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Desalination method by membrane vaporization absorption

A desalination and absorbent technology, applied in chemical instruments and methods, general water supply conservation, water/sewage multi-stage treatment, etc. High yield, comprehensive utilization, and reduction of concentrated water discharge

Inactive Publication Date: 2012-05-16
吕晓龙
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

There are two main problems in reverse osmosis technology: one is the low recycling rate of reverse osmosis fresh water, which generally can only reach about 40%, and about 60% of the concentrated water is still discharged
If the reverse osmosis treatment of concentrated seawater is continued, the operating pressure will be greatly increased and the cost will be increased
Second, reverse osmosis seawater desalination technology cannot fully remove boron in natural seawater, far exceeding the standards set by the World Health Organization
[0022] In recent years, for large-scale seawater desalination projects, the cost of desalinated water has been reduced to 6-7 yuan / t, but it is still too expensive for poor and underdeveloped countries and regions
Although the membrane distillation method produces good water quality, it requires additional energy to condense the steam, consumes phase change heat, and consumes a lot of energy.

Method used

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  • Desalination method by membrane vaporization absorption
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  • Desalination method by membrane vaporization absorption

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0062] According to the white granulated sugar of 1.2 parts quality and the pure water of 1 part quality, prepare 54.5wt% white granulated sugar solution as absorbent, the initial conductivity of white granulated sugar absorbent is 44 μ S / cm, and salt water is seawater near Tianjin, TDS (total dissolved in water The total dissolved solids (TDS for short) is 3.3wt%. The absorbent volume is 3 liters, the seawater volume is 500ml, and the membrane module material is a hydrophobic polyvinylidene fluoride hollow fiber membrane with a membrane area of ​​0.053m 2 . Such as figure 2 , a water bath 13 is provided, and a sea water tank 11 and a white sugar absorbent tank 12 are arranged in the water bath 13 . First pass through the water bath 13, heat the seawater and white sugar absorbent to 75°C, then pump the seawater into the tube side of the hollow fiber membrane module through the seawater pump 15, and then pass the white sugar absorbent through the absorbent pump 14 Pump into ...

Embodiment 2

[0065] According to 2 parts of quality glucose (analytical pure) and 1 part of quality of pure water, prepare 66.7wt% glucose aqueous solution as absorbent, the initial conductivity of glucose absorbent is 5.5μS / cm, the salt water is Tianjin offshore seawater, TDS is 3.3 wt%. Absorbent volume is 3 liters, and seawater volume is 1000ml, all the same with embodiment 1.

[0066] Such as Figure 4 , as the absorbent is diluted by the pure water passing through the membrane, glucose powder is continuously added to the absorbent during the process to keep the concentration of the absorbent constant. When the seawater TDS is concentrated 11.8 times from 3.3wt% to 29.7wt%, the membrane flux is from the initial 1.46kg / m 2 .h gradually reduced to 0.11kg / m 2 .h, the water production rate of seawater reached 92%.

Embodiment 3

[0068] Separation is carried out by utilizing the solubility difference of pure water in the absorbent at different temperatures. Such as using butanol, DOP (dioctyl phthalate) and other absorbents, the process is as follows Figure 5 . After the absorption liquid is heated, it enters the tube side of the membrane module, and the seawater is heated by the heat exchanger and enters the shell side of the membrane module. In the membrane module, after the absorbent absorbs water molecules, it is discharged into the heat exchanger as a heat source, and the absorbent after heat exchange By cooling and stratifying, fresh water is produced. Since part of the absorbent can also be dissolved in water, the produced water is an aqueous solution of the absorbent, which requires secondary separation to remove the absorbent.

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Abstract

The invention provides a desalination method by membrane vaporization absorption. The method provided by the invention is characterized by comprising the following steps of: using a hydrophobic millipore membrane as a separation device and allowing two side surfaces of the hydrophobic millipore membrane to respectively contact with a processed liquid and an absorbent; absorbing water molecules in the processed liquid by the absorbent, wherein the temperature of the processed liquid is the same as or similar to that of the absorbent; separating the absorbent and water after absorption of the water molecules by the absorbent, so as to obtain desalinated water. The invention has the following effects: high-quality desalinated water is obtained at low cost; membrane pollution is slight; the yield of seawater desalination is high, and the discharge of concentrated water is minimized after seawater desalination so as to cause no unfavorable influence on the ecological environment; comprehensive utilization of seawater chemical resources can be realized, the technology is optimized to extract potassium, bromine and magnesium chemical products, and consumption of acid, alkali and chlorine chemical medicines is minimized during the technological process; and seawater only undergoes simple sand filtration as a pretreatment. In comparison with a reverse osmosis technology, the pretreatment is simple, and the quality of the desalinated water by the pretreatment is much better than that of product water by reverse osmosis.

Description

technical field [0001] The invention relates to a membrane desalination method, especially a method suitable for seawater desalination. Background technique [0002] With the rapid development of society and the rapid increase of population, the shortage of fresh water resources has attracted the attention of all countries in the world. According to statistics from the United Nations, nearly 700 million people in 43 countries around the world often face "water stress" and water shortages. About one-sixth of the people have no clean drinking water, and one-third of the people have difficulty in living with water. In 2009, drought victims The number is several times the number of migrants due to armed conflict. In the context of global warming, "water security" has become a top global issue, and water resources have become a country's strategic resource. The competition for fresh water resources such as rivers will lead to armed conflicts and wars among countries. In fact, t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/10C02F103/08
CPCY02A20/131
Inventor 吕晓龙
Owner 吕晓龙
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