The invention relates to high performance leadless piezoelectric ceramics and its preparation technology, the preparation technology comprises the following steps: burdening titanium dioxide, barium carbonate and stannic oxide according to stoichiometric ratio of 0.89: 1: 0.11, ball milling, pre-burning, performing secondary ball milling, granulation granulating and molding, covering by a crucible finally, putting in a sintering furnace, heating to the temperature of 500 DEG C by a speed of 2 DEG C/min, insulating for 2 hours and dumping, then heating to the temperature of 1400 DEG C at the speed of 4 DEG C/min and insulating for 4 hours, and then cooling in furnace to the room temperature to obtain the required leadless piezoelectric ceramics. The leadless piezoceramic material has high dielectric and piezoelectric performance at quasi four-phase point, the relative dielectric constant of the material can reach 75000 which is 6-7 times of the dielectric constant of pure barium titanate at the Curie temperature, the piezoelectric coefficient d33 can reach 697pC/N which is 5 times of the room temperature piezoelectric coefficient of the pure barium titanate, and the data can be the highest data in that of the leadless piezoceramic material.