Method for preparing high-viscosity heat-resistant resin with ethylene tar as raw material
A technology of ethylene tar and heat-resistant resin, which is applied in the direction of tar processing and adhesives through distillation, which can solve the problems of weak market competition and high production costs, and achieve good bonding performance and good heat resistance.
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[0011] Example 1
[0012] Take a certain amount of ethylene tar in a distillation flask, slowly raise the temperature to 250°C, and distill under normal pressure to remove the fractions before 250°C to obtain ethylene heavy tar with a mass yield of 77.24%. Add ethylene heavy tar and terephthalic dimethanol with a mass ratio of 5:1 to the reactor, and add 5% of the total mass of p-toluenesulfonic acid. Under the protection of nitrogen, the temperature is raised to 140°C and reacted for 3h to obtain a resin The product, the resin mass yield is 94.06%, the softening point is 117°C, and the carbon residue rate at 500°C in the air is 35.43% (mass ratio), indicating that it has good heat resistance. Its bonding performance is expressed by the mass content of toluene-insoluble quinoline solubles (β resin), in which the mass content of toluene insolubles is 18.25%, the mass content of quinoline insolubles is 5.83%, and the mass content of β resin is 12.42%. The binding performance is eq...
Example Embodiment
[0013] Example 2
[0014] Take a certain amount of ethylene tar in a distillation flask, slowly raise the temperature to 300°C, and distill under normal pressure to remove the fractions before 300°C to obtain ethylene heavy tar with a mass yield of 62.59%. Add ethylene heavy tar and terephthalic methanol with a mass ratio of 5:1 to the reactor, and add 5% of the total mass of p-toluenesulfonic acid, and heat to 140℃ under the protection of nitrogen, and react for 2h to obtain resin The product, the resin mass yield is 91.13%, the softening point is 114°C, and the carbon residue rate at 500°C in the air is 40.70% (mass ratio), indicating that it has good heat resistance. The mass content of toluene insoluble matter is 32.04%, the mass content of quinoline insoluble matter is 10.93%, and the mass content of β resin is 21.11%. Its adhesiveness is equivalent to the first grade electrode pitch used as a binder (GB8730-88: Toluene insoluble matter 28-34, quinoline insoluble matter, 8-...
Example Embodiment
[0015] Example 3
[0016] The preparation of ethylene heavy tar is the same as in Example 1. Add ethylene heavy tar and benzaldehyde with a mass ratio of 3:1 to the reactor, and add 5% of the total mass of p-toluenesulfonic acid, and heat to 160°C under the protection of nitrogen. After reacting for 3 hours, a resin product was obtained. The resin mass yield was 97.23%, the softening point was 96°C, and the carbon residue rate at 500°C in the air was 35.60% (weight ratio), indicating good heat resistance. The mass content of toluene insoluble matter is 25.44%, the mass content of quinoline insoluble matter is 9.63%, and the mass content of β resin is 15.81%, indicating that it has good bonding properties.
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