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Adhesive

An adhesive, urea technology, applied in the direction of adhesive, adhesive type, aldehyde/ketone condensation polymer adhesive, etc., can solve the problem of uneven mixing of scavenger or modifier and adhesive, and unstable formaldehyde emission from particleboard. , increase production costs and other issues, to achieve the effect of reducing the discharge time of water vapor, improving the working environment of the workshop, and having a high level of environmental protection

Inactive Publication Date: 2012-07-25
上海美连商务信息咨询服务有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the production method of E0 grade particleboard, if modified dehydration urea-formaldehyde resin adhesive is used, the wastewater released in the production process needs to be treated before discharge, which increases production costs; while using non-dehydrated modified urea-formaldehyde resin adhesive, in It is necessary to add formaldehyde scavenger or modifier or compound additives when mixing glue to make the environmental protection level of the produced particleboard reach E0 level, but adding formaldehyde scavenger or modifier when mixing glue will cause short stirring time and easy Cause the capture agent or modifier and the adhesive to be stirred unevenly, so that the formaldehyde emission of the produced particleboard board is unstable, which can reach the E0F4 level in Japan, and the "Toxic Air Pollutant Control Measures for Reducing Formaldehyde Emissions from Composite Wood Products" in California, USA. The standard for formaldehyde emission in the second stage is even less

Method used

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  • Adhesive

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] It is prepared from 12666kg of formaldehyde aqueous solution, 9972kg of urea, 55kg of polyvinyl alcohol, 1176kg of melamine and 11kg of sodium hydroxide aqueous solution; in the process of preparing the adhesive, the weight parts of urea were added in four times: the first time 2092kg of urea was added, 2811.6kg of urea was added for the second time, 2252.8kg of urea was added for the third time, and 2815.6kg of urea was added for the fourth time.

Embodiment 2

[0030] It is prepared from 12696 kg of formaldehyde aqueous solution, 10104.6 kg of urea, 60 kg of polyvinyl alcohol, 1200 kg of melamine and 12 kg of sodium hydroxide aqueous solution; Add 2112kg of urea for the first time, add 2841.6kg of urea for the second time, add 2302.8kg of urea for the third time, and add 2848.2kg of urea for the fourth time.

Embodiment 3

[0032] It is prepared from 12726 kg of formaldehyde aqueous solution, 10237.2 kg of urea, 65 kg of polyvinyl alcohol, 1224 kg of melamine and 13 kg of sodium hydroxide aqueous solution; Add 2132kg of urea for the first time, add 2871.6kg of urea for the second time, add 2352.8kg of urea for the third time, and add 2880.8kg of urea for the fourth time.

[0033] During the preparation of this adhesive, the type of polyvinyl alcohol selected as the raw material is 20-99 type; the melamine is selected as an industrial first-grade product with a mass content of melamine ≥ 99.0%.

[0034]When using the adhesive of the present invention to manufacture particle boards, the composite curing agent used in the glue adjustment process is composed of industrial dipotassium hydrogen phosphate, industrial ammonium sulfate and industrial phosphoric acid with a mass fraction of 50% according to the mass ratio of 2:2:5. Mix it up. The glue blending process is divided into surface layer glue bl...

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Abstract

The invention discloses an adhesive. The adhesive is characterized in that the adhesive is prepared from raw materials including 12,666 to 12,726kg of aqueous formaldehyde solution, 9,972 to 10,237.2kg of urea, 55 to 65kg of polyvinyl alcohol, 1,176 to 1,224kg of melamine and 11 to 13kg of aqueous sodium hydroxide solution. In the aqueous formaldehyde solution, the mass percent of formaldehyde is36.5 to 37.5; in the urea, the mass percent of nitrogen is 46.0 to 46.4; and in the aqueous sodium hydroxide solution, the mass percent of sodium hydroxide is 25 to 35. The adhesive has the advantages that the productive technology is simple, the solid content is high, the free formaldehyde content is low, formaldehyde catcher or modifying agent is not required to be added during adhesive mixing process when the adhesive is used for manufacturing particle boards, the curing time of the mixed adhesive is short, and the formaldehyde emission of the particle boards manufactured through the adhesive is stable, and can meet the standard of E0F4 level of Japan and the standard on formaldehyde emission in the second stage according to Composite Wood Products Airborne Toxic Control Measure (ATCM)of California, USA.

Description

technical field [0001] The invention relates to an adhesive, which is suitable for the manufacture of composite wood products such as particle boards. Background technique [0002] In recent years, the awareness of environmental protection in various countries in the world has been increasing, and the standards for the formaldehyde emission of urea-formaldehyde resin products have been set higher and higher. According to the "Toxic Air Pollutant Control Measures for Reducing Formaldehyde Emissions from Composite Wood Products" issued by California, USA, the formaldehyde emission of particleboard produced before January 1, 2009 must be below 0.18ppm; the formaldehyde emission of particleboard produced before January 1, 2011 The amount must be below 0.09ppm. Japan's JISA5908-2003 standard stipulates that the formaldehyde emission of F4 star particleboard must be below 0.3mg / L. [0003] But at this stage, due to the convenient use of urea-formaldehyde resin adhesives and high...

Claims

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Application Information

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IPC IPC(8): C09J161/30C08G12/38
Inventor 刘志英袁运增杨红延马凤新张希国陈奇志张国华
Owner 上海美连商务信息咨询服务有限公司
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