Method for preparing cardanol modified phenolic paper-based copper clad plate
A phenolic paper-based, cardanol technology is applied in chemical instruments and methods, synthetic resin layered products, layered products, etc., and can solve the problems of cardanol ineffectiveness, difficulty in reducing product cost, and increasing the amount of tung oil. , to achieve the effect of improving flexibility, saving tung oil consumption and low price
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Embodiment 1
[0029] A kind of preparation method of cardanol modified phenolic paper base copper clad laminate, described method comprises the steps:
[0030] 1. Preparation of modified phenolic resin mixed solution:
[0031] Step A, preparation of cardanol modified phenolic resin
[0032] The raw material mass portion proportioning of described cardanol modified phenolic resin is as follows:
[0033] 1200 parts of phenol;
[0034] Cardanol 800 parts;
[0035] 1500 parts of formaldehyde;
[0036] 2 parts of triethylamine;
[0037] Ammonia 25% concentration 80 parts;
[0038] 1300 parts of methanol;
[0039] During preparation, phenol, cardanol, formaldehyde, triethylamine and ammonia water are added to the reaction kettle for reaction, the reaction temperature is 95-100°C, the reaction time is 40-60 minutes, and then methanol is added as a solvent to obtain a phenolic resin solution;
[0040] Step B, prepare tung oil modified phenolic resin
[0041] First add 260 parts by mass of t...
Embodiment 2
[0048] The preparation method in this embodiment is identical with embodiment 1, and its difference is only in:
[0049] In step A:
[0050] 1100 parts of phenol;
[0051] Cardanol 700 parts;
[0052] 1300 parts of formaldehyde;
[0053] 1.5 parts of triethylamine;
[0054] Ammonia 25% concentration 70 parts;
[0055] 1200 parts of methanol.
Embodiment 3
[0057] The preparation method in this embodiment is identical with embodiment 1, and its difference is only in:
[0058] In step A:
[0059] 1300 parts of phenol;
[0060] Cardanol 900 parts;
[0061] 1500 parts of formaldehyde;
[0062] 2.5 parts of triethylamine;
[0063] Ammonia 25% concentration 90 parts;
[0064] Methanol 1500 parts.
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