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Wide-temperature-range high-damping rubber composition and preparation method thereof

A rubber composition and high damping technology, applied in the field of rubber materials, can solve the problems of poor mechanical properties of materials and the inability to meet the requirements for the use of high damping isolation rubber parts, and achieve high damping performance, excellent tensile strength and elongation at break. effect of length

Inactive Publication Date: 2013-11-20
武汉众道工程技术有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The prior art discloses some preparation methods of wide temperature range high damping rubber, such as the wide temperature range damping material prepared from chloroprene rubber, nitrile rubber and butyl rubber disclosed by Lu Xun et al. (Patent Publication No. CN 102229724 A), the obtained The material has excellent damping performance, but the mechanical properties of the material are poor. The tensile strength is basically 12-14MPa, and the elongation at break is less than 500%, which cannot meet the specific requirements of high-damping and shock-isolating rubber parts.

Method used

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  • Wide-temperature-range high-damping rubber composition and preparation method thereof

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Embodiment 1

[0036] Embodiment 1 (each component is proportioned according to mass parts and mass percentages, the following examples are the same)

[0037] At 40°C, 100 parts of standard full latex granules, 50 parts of isoprene rubber with a cis configuration content of 92%-97%, 1,4-polybutadiene structure at 90% by mass, syndiotactic 60 parts of butadiene rubber with 3-20% by mass of 1,2-polybutadiene and cis-configuration content of 92%-97% were put into the internal mixer respectively, and blended after masticating for 20 minutes; Then add 80 parts of copolymerized petroleum resins, 40 parts of 1500 mesh magnesium strong powder, 140 parts of carbon black N110, 80 parts of sulfur, 120 DEG C of softening point, relative density of 1, acid value of 0.5 mg KOH / g to the blended masticated rubber. 2 parts, 2 parts of vulcanization accelerator N-cyclohexyl-2-benzothiazole, 12 parts of active agent zinc oxide, 2 parts of anti-aging agent N-isopropyl-N'-phenyl-p-phenylenediamine, prepared into...

Embodiment 2

[0040] At 80°C, 100 parts of standard full latex granules, 50 parts of isoprene rubber with a cis configuration content of 92%-97%, 1,4-polybutadiene structure at 90% by mass, syndiotactic 1 , 60 parts of butadiene rubber with 3-20% mass fraction of 2-polybutadiene and cis-configuration content of 92%-97% were put into the internal mixer respectively, and blended after masticating for 20 minutes; It is 120 ℃, relative density 1, acid value 0.5mg KOH / g copolymerized petroleum resin 90 parts, magnesium strong powder 40 parts, carbon black N110 150 parts, sulfur 8 parts, 2 parts of accelerator dibenzothiazole disulfide, 12 parts of active agent zinc oxide, 1 part of active agent stearic acid, 4 parts of antioxidant N-isopropyl-N'-phenyl-p-phenylenediamine, prepared by mixing rubber; park the mixed rubber for 10 hours, and then vulcanize it on a flat vulcanizing machine for 30 minutes at 150°C and a pressure of 20 MPa to obtain the required wide temperature range high damping rubb...

Embodiment 3

[0043] At 100°C, 100 parts of standard full latex granules, 60 parts of isoprene rubber with a cis configuration content of 92%-97%, 1,4-polybutadiene structure at 90% by mass, syndiotactic 50 parts of butadiene rubber with 3-20% by mass of 1,2-polybutadiene and cis-configuration content of 92%-97% were put into the internal mixer respectively, and blended after masticating for 15 minutes Adding 90 parts of copolymerized petroleum resin, 40 parts of magnesium powder, 30 parts of reinforcing agent white carbon black, 120 parts of reinforcing agent carbon black N110, 8 parts of sulfur, 3 parts of accelerator dibenzothiazole disulfide, 12 parts of active agent zinc oxide, 2 parts of active agent stearic acid, anti-aging agent N-isopropyl-N'- 2 parts of phenyl-p-phenylenediamine were prepared into rubber mixture; after the rubber mixture was parked for 7 hours, it was vulcanized on a flat vulcanizing machine for 10 minutes at 200°C and a pressure of 20 MPa to obtain the required w...

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Abstract

The invention provides a wide-temperature range high damping rubber composition and a preparation method thereof, belonging to the field of rubber material. According to the formula, the composition provided by the invention comprises the following components in parts by weight:100 parts of standard full emulsion particles, 50-70 parts of isoprene rubber, 40-60 parts of butadiene rubber, 80-110 parts of high damping additive selected from C5 / C9 copolymerized petroleum resins, 40 parts of magnesium powder, 140-170 parts of reinforcing agent, 8 parts of vulcanizer, 2-4 parts of vulcanization accelerator, 12-17 parts of active agent and 2-4 parts of anti-aging agent. Through adoption of the proper formula and processing process, the high-performance rubber composition having high damping performance, and excellent tensile strength and elongation at break and wide temperature range of over 110 DEG C from -65 to +68 DEG C; the tensile strength and elongation at break of the composition are far beyond the requirements in Rubber Support Section II: Bridge Shock Insulation Rubber Support of National Standard GB 20688.2-2006, so that the composition can be widely applied to highways, bridge shock insulation supports, shock absorption and noise reduction devices and the like, in particular suitable for high damping rubber shock absorption / insulation supports of highways and bridges.

Description

technical field [0001] The invention relates to a wide temperature range high damping rubber composition and a preparation method thereof, belonging to the field of rubber materials, in particular to a high damping rubber material and a preparation method thereof. technical background [0002] The U.S. Materials Review Committee uses a specially developed natural rubber compound as the base-level seismic isolation material. It has now developed into one of the world's most important seismic isolation building materials. The development of high-damping rubber materials has far-reaching significance. The high-performance damping material used in the high-damping rubber seismic isolation bearing has a wide temperature range, high damping value and good comprehensive mechanical properties, and it is also a hot spot in the research of damping materials today. [0003] High-damping shock-isolation rubber materials can produce large internal friction (that is, high damping), but ma...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L21/00C08L9/00C08L57/02C08K13/06C08K3/04C08K3/36C08K3/34C08K3/22C08K3/06C08K5/18
Inventor 曾令子张飞蒋凯峰骆益海
Owner 武汉众道工程技术有限公司