Regenerated animal micropowder protein cellulose fiber and preparation method thereof

A cellulose fiber and animal technology, applied in the direction of cellulose/protein conjugated artificial filament, spinning solution preparation, wet spinning method, etc., can solve the problems of inability to carry out textile processing research, affect the quality of protein fibers, and destroy cavities structure and other issues, to achieve the effect of regenerated animal micropowder protein cellulose fiber with better textile processing and wearing performance, smaller density and comfortable wearing

Active Publication Date: 2013-12-18
潍坊欣龙生物材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the early 1940s, the United States developed casein fiber; in 1945, the United States and Britain studied soybean protein fiber; in 1948, General Motors of the United States extracted soybean protein fiber from soybean meal, but most of them could not be processed because of poor fiber performance. Textile processing while interrupting research
[0007] Based on the production technology of protein fibers disclosed at home and abroad, no matter it is viscose fiber or other wet-spun synthetic fibers, it basically adopts the lye treatment of first dissolving animal or vegetable protein to obtain protein, and then Adding it to the traditional fiber production process for wet spinning, on the one hand, the original cavity structure of the protein fiber is completely destroyed after the protein is dissolved; on the other hand, in order to solidify the protein liquid, aldehydes must be used to shrink Formaldehyde or use of heavy metal chromium salts for denaturation and curing not only affects the quality of protein fibers, but also such toxic substances will cause serious environmental pollution

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] Example 1 1.67dtex×38mm regenerated animal micronized protein viscose fiber

[0034] First prepare animal micropowder protein: add textile waste wool to 9wt% sodium hydroxide solution, the bath ratio is 1:6, soak at a temperature of 21°C for 60 minutes, wash at a temperature of 35°C, and filter to remove impurities Finally, it is dried in a three-dimensional rotary oven at a drying temperature of 80°C, and then pre-crushed. The pre-crushed wool is added to a 15.8wt% sodium hydroxide solution with a bath ratio of 1:11.5 and a temperature of 31°C. Swell for 105 minutes, then grind to animal protein powder with an average particle size of 8.5 microns by a grinding pump, wash the ground animal protein powder at a temperature of 41°C, and then dry it at 71°C, and dry the dried animal protein powder The protein powder is pulverized to an average particle size of 1.3 microns to obtain animal micropowder protein.

[0035] Preparation of animal micropowder protein viscose fibe...

Embodiment 2

[0037] Example 21.33dtex×38mm regenerated animal micronized protein viscose fiber

[0038] First prepare animal micropowder protein: add pig hair to 11.5wt% sodium hydroxide solution, the bath ratio is 1:8, soak at 23°C for 80 minutes, wash at 38°C, filter to remove impurities Use a three-dimensional rotary oven for drying, the drying temperature is 83°C, and then pre-grind, add the pre-grinded pig hair to 18.7wt% sodium hydroxide solution, the bath ratio is 1:14.5, and the temperature is 33°C Swell for 120 minutes, then grind to an animal protein powder with an average particle size of 9.5 microns by a grinding pump, wash the ground animal protein powder at a temperature of 43°C, and then dry it at 72°C, and dry the dried animal protein powder The protein powder is crushed to an average particle size of 2.0 microns to obtain animal micronized protein.

[0039] Preparation of animal micropowder protein viscose fiber: the animal micropowder protein with an average particle s...

Embodiment 3

[0041] Example 3 2.78dtex×51mm regenerated animal micronized protein viscose fiber

[0042] First prepare animal micropowder protein: add feathers to 8.2wt% sodium hydroxide solution with a bath ratio of 1:5, soak for 62 minutes at a temperature of 18°C, wash with water at a temperature of 33°C, and filter to remove impurities. Dry in a three-dimensional rotary oven, the drying temperature is 77.5°C, and then pre-grind, add the pre-grinded feathers to 15wt% sodium hydroxide solution, the bath ratio is 1:10.5, and the temperature is 28°C to swell for 105 minutes , and then grind to animal protein powder with a particle size of 8-10 microns by a grinding pump, wash the ground animal protein powder at a temperature of 38°C, and then dry it at 68°C, and dry the dried animal protein powder Grinding to a particle size of 1-2.2 microns to obtain animal micropowder protein.

[0043] Preparation of animal micropowder protein viscose fiber: Add animal micropowder protein with an aver...

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Abstract

The invention discloses a regenerated animal micropowder protein cellulose fiber and a preparation method thereof. The preparation method comprises the following steps of: adding nanoscale animal micropowder protein into a dispersant solution, stirring the mixture uniformly, filtering to obtain 20 to 35 weight percent of animal micropowder protein liquid; preparing viscose by using cellulose pulp as a raw material, adding denaturant in the dissolution step to obtain modified viscose; adding the animal micropowder protein liquid into the modified viscose in a weight ratio of animal micropowder to the finished fiber of (1-30):100, uniformly stirring to obtain animal micropowder compounding viscose; and defoaming and filtering, spinning molding by introducing a coagulating bath, and then drawing filament and performing aftertreatment to obtain the animal micropowder protein viscose fiber. The fabric made of the regenerated animal micropowder protein cellulose fiber is low in density, and is light; the hygroscopicity, the air permeability and the thermal insulating property of the fabric are further improved; the fiber textile processing and wearability are good; and the production process is pollution-free.

Description

technical field [0001] The invention relates to the technical field of modified cellulose, in particular to a regenerated animal micropowder protein cellulose fiber and a preparation process thereof. Background technique [0002] Protein fibers are divided into two categories: natural protein fibers (such as wool, silk, etc.) and regenerated protein fibers. According to the source of raw materials, regenerated protein fibers can be divided into regenerated animal protein fibers and regenerated plant protein fibers. Regenerated animal protein fiber mainly refers to fiber spun from milk, feathers, wool, pig hair, etc., and regenerated plant protein fiber mainly refers to fiber spun from corn, soybean, peanut, rapeseed, etc. [0003] Foreign countries began to research on regenerated protein fiber from the end of the 19th century and the beginning of the 20th century. Italian scientists in 1935, British ICI Company in 1938, and Corn Product Refining Company in 1939 discussed ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D01F8/02D01F2/06D01D5/06D01D1/02
Inventor 王乐军马君志秦翠梅姜明亮李昌垒王东郝连庆吴亚红
Owner 潍坊欣龙生物材料有限公司
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