dip-coated with coating solution is controlled under an air knife to control the thickness of the coating, the air knife pressure is 0.008MPa, and the coating thickness...

Embodiment 2

[0032] A strip steel hot-dip galvanizing method, comprising the steps of:

[0033] (1) Pretreatment: The strip steel is subjected to an electrochemical degreasing process to completely remove impurities such as oil stains, rust and carbon black on the surface of the steel plated parts;

[0034] (2) Annealing: The strip steel after degreasing and cleaning enters the continuous annealing furnace for heat treatment: the heat treatment temperature is 750°C;

[0035] (3) Hot-dip galvanizing: the temperature of the steel strip entering the zinc pot is 520°C, and the temperature of the zinc bath is 470°C; the zinc bath contains the following components in weight percentage: Al 0.8%, Cu 0.03%, Fe 0.7%, the balance for zinc and unavoidable impurities;

[0036] (4) air knife thickness control: the above-mentioned steel strip that is dip-coated with coating solution is controlled under the air knife to control the thickness of the coating, the air knife pressure is 0.01MPa, and the coat...

Embodiment 3

[0041] A strip steel hot-dip galvanizing method, comprising the steps of:

[0042] (1) Pretreatment: The strip steel is subjected to an electrochemical degreasing process to completely remove impurities such as oil stains, rust and carbon black on the surface of the steel plated parts;

[0043] (2) Annealing: The strip steel after degreasing and cleaning enters the continuous annealing furnace for heat treatment: the heat treatment temperature is 740°C;

[0044] (3) Hot-dip galvanizing: the temperature of the steel strip entering the zinc pot is 510°C, and the temperature of the zinc bath is 480°C; the zinc bath contains the following components in weight percentage: Al 0.6%, Cu 0.05%, Fe 0.5%, the balance for zinc and unavoidable impurities;

[0045] (4) Air knife thickness control: the above-mentioned steel strip that is dip-coated with coating solution is controlled under an air knife to control the thickness of the coating, the air knife pressure is 0.009MPa, and the coat...

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Abstract

The invention discloses a method for hot-dip galvanizing strip steels, the method of the invention optimizes the traditional hot-dip galvanizing liquid, optimizes the orientation of coating crystal grains and obviously raises the scratch resistance, wear resistance and adhesiveness of a coating layer. The method employs a non-chrome environmentally-friendly passivating solution formula for satisfying the requirement of environmental protection. Compared with the prior art, the hot-dip galvanized strip steels have good welding performance and coating performance of the traditional alloying hot-dip galvanizing strip steels, and have excellent corrosion resistant performance, black resistance performance, conductivity and environmental protection performance.

Description

technical field [0001] The invention relates to the field of strip steel surface coating, in particular to a strip steel hot-dip galvanizing method. Background technique [0002] The production method of hot-dip galvanized steel strip has experienced the evolution process of the early Sendzimir process, the improved Sendzimir process and the United States steel process. Affected by the production process, it is difficult for the products produced by the improved Sendzimir process to meet the requirements of alloyed strip regardless of their surface quality (including spangle structure) or the range of steel types that can be produced; in addition, the post-treatment of the Sendzimir process The production of environmentally friendly alloyed hot-dip galvanized steel strips is generally not considered in the design of the section, so the equipment configuration of the post-processing section cannot meet the needs of producing environmentally friendly alloyed hot-dip galvanized...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C2/06C23C22/42C23C2/16C23C2/02
Inventor 王一新黎立
Owner WUXI GUANGRUN METAL PROD CO LTD
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